Organic light emitting diode and organic light emitting device including the same
The present disclosure relates to an OLED that includes a first electrode; a second electrode facing the first electrode; a first emitting material layer including a first host, a second host and a blue dopant and positioned between the first and second electrodes; a first electron blocking layer including an electron blocking material of a spirofluorene-substituted amine derivative and positioned between the first electrode and the first emitting material layer; and a first hole blocking layer including a first hole blocking material of an azine derivative and positioned between the second electrode and the first emitting material layer, wherein the first host is an anthracene derivative, and the second host is a deuterated anthracene derivative.
1. An organic light emitting diode (OLED), comprising:
a first electrode;
a second electrode facing the first electrode;
a first emitting material layer including a first host, a second host and a blue dopant and positioned between the first and second electrodes;
a first electron blocking layer including a spirofluorene-substituted amine derivative and positioned between the first electrode and the first emitting material layer; and
a first hole blocking layer including a benzimidazole derivative and positioned between the second electrode and the first emitting material layer,
wherein the first host is an anthracene derivative, and the second host is a deuterated anthracene derivative.
2. The OLED of claim 1 , wherein the benzimidazole derivative is represented by Formula 1:
wherein Ar is C 10 ˜C 30 arylene group, R 1 is C 6 ˜C 30 aryl group or C 5 ˜C 30 hetero aryl group, and R 2 is hydrogen, C 1 ˜C 10 alkyl group or C 6 ˜C 30 aryl group.
3. The OLED of claim 2 , wherein the benzimidazole derivative is selected from the followings of Formula 2:
4. The OLED of claim 1 , wherein the first host is represented by Formula 3:
wherein each of R 1 and R 2 is independently C 6 ˜C 30 aryl group or C 5 ˜C 30 heteroaryl group, and each of L 1 and L 2 is independently C 6 ˜C 30 arylene group, and
wherein each of a and b is an integer of 0 or 1, and at least one of a and b is 0.
5. The OLED of claim 4 , wherein the first host is a compound being one of the followings of Formula 4:
6. The OLED of claim 4 , wherein the second host is represented by Formula 5:
wherein the definition of R 1 , R 2 , L 1 , L 2 , a and be is same as Formula 3, and
wherein each of x, y, m and n is independently a positive integer, and a summation of x, y, m and n may be 15 to 29.
7. The OLED of claim 6 , wherein the second host is a compound being one of the followings of Formula 5-1:
8. The OLED of claim 1 , wherein the second host is a compound in which all or part of hydrogen of the first host is substituted with deuterium.
9. The OLED of claim 1 , wherein a weight % ratio of the first host to the second host is 3:7 to 7:3.
10. The OLED of claim 9 , wherein the weight % ratio of the first host to the second host is 7:3.
11. The OLED of claim 1 , wherein the blue dopant is represented by Formula 6:
wherein each of c and dis independently an integer of 0 to 4, and e is an integer of 0 to 3,
wherein each of R 11 and R 12 is independently selected from the group consisting of C 1 ˜C 20 alkyl group, C 6 ˜C 30 aryl group, C 5 ˜C 30 hetero aryl group and C 6 ˜C 30 aryl amino group, or adjacent two among R 11 or adjacent two among R 12 form a fused aromatic ring or a hetero-aromatic ring,
wherein R 13 is selected from the group consisting of C 1 ˜C 10 alkyl group, C 6 ˜C 30 aryl group, C 5 ˜C 30 hetero aryl group and C 5 ˜C 30 aromatic amino group,
wherein each of X 1 and X 2 is independently oxygen (O) or NR 14 , and R 14 is C 6 ˜C 30 aryl group.
12. The OLED of claim 11 , wherein the blue dopant is a compound being one of the followings of Formula 7:
13. The OLED of claim 1 , wherein the spirofluorene-substituted amine derivative is represented by Formula 8:
wherein L is arylene group, and a is 0 or 1, and
wherein each of R 1 and R 2 is independently selected from the group consisting of C 6 to C 30 arylene group and C 5 to C 30 heteroarylene group.
14. The OLED of claim 13 , wherein the spirofluorene-substituted amine derivative is selected from the followings of Formula 9:
15. The OLED of claim 1 , further comprising:
a second emitting material layer including the first host, the second host and the blue dopant and positioned between the first emitting material layer and the second electrode; and
a first charge generation layer between the first and second emitting material layers.
16. The OLED of claim 15 , further comprising:
a third emitting material layer emitting a yellow-green light and positioned between the first charge generation layer and the second emitting material layer; and
a second charge generation layer between the second and third emitting material layers.
17. The OLED of claim 15 , further comprising:
a third emitting material layer emitting a red light and a green light and positioned between the first charge generation layer and the second emitting material layer; and
a second charge generation layer between the second and third emitting material layers.