IP Library Granted Patent US 12,351,775
Granted Patent B2
US 12,351,775 · App. 17/663,246 · Granted Jul 8, 2025

Neutralizing instrument reprocessing

Inventors: Wendy Lo (Saint Paul, MN); Michael S. Rischmiller (Saint Paul, MN); Erik C. Olson (Saint Paul, MN)
Assignee: ECOLAB USA INC.
C11D1/72A01N37/36A01P1/00C11D3/2086C11D17/0008C23C22/48C23G1/02C11D2111/16
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Quick Facts
Patent No.
US 12,351,775
App. No.
17/663,246
Granted
Jul 8, 2025
Kind
B2
Abstract

A neutralizer, destainer/descaling, and passivating composition and methods of using the same on metal surfaces are disclosed. The compositions are particularly well suited for the treatment of health care surfaces and other hard surfaces in need of treatment. In particular, the neutralizer, destainer/descaling, and passivating composition is an acid-based composition for use in instrument reprocessing.

Claims (12)

1. A neutralizer, destainer, and passivating composition comprising:

from about 40 wt-% to 75 wt-% of citric acid and an additional weak acid having a pKa greater than about 2.5, wherein the additional weak acid comprises from about 0.001 wt-% to 10 wt-%;

an alcohol alkoxylated nonionic surfactant according to the formula: R 1 —O—(EO) x (PO) y -Π wherein R is a straight-chain C 10 -C 16 alkyl, and wherein x is from 4 to 8, and wherein y is from 2 to 5; and

water.

2. The composition of claim 1 , wherein the additional weak acid comprises lactic acid, oxalic acid, tartaric acid, malic acid, gluconic acid, or a combination thereof.

3. The composition of claim 1 , wherein a ratio of the additional weak acid and the citric acid on a weight percent basis is (a) from about 1:20 to about 1:90, (b) from about 20:1 to about 90:1, or (c) from about 1:60 to about 60:1.

4. The composition of claim 3 , wherein the additional weak acid is lactic acid.

5. The composition of claim 1 , further comprising an additional alcohol alkoxylated nonionic surfactant, wherein the additional alcohol alkoxylate is branched and has both ethylene oxide and propylene oxide groups.

6. The composition of claim 5 , wherein the branched alcohol alkoxylated nonionic surfactant is according to the formula: 2-ethylhexyl (PO) m (EO) n, wherein m is from 3 to 5, and n is from 5 to 8.

7. The composition of claim 1 , wherein the composition is a liquid concentrate that is diluted to form a use solution prior to use.

8. The composition of claim 7 , wherein the additional weak acid and citric acid is present in the use solution in an amount of from about 700 ppm to about 12,000 ppm, and the alcohol alkoxylated nonionic surfactant is present in the use solution in an amount of from about 25 ppm to about 500 ppm, and wherein the use solution has a pH of about 7 or less.

