Electrochemical systems, methods, and devices using stacked electrode assemblies with in-stack sensor arrays
Presented are electrochemical devices with in-stack sensor arrays, methods for making/using such electrochemical devices, and lithium-class battery cells with stacked electrode assemblies having in-stack sensor arrays. An electrochemical device includes a device housing that stores an electrolyte composition for conducting ions. An electrode stack, which is located inside the device housing in electrochemical contact with the electrolyte, includes at least two working electrodes. An electrically insulating and ionically transmissive separator is interposed between each neighboring pair of working electrodes. A reference electrode is attached to one side of the separator and connected to multiple electrical sensing devices. Multiple electrical sensing leads are attached to another side of the separator, opposite the reference electrode, with each abutting a discrete region of a working electrode and each connecting to one of the sensing devices to transmit thereto electrical signals indicative of an electrical characteristic (e.g., voltage) of the discrete region it contacts.
1. An electrochemical device, comprising:
a device housing;
an electrolyte located inside the device housing and configured to conduct ions;
an electrode stack located inside the device housing and including first and second working electrodes in electrochemical contact with the electrolyte;
an electrically insulating separator interposed between the first and second working electrodes, the separator being configured to transmit therethrough the ions of the electrolyte;
a plurality of electrical sensing devices configured to detect electrode characteristics;
a reference electrode mounted onto a first face of the separator, abutting the second working electrode, and electrically connected to the plurality of electrical sensing devices; and
a plurality of electrical sensing leads each abutting a respective discrete region of the first working electrode, each mounted onto a second face of the separator, opposite the first face, and each electrically connected to a respective one of the electrical sensing devices to transmit thereto an electrical signal indicative of an electrical characteristic of the discrete region to which it abuts.
2. The electrochemical device of claim 1 , wherein the electrode stack includes a plurality of the first working electrodes interleaved with a plurality of the second working electrodes, and wherein the separator includes a plurality of electrically insulating separators each sandwiched between a respective neighboring pair of the first and second working electrodes.
3. The electrochemical device of claim 2 , wherein the electrical sensing leads all abut a common one of the first working electrodes and all attach to a common one of the separators.
4. The electrochemical device of claim 2 , wherein a first subset of the electrical sensing leads abuts a first one of the first working electrodes and attaches to a first one of the separators, and a second subset of the electrical sensing leads abuts a second one of the first working electrodes and attaches to a second one of the separators.
5. The electrochemical device of claim 4 , wherein both the first and second subsets of the electrical sensing leads electrically connect to the reference electrode and cooperate therewith to transmit electrical signals to the electrical sensing devices.
6. The electrochemical device of claim 1 , wherein a first of the electrical sensing leads is electrically connected in series with the reference electrode and a first of the electrical sensing devices, and a second of the electrical sensing leads is electrically connected in series with the reference electrode and a second of the electrical sensing devices.
7. The electrochemical device of claim 1 , further comprising a reference current collector sandwiched between the reference electrode and the separator and electrically connecting the reference electrode to the plurality of electrical sensing devices.
8. The electrochemical device of claim 7 , wherein the reference current collector is a single-piece construction formed with an electrically conductive material and having a collector surface area smaller than a reference surface area of the reference electrode.
9. The electrochemical device of claim 1 , wherein the reference electrode is a single-piece construction formed with an electroactive material and having a reference surface area substantially coterminous with a separator surface area of the first side of the separator.
10. The electrochemical device of claim 1 , wherein the reference electrode is formed with an electrically conductive and ionically permeable electrode film with a reference electrode thickness of about 0.02 micrometers (μm) to about 5.0 μm.
11. The electrochemical device of claim 1 , wherein each of the electrical sensing leads is formed with an electrically conductive and ionically permeable pad with a lead thickness of approximately 0.01 micrometers (μm) to about 1.0 μm.
12. The electrochemical device of claim 1 , further comprising a plurality of electrical wires or traces fixed to the second face of the separator and each electrically connecting a respective one of the electrical sensing leads to a respective one of the electrical sensing devices.
13. The electrochemical device of claim 1 , wherein the device housing includes a flexible pouch-type outer housing, a rigid prismatic-type outer housing, or a rigid cylindrical-type outer housing.
14. An electric-drive vehicle, comprising:
a vehicle body;
a plurality of road wheels attached to the vehicle body;
a traction motor attached to the vehicle body and operable to drive one or more of the road wheels to thereby propel the electric-drive vehicle; and
a traction battery pack attached to the vehicle body and operable to power the traction motor, the traction battery pack containing a plurality of lithium-class battery cells, each of the lithium-class battery cells including:
a battery housing;
an electrolyte located inside the battery housing and configured to conduct ions;
an electrode stack located inside the battery housing in electrochemical contact with the electrolyte, the electrode stack including a plurality of first working electrodes interleaved with a plurality of second working electrodes;
a plurality of electrically insulating separators each interposed between a respective pair of the first and second working electrodes and each being configured to transmit therethrough the ions of the electrolyte;
a plurality of electrical voltage sensing devices configured to detect electrode voltage;
a reference electrode mounted onto a first major face of one of the separators and physically contacting one of the second working electrodes, the reference electrode being formed with an electrically conductive and ionically permeable electrode film;
a reference current collector sandwiched between the reference electrode and the one of the separators, the reference current collector electrically connecting the reference electrode to the plurality of electrical voltage sensing devices; and
a plurality of electrical sensing leads each physically contacting a respective discrete region of one of the first working electrodes, each mounted onto a second major face of the one of the separators, opposite the first major face, and each electrically connected to a respective one of the voltage sensing devices to transmit thereto an electrical signal indicative of a real-time voltage of the discrete region to which it abuts, the electrical sensing leads each being formed with an electrically conductive and ionically permeable pad.
15. A method of assembling an electrochemical device, the method comprising:
receiving a device housing of the electrochemical device;
locating an electrolyte inside the device housing, the electrolyte being configured to conduct ions;
locating an electrode stack inside the device housing in electrochemical contact with the electrolyte, the electrode stack including first and second working electrodes;
locating an electrically insulating separator between the first and second working electrodes, the separator being configured to transmit therethrough the ions of the electrolyte;
receiving a plurality of electrical sensing devices configured to detect electrode characteristics;
attaching a reference electrode to a first face of the separator such that the reference electrode abuts the second working electrode;
connecting the reference electrode to the plurality of electrical sensing devices;
attaching a plurality of electrical sensing leads to a second face of the separator, opposite the first face, such that each of the electrical sensing leads abuts a respective discrete region of the first working electrode; and
connecting each of the electrical sensing leads to a respective one of the sensing devices to transmit thereto an electrical signal indicative of an electrical characteristic of the discrete region to which it abuts.
16. The method of claim 15 , further comprising locating a reference current collector between the reference electrode and the separator, the reference current collector electrically connecting the reference electrode to the plurality of electrical sensing devices.
17. The method of claim 16 , wherein the reference current collector is a single-piece construction formed with an electrically conductive material and having a collector surface area smaller than a reference surface area of the reference electrode.
18. The method of claim 15 , wherein the reference electrode is a single-piece construction formed with an electroactive material and having a reference surface area substantially coterminous with a separator surface area of the first side of the separator.
19. The method of claim 15 , wherein each of the electrical sensing leads is formed with an electrically conductive and ionically permeable pad with a lead thickness of approximately 0.01 micrometers (μm) to about 1.0 μm.
20. The method of claim 15 , further comprising fixing a plurality of electrical wires or traces to the second face of the separator, each of the electrical wires or traces electrically connecting a respective one of the electrical sensing leads to a respective one of the sensing devices.