Polymer-based nanocomposite and optical filter based thereon
The present disclosure discloses a polymer-based nanocomposite and an optical filter based thereon, wherein components of the polymer-based nanocomposite have a polymer matrix and a semiconductor material; and the polymer-based nanocomposite has an average light transmittance of greater than 90% in at least one light-transmitting wavelength range and a light transmittance of less than 1% in at least one cut-off wavelength range, wherein the semiconductor material is a non-radiative recombination-type perovskite material.
1. A polymer-based nanocomposite, wherein components of the polymer-based nanocomposite comprise a polymer matrix and only one perovskite material having non-radiative recombination property; and
wherein the polymer-based nanocomposite has an average light transmittance of greater than 90% in at least one light-transmitting wavelength range and a light transmittance of less than 1% in at least one cut-off wavelength range,
wherein the perovskite material has a size of 2-100 nm and has general chemical formula of A 3 B 2 X 9 , and
wherein A is one of CH 3 NH3, CH(NH)NH 3 , and Cs; B is one of Ag, Sb, Bi, In, Al, Ti, and Sn; and X is one of halogen elements.
2. The polymer-based nanocomposite according to claim 1 , wherein the polymer-based nanocomposite has an average light transmittance of greater than 90% in at least one light-transmitting wavelength range and a light transmittance of less than 1% in at least one cut-off wavelength range in a range of 3000-200 nm.
3. The polymer-based nanocomposite according to claim 1 , wherein a polymer of the polymer matrix is selected from at least one of polyvinylidene fluoride, polyvinylidene chloride, polymethyl methacrylate, polyvinyl acetate, cellulose acetate, polysulfone, polyamide, polyimide, polycarbonate, polystyrene, polyvinyl chloride, polyvinyl alcohol, transparent ABS plastics, polyacrylonitrile, polyolefin elastomers, thermoplastic polyurethane, and polyvinyl carbazole.
4. The polymer-based nanocomposite according to claim 1 ,
the perovskite material has a solid content of 2 wt %-50 wt %.
5. The polymer-based nanocomposite according to claim 1 , wherein the polymer-based nanocomposite further comprises an additive component;
wherein the additive component is selected from at least one of poly(p-phenylenevinylene), poly(3-hexylthiophene), [6,6]-phenyl C61 butyric acid methyl ester, polyvinylcarbazole, perylene diimide, fullerene, and poly[2-methoxy-5-[(3,7-dimethyloctyloxy)-1,4-phenylene]-1,2-vinylene-diyl]; and
wherein the additive component in the polymer-based nanocomposite has a content of 1 wt %-20 wt %.
6. An optical filter based on the polymer-based nanocomposite according to claim 1 , wherein production steps of the optical filter comprise at least:
a) dissolving the polymer matrix and a precursor of the perovskite material in organic solvents, respectively, to obtain a polymer gum solution and a precursor solution;
b) adding the precursor solution to the polymer gum solution followed by uniformly mixing, to obtain a mixed solution;
c) coating the mixed solution obtained in step b) on a substrate, to form a film with a wet film thickness of 50-1000 μm; and
d) subjecting the substrate coated with the wet film to drying treatment followed by heat treatment at 20-100° C. for 0.17-1 hour, to obtain the optical filter.
7. The optical filter according to claim 6 , wherein the organic solvents in step a) are selected from at least one of N,N-dimethylformamide, dimethylacetamide, dimethyl sulfoxide, ethyl acetate, N-methylpyrrolidone, tetrahydrofuran, toluene, chloroform, and acetone;
wherein the precursor in step a) comprises a precursor I and a precursor II, wherein the precursor I is selected from at least one of methylamine halide, formamidine halide, and cesium halide, the precursor II is selected from at least one of bismuth halide, indium halide, antimony halide, silver halide, and titanium halide, and a molar mixing ratio of the precursor I to the precursor II is in a range of 1:2-3:1;
wherein the substrate in step c) is selected from any of a glass plate and PET; and
wherein the heat treatment in step d) is annealing treatment.
8. The optical filter according to claim 6 , wherein the optical filter is a long-wave-pass optical filter or a double-wave-pass optical filter;
wherein the long-wave-pass optical filter has an optical filtering waveband range in a range of 3000 nm-250 nm;
wherein the double-wave-pass optical filter has an optical filtering waveband range including two non-overlapping waveband ranges in a range of 3000 nm-250 nm; and
wherein the long-wave-pass optical filter and the double-wave-pass optical filter have a light transmittance in a range of 80%-92% in a light-transmitting waveband range.
9. A narrowband optical filter, comprising the optical filter of claim 6 ,
wherein the narrowband optical filter has an optical filtering waveband range in a range of 3000 nm-250 nm and a light transmittance in a range of 80%-92% in a light-transmitting waveband range.
10. The narrowband optical filter according to claim 9 , wherein the narrowband optical filter further comprises at least one of a short-wave-pass optical filter and a dye-doped polymer.