Electrolyte compositions
Disclosed are electrolyte compositions for electrochemical devices, where the electrolyte compositions comprise a microemulsion and where the microemulsion comprises an aqueous phase and a water-immiscible phase. Also disclosed are microemulsion electrolyte compositions for electrically rechargeable electrochemical energy storage devices, including ion batteries (such as lithium ion, sodium ion, magnesium ion, calcium ion, and aluminium ion batteries), redox flow batteries and supercapacitors.
1. An energy storage device comprising:
a liquid electrolyte composition wherein the liquid electrolyte composition comprises a microemulsion, and wherein the microemulsion comprises an aqueous phase and a water-immiscible phase; and
wherein the energy storage device is an electrically rechargeable electrochemical energy storage device.
2. The device of claim 1 , wherein the aqueous phase is a continuous phase.
3. The device of claim 2 , wherein the water-immiscible phase is a dispersed phase.
4. The device of claim 1 , wherein the microemulsion is a bicontinuous microemulsion.
5. The device of claim 1 , wherein the microemulsion further comprises a dissolved salt.
6. The device of claim 5 , wherein the dissolved salt is selected from the group consisting of: a lithium salt, a sodium salt, a potassium salt, a magnesium salt, a calcium salt, and an aluminum salt.
7. The device of claim 6 , wherein the dissolved salt is at a concentration of between 0.001 mol/kg and 10 mol/kg.
8. The device of claim 1 , wherein the microemulsion further comprises one or more redox active organic species.
9. The device of claim 8 , wherein the redox active organic species are dissolved in the water-immiscible phase or aqueous phase.
10. The device of claim 8 , wherein the redox active organic species are dissolved in the water-immiscible phase.
11. The device of claim 1 , wherein the water-immiscible phase comprises an organic solvent.
12. The device of any claim 11 , wherein the organic solvent is selected from the group consisting of aliphatic solvents; aromatic solvents; halogenated solvents; substantially water immiscible ketone solvents; substantially water immiscible ester solvents; or a combination thereof.
13. The device of claim 1 , wherein the microemulsion further comprises a surfactant, a co-surfactant and/or co-solvent.
14. The device of claim 1 , further comprising an anodic electrode and a cathodic electrode and optionally a current collector, wherein at least a portion of the surface of one or more of the anodic electrode, cathodic electrode and current collector is hydrophobic.
15. The device of claim 14 , wherein the portion of the surface of one or more of the anodic electrode, cathodic electrode and current collector is non-metallic or conductive carbon or a conductive polymer.
16. The device of claim 14 , further including an ion permeable separator located between the cathodic electrode and anodic electrode.
17. The device of claim 1 , wherein the device has a cell voltage of greater than 1.23 V.
18. A method for using an electrically rechargeable electrochemical energy storage device comprising connecting the electrically rechargeable electrochemical energy storage device to a load and supplying a charge to the load, wherein the electrically rechargeable electrochemical energy storage device comprises an electrolyte composition, wherein the electrolyte composition comprises a microemulsion, and wherein the microemulsion comprises an aqueous phase and a water-immiscible phase.
19. An electrolyte composition when used in an electrically rechargeable electrochemical energy storage device, wherein the electrolyte composition comprises a microemulsion, wherein the microemulsion comprises an aqueous phase and a water-immiscible phase.