Resin-extended rubber and process for preparing
View Patent ↗Disclosed herein are processes for preparing a resin-extended rubber by mixing at least one thermoplastic resin with a resin-rubber-solvent cement comprising at least one conjugated diene monomer-containing rubber and the resin-extended rubber resulting from such processes. Also disclosed is a resin-extended rubber-solvent-cement comprising at least one conjugated diene monomer-containing rubber, at least one non-polar solvent, and at least one thermoplastic resin as well as a rubber composition comprising a resin-extended rubber.
1. A rubber composition comprising:
a. resin-extended rubber comprising n parts of rubber including at least one conjugated diene monomer-containing rubber and up to 100 phr of at least one thermoplastic resin, wherein n is an integer from 10 to 100;
wherein the resin-extended rubber is polymerized in at least one non-polar solvent, wherein the non-polar solvent is selected from the group consisting of: alkanes having from 4 to 9 carbon atoms, cycloalkanes or alkyl cycloalkanes having from 5 to 10 carbon atoms, or aromatics and alkyl substituted aromatics having from 6 to 12 carbon atoms;
b. optionally at least one additional rubber in an amount of 100-n parts;
c. at least one reinforcing filler in a total amount of 10-200 phr; and
d. a cure package;
wherein the at least one thermoplastic resin is selected from the group consisting of a terpene resin, a C5 containing resin, or both;
wherein the at least one conjugated diene monomer-containing rubber is produced by an anionic polymerization process that utilizes a randomizer.
2. The rubber composition of claim 1 , wherein when the thermoplastic resin is added to rubber to form the resin-extended rubber a second non-polar solvent is present.
3. The rubber composition of claim 2 , wherein the second non-polar solvent is the same as the non-polar solvent.
4. The rubber composition of claim 1 , wherein the resin-extended rubber is a solution synthesized styrene-butadiene rubber, the at least one additional rubber is present and is natural rubber or polyisoprene, the at least one reinforcing filler comprises silica and carbon black; and silica is present in an amount of about 80 to about 200 phr.
5. The rubber composition of claim 1 , wherein the at least one thermoplastic resin is present in an amount of 80 to 100 phr.
6. The rubber composition of claim 1 , wherein the non-polar solvent is exclusive of a solvent in any amount that causes coagulation of the conjugated diene monomer-containing rubber.
7. The rubber composition of claim 1 , wherein the reinforcing filler comprises silica, carbon black, or both silica and carbon black.
8. The rubber composition of claim 1 , wherein
the at least one conjugated diene monomer-containing rubber comprises at least one of styrene-butadiene copolymer, polybutadiene, styrene-isoprene rubber, styrene-butadiene-isoprene rubber, natural rubber, or polyisoprene.
9. The rubber composition of claim 1 , wherein the at least one thermoplastic resin has a Mn of 400 to 5000 grams/mole.
10. The rubber composition of claim 1 , wherein the at least one thermoplastic resin is a solid at 25° C.
11. The rubber composition of claim 1 , wherein the at least one thermoplastic resin has a Tg of at least 25° C.
12. The rubber composition of claim 1 , wherein the at least one thermoplastic resin meets each of the following:
a. has a Mn of 400 to 5000 grams/mole;
b. is a solid at 25° C.;
c. has a Tg of at least 25° C.
13. The rubber composition of claim 1 , wherein the at least one reinforcing filler comprises silica and carbon black; and silica is present in an amount of about 50 to about 200 phr.
14. The rubber composition of claim 1 , wherein the thermoplastic resin has a softening point of at least 70° C.
15. The rubber composition of claim 1 , wherein the thermoplastic resin is present in an amount of 40 to 90 phr.
16. The rubber composition of claim 1 , further comprising at least one petroleum oil or plant oil.
17. The rubber composition of claim 1 , wherein the C5 containing resin is present and further comprises a C9 fraction.
18. The rubber composition of claim 1 , wherein the C5 containing resin is present, and the C5 containing resin is selected from the group consisting of: C5 fraction/C9 fraction copolymer resin, C5 fraction/vinylaromatic copolymer resin, and partially or fully hydrogenated C5 resin.
19. The rubber composition of claim 1 , wherein the terpene resin is present, and the terpene resin is selected from the group consisting of: polylimonene, alpha-pinene resin, beta-pinene resin, limonene resins, beta-phellandrene, delta-3-carene, and delta-2-carene, fully or partially hydrogenated terpene resin, DCPD/terpene copolymer resin, and CPD/terpene copolymer resin, terpene/phenol copolymer resin, terpene/vinylaromatic copolymer resin.