9. The composition of claim 1 , wherein the composition achieves a pass rating under a passivation test according to ASTM A380/A380M-17 and/or ASTM A967/A967M-17 and/or does not cause any discoloration to a treated surface.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 13, 2022
From: LO, WENDY; RISCHMILLER, MICHAEL S.; OLSON, ERIK C.
To: ECOLAB USA INC.
Reel/Frame 059900/0310 →
Continuity (3)
Provisional Application 63262888 · Oct 22, 2021
Provisional Application 63201817 · May 14, 2021
Related Publication 20220364018A1 · Nov 17, 2022
References Cited (163)
US 3909437A · Alexander et al. · 1975 [cited by applicant]
US 4256601A · Sobata et al. · 1981 [cited by applicant]
US 4311618A · Schäfer-Burkhard · 1982 [cited by applicant]
US 5489531A · Benson · 1996 [cited by applicant]
US 5705472A · Hayes et al. · 1998 [cited by applicant]
US 5766684A · Shah et al. · 1998 [cited by applicant]
US 6096701A · Mondin et al. · 2000 [cited by applicant]
US 6239092B1 · Papasso et al. · 2001 [cited by applicant]
US 6703358B1 · Aubay et al. · 2004 [cited by applicant]
US 6767410B2 · Aubay et al. · 2004 [cited by applicant]
US 6794346B2 · Wick et al. · 2004 [cited by applicant]
US 6849586B2 · Avery et al. · 2005 [cited by applicant]
US 7144846B2 · Keller et al. · 2006 [cited by applicant]
US 7214651B2 · Mohr et al. · 2007 [cited by applicant]
US 7341983B2 · Pedersen et al. · 2008 [cited by applicant]
US 7368417B2 · Gaudreault · 2008 [cited by applicant]
US 7635672B1 · Dastbaz et al. · 2009 [cited by applicant]
US 7648583B2 · McRae et al. · 2010 [cited by applicant]
US 7745383B2 · Dreja et al. · 2010 [cited by applicant]
US 8198227B2 · Cermenati et al. · 2012 [cited by applicant]
US 8293174B2 · Kaiser et al. · 2012 [cited by applicant]
US RE44058E · Aubay et al. · 2013 [cited by applicant]
US 8512484B2 · Laudenklos et al. · 2013 [cited by applicant]
US 8574370B2 · Laffitte et al. · 2013 [cited by applicant]
US 8815788B2 · Osborn et al. · 2014 [cited by applicant]
US 8921295B2 · Kneipp et al. · 2014 [cited by applicant]
US 9006286B2 · Kiesel et al. · 2015 [cited by applicant]
US 9486892B2 · Onishi et al. · 2016 [cited by applicant]
US 9546346B2 · Bjelopavlic et al. · 2017 [cited by applicant]
US 11026422B2 · Hanson et al. · 2021 [cited by applicant]
US 11129385B2 · Alderson · 2021 [cited by applicant]
US 20030109395A1 · Neumiller · 2003 [cited by applicant]
US 20050130873A1 · Cheung et al. · 2005 [cited by applicant]
US 20080004197A1 · Kneer · 2008 [cited by applicant]
US 20080011323A1 · Fischer · 2008 [cited by examiner]
US 20080096784A1 · Barg et al. · 2008 [cited by applicant]
US 20120142577A1 · Sun et al. · 2012 [cited by applicant]
US 20130079408A1 · Ho · 2013 [cited by applicant]
US 20130157921A1 · Marin et al. · 2013 [cited by applicant]
US 20130303430A1 · Reinoso Garcia et al. · 2013 [cited by applicant]
US 20140039051A1 · Strodtholz et al. · 2014 [cited by applicant]
US 20190169541A1 · Hodge et al. · 2019 [cited by applicant]
US 20190330568A1 · Ceulemans et al. · 2019 [cited by applicant]
US 20200345005A1 · Tinwala et al. · 2020 [cited by applicant]
US 20200367492A1 · Budhian et al. · 2020 [cited by applicant]
US 20210340464A1 · Anderson et al. · 2021 [cited by applicant]
AU 2000059890A1 · 2001 [cited by applicant]
AU 2000064493A1 · 2001 [cited by applicant]
AU 2001253046B2 · 2001 [cited by applicant]
AU 2003259326B2 · 2004 [cited by applicant]
AU 2008294615B2 · 2009 [cited by applicant]
BE 1027322B1 · 2021 [cited by applicant]
BR 112012009188A2 · 2016 [cited by applicant]
BR PI0911361A2 · 2016 [cited by applicant]
BR PI0820350B1 · 2017 [cited by applicant]
BR 112015028651A2 · 2017 [cited by applicant]
BR 112012001605A2 · 2019 [cited by applicant]
BR 112013011859B1 · 2020 [cited by applicant]
CA 2108898C · 1992 [cited by applicant]
CA 2126626A1 · 1994 [cited by applicant]
CA 2235484C · 1997 [cited by applicant]
CA 2331582C · 1999 [cited by applicant]
CA 2396742C · 2001 [cited by applicant]
CA 2397496C · 2001 [cited by applicant]
CA 2515399C · 2004 [cited by applicant]
CA 2554746C · 2005 [cited by applicant]
CA 2719335C · 2009 [cited by applicant]
CA 2782407C · 2011 [cited by applicant]
