IP Library › Granted Patent US 12,319,616
Granted Patent B2
US 12,319,616 · App. 17/563,760 · Granted Jun 3, 2025

Optical glass, optical element including optical glass, and optical apparatus

Inventors: Hiroyuki Inoue (Tokyo, JP); Atsunobu Masuno (Tokyo, JP); Kohei Yoshimoto (Kawasaki, JP); Motoi Ueda (Naka, JP); Hiroshi Yamamoto (Yamato, JP); Tatsunori Kawashima (Sagamihara, JP)
Assignees: THE UNIVERSITY OF TOKYO; NIKON CORPORATION
C03C3/12C03C3/062C03C3/068C03C3/15C03C3/155C03C3/253G02B1/00
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Quick Facts
Patent No.
US 12,319,616
App. No.
17/563,760
Granted
Jun 3, 2025
Kind
B2
Abstract

Provided is optical glass containing, in terms of mol % of cations: 10 to 60% of a La 3+ component; more than 0% and up to 75% of a Ga 3+ component; and 5 to 75% of a Nb 5+ component, in which a total amount of the La 3+ component, Ga 3+ component, and Nb 5+ component is 60 to 100%.

Claims (51)

1. Optical glass comprising:

10 mol % to 60 mol % of a La 3+ in terms of mol % of cations;

10 mol % or more and up to 75 mol % of a Ga 3+ in terms of mol % of cations; and

at least one selected from a group consisting of Nb 5+ , Ti 4+ , and Ta 5+ .

2. The optical glass according to claim 1 , further comprising:

0 mol % to 75 mol % of a Nb 5+ in terms of mol % of cations;

0 mol % to 30 mol % of a Ti 4+ in terms of mol % of cations; and

0 mol % to 30 mol % of a Ta 5+ in terms of mol % of cations.

3. The optical glass according to claim 1 , further comprising:

5 mol % to 60 mol % of a Nb 5+ in terms of mol % of cations;

0 mol % to 20 mol % of a Ti 4+ in terms of mol % of cations; and

5 mol % to 25 mol % of a Ta 5+ in terms of mol % of cations.

4. The optical glass according to claim 3 , further comprising:

10 mol % to 20 mol % of a Ti 4+ in terms of mol % of cations.

5. The optical glass according to claim 1 , further comprising:

10 mol % to 50 mol % of a Nb 5+ in terms of mol % of cations;

0 mol % to 10 mol % of a Ti 4+ in terms of mol % of cations; and

10 mol % to 20 mol % of a Ta 5+ in terms of mol % of cations.

6. The optical glass according to claim 1 , further comprising at least one selected from a group consisting of Zr 4+ , Hf 4+ , W 6+ , Al 3+ , B 3+ , Si 4+ , Ge 4+ , Zn 2+ , Y 3+ , Gd 3+ , Lu 3+ , Mg 2+ , Ca 2+ , Sr 2+ , and Ba 2+ .

7. The optical glass according to claim 6 , further comprising:

0 mol % to 30 mol % of a B 3+ in terms of mol % of cations;

0 mol % to 20 mol % of a Si 4+ in terms of mol % of cations; and

0 mol % to 20 mol % of a Ge 4+ in terms of mol % of cations.

8. The optical glass according to claim 7 , further comprising:

0 mol % to 10 mol % of a B 3+ in terms of mol % of cations;

0 mol % to 10 mol % of a Si 4+ in terms of mol % of cations; and

0 mol % to 10 mol % of a Ge 4+ in terms of mol % of cations.

9. The optical glass according to claim 7 , wherein the total content of the B 3+ , the Si 4+ , and the Ge 4+ (B 3+ +Si 4+ +Ge 4+ ) is 0 mol % to 30 mol %, in terms of mol % of cations.

10. The optical glass according to claim 9 , wherein the total content of the B 3+ , the Si 4+ , and the Ge 4+ (B 3+ +Si 4+ +Ge 4+ ) is 0 mol %.

11. The optical glass according to claim 6 , further comprising:

0 mol % to 30 mol % of a Zr 4+ in terms of mol % of cations;

0 mol % to 30 mol % of a Hf 4+ in terms of mol % of cations;

0 mol % to 20 mol % of a W 6+ in terms of mol % of cations;

0 mol % to 30 mol % of a Al 3+ in terms of mol % of cations; and

0 mol % to 20 mol % of a Zn 2+ in terms of mol % of cations.

12. The optical glass according to claim 11 , further comprising:

5 mol % to 20 mol % of a Zr 4+ in terms of mol % of cations;

5 mol % to 20 mol % of a Hf 4+ in terms of mol % of cations;

0 mol % to 10 mol % of a W 6+ in terms of mol % of cations;

0 mol % to 15 mol % of a Al 30 in terms of mol % of cations; and

0 mol % to 10 mol % of a Zn 2+ in terms of mol % of cations.

13. The optical glass according to claim 6 , wherein a total content of a Ln 3+ (representing one or more of Ln=Y, Gd, and Lu) (Y 3+ +Gd 3+ +Lu 3+ ) is 0 mol % to 30 mol %, and a total mol % of an R 2+ (representing one or more of R=Mg, Ca, Sr, and Ba) (Mg 2+ +Ca 2+ +Sr 2+ +Ba 2+ ) is 0 mol % to 20 mol %, in terms of mol % of cations.

14. The optical glass according to claim 13 , wherein a total content of a Ln 3+ (representing one or more of Ln=Y, Gd, and Lu) (Y 3+ +Gd 3+ +Lu 3+ ) is 0 mol % to 20 mol %, and a total content of an R 2+ (representing one or more of R=Mg, Ca, Sr, and Ba) (Mg 2+ +Ca 2+ +Sr 2+ +Ba 2+ ) is 0 mol % to 10 mol %, in terms of mol % of cations.

15. The optical glass according to claim 1 , wherein a refractive index (n d ) in a d-line is 1.85 to 2.25.

16. The optical glass according to claim 1 , wherein an Abbe number (ν d ) is 19 to 37.

17. The optical glass according to claim 1 , wherein a wavelength (UVλ 5 ) at which an ultraviolet transmittance value including a surface reflection loss becomes 5% per a thickness of 1 mm is 370 nm or less.

18. The optical glass according to claim 1 , wherein a wavelength (IRλ 5 ) at which an infrared transmittance value including a surface reflection loss becomes 5% per a thickness of 1 mm is 6 μm or more.

19. An optical element comprising the optical glass according to claim 1 .

20. An objective lens comprising the optical element according to claim 19 .

21. A lens barrel comprising the optical element according to claim 19 .

22. An optical apparatus comprising the optical element according to claim 19 .

Priority Claims (1)
JP 2016-165366 · Aug 26, 2016 · national
Continuity (3)
Continuation 16283349 · Feb 22, 2019
Continuation PCTJP2017026520 · Jul 21, 2017
Related Publication 20220119302A1 · Apr 21, 2022
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