CA 2727123C · 2017 [cited by applicant]
CN 1132802A · 1996 [cited by applicant]
CN 1137977C · 2004 [cited by applicant]
CN 1478923A · 2004 [cited by applicant]
CN 101654599A · 2010 [cited by applicant]
CN 102002722A · 2011 [cited by applicant]
CN 103882443A · 2014 [cited by applicant]
CN 104313607A · 2015 [cited by applicant]
CN 104629945A · 2015 [cited by applicant]
CN 104845745A · 2015 [cited by applicant]
CN 102337080B · 2016 [cited by applicant]
CN 105733822A · 2016 [cited by applicant]
CN 104947113B · 2017 [cited by applicant]
CN 109072132A · 2018 [cited by applicant]
CN 104508108B · 2019 [cited by applicant]
CN 109487280A · 2019 [cited by applicant]
CN 109536969A · 2019 [cited by applicant]
CN 112105265A · 2020 [cited by applicant]
CN 112203513A · 2021 [cited by applicant]
DE 102004019022A1 · 2005 [cited by applicant]
DE 4210364B4 · 2006 [cited by applicant]
DE 102007014875A1 · 2008 [cited by applicant]
DE 102007016201A1 · 2008 [cited by applicant]
DE 102009001559A1 · 2009 [cited by applicant]
EP 0592906A1 · 1994 [cited by applicant]
EP 1009781A1 · 2000 [cited by applicant]
EP 1466961A1 · 2004 [cited by applicant]
EP 1706472A2 · 2005 [cited by applicant]
EP 1180133B1 · 2008 [cited by applicant]
EP 1899449B1 · 2009 [cited by applicant]
EP 1904613B1 · 2009 [cited by applicant]
EP 2184620A1 · 2010 [cited by applicant]
EP 1196528B1 · 2010 [cited by applicant]
EP 2221357A1 · 2010 [cited by applicant]
EP 1781717B1 · 2012 [cited by applicant]
EP 2231844B1 · 2015 [cited by applicant]
EP 2245213B1 · 2016 [cited by applicant]
EP 2586855B1 · 2016 [cited by applicant]
EP 2152845B1 · 2017 [cited by applicant]
EP 2304008B1 · 2017 [cited by applicant]
EP 3418362A1 · 2018 [cited by examiner]
EP 3337885B1 · 2020 [cited by applicant]
EP 2617867B1 · 2022 [cited by applicant]
FR 2520373A1 · 1983 [cited by applicant]
GB 2429015A · 2007 [cited by applicant]
HK 1189618B · 2020 [cited by applicant]
HK 1189619B · 2020 [cited by applicant]
IN 228599B · 2005 [cited by applicant]
IN 200400447P4 · 2005 [cited by applicant]
IN 231322B · 2007 [cited by applicant]
IN 200502340P4 · 2007 [cited by applicant]
IN 226695B · 2007 [cited by applicant]
IN 200502342P4 · 2007 [cited by applicant]
IN 200200688P1 · 2010 [cited by applicant]
IN 201200440P4 · 2013 [cited by applicant]
IN 201203640P4 · 2013 [cited by applicant]
IN 294414B · 2014 [cited by applicant]
IN 330195B · 2014 [cited by applicant]
IN 201304408P1 · 2014 [cited by applicant]
IN 312797B · 2015 [cited by applicant]
IN 351216B · 2018 [cited by applicant]
IN 201847019472A · 2018 [cited by applicant]
IN 201941011280A · 2020 [cited by applicant]
IN 202048044958A · 2020 [cited by applicant]
JP S5892499A · 1983 [cited by applicant]
JP 1135987A · 1999 [cited by applicant]
JP 2003516751A · 2003 [cited by applicant]
JP 3417703B2 · 2003 [cited by applicant]
JP 2003534396A · 2003 [cited by applicant]
JP 4942981B2 · 2012 [cited by applicant]
JP 5514722B2 · 2014 [cited by applicant]
KR 2020082374A · 2020 [cited by applicant]
NZ 532144A · 2006 [cited by applicant]
NZ 585930A · 2011 [cited by applicant]
PL 191444B1 · 2006 [cited by applicant]
RU 2013149225A · 2015 [cited by applicant]
TW 200630471A · 2006 [cited by applicant]
TW 200941582A · 2009 [cited by applicant]
TW 201512392A · 2015 [cited by applicant]
TW I503878B · 2015 [cited by applicant]
WO 0063337A1 · 2000 [cited by applicant]
WO 0121753A1 · 2001 [cited by applicant]
WO 0157174A1 · 2001 [cited by applicant]
WO 03020863A1 · 2003 [cited by applicant]
WO 03031550A1 · 2003 [cited by applicant]
WO 2005017083A1 · 2005 [cited by applicant]
WO 2006114243A1 · 2006 [cited by applicant]
WO 2007001593A1 · 2007 [cited by applicant]
WO WO2007098831A1 · 2007 [cited by examiner]
WO 2008116509A1 · 2008 [cited by applicant]
WO 2009092817A1 · 2009 [cited by applicant]
WO 2018075089A1 · 2018 [cited by applicant]
WO 2020018356A1 · 2020 [cited by applicant]
International Search Report and Written Opinion in PCT/US2022/029127, mailed Sep. 8, 2022, 8 pages. [cited by applicant]
International Search Report and Written Opinion in PCT/US2022/029127, 8 pages, mailed Sep. 8, 2022. [cited by applicant]