Granted Patent B2

US 12,382,778 · App. 17/626,458 · Granted Aug 5, 2025

Inventors: Lixia Qiu (Beijing, CN); Lei Chen (Beijing, CN); Congcong Jia (Beijing, CN)

Assignee: BOE Technology Group Co., Ltd.

H10K50/11H10K50/12H10K71/00H10K50/18H10K59/10H10K85/626H10K2101/30H10K2101/40H10K2102/351

Abstract

Claims (23)

1. An organic electroluminescent device, comprising: an anode and a cathode arranged opposite to each other, an organic electroluminescent layer between the anode and the cathode, and an electron blocking layer between the anode and the organic electroluminescent layer; wherein

the organic electroluminescent layer comprises: a first sub luminescent layer, and a second sub luminescent layer between the cathode and the first sub luminescent layer; and

the first sub luminescent layer is composed of a luminescent host material, a luminescent object material and a hole trapping material, and the second sub luminescent layer is composed of the luminescent host material and the luminescent object material;

wherein a hole mobility of the hole trapping material is larger than a hole mobility of the luminescent host material.

2. The organic electroluminescent device according to claim 1 , wherein a lowest unoccupied molecular orbital of the hole trapping material is higher than a lowest unoccupied molecular orbital of the luminescent host material and lower than a lowest unoccupied molecular orbital of the electron blocking layer.

3. The organic electroluminescent device according to claim 2 , wherein a difference between the lowest unoccupied molecular orbital of the hole trapping material and the lowest unoccupied molecular orbital of the luminescent host material is larger than 0 eV, and a difference between the lowest unoccupied molecular orbital of the electron blocking layer and the lowest unoccupied molecular orbital of the luminescent host material is larger than 0.1 eV.

4. The organic electroluminescent device according to claim 1 , wherein a highest occupied molecular orbital of the hole trapping material is higher than a highest occupied molecular orbital of the luminescent host material and lower than a highest occupied molecular orbital of the luminescent object material.

5. The organic electroluminescent device according to claim 4 , a difference between the highest occupied molecular orbital of the hole trapping material and the highest occupied molecular orbital of the luminescent host material is larger than 0 eV, and a difference between the highest occupied molecular orbital of the luminescent object material and the highest occupied molecular orbital of the luminescent host material is larger than 0 eV and smaller than 0.2 eV.

6. The organic electroluminescent device according to claim 1 , wherein a thickness of the first sub luminescent layer is smaller than ½ of or equal to ½ of a thickness of the organic electroluminescent layer.

7. The organic electroluminescent device according to claim 6 , wherein the thickness of the first sub luminescent layer is 5 nm to 20 nm.

8. The organic electroluminescent device according to claim 1 , wherein in the first sub luminescent layer, a mass ratio of the hole trapping material to the luminescent host material is 3:7 to 7:3.

9. The organic electroluminescent device according to claim 1 , wherein the hole trapping material is selected from one or any combination of AND, ADNP, An-1 or An-2:

10. The organic electroluminescent device according to claim 1 , wherein the luminescent host material is selected from one or any combination of 4,4′-bis(2,2-distyryl)-1,1′-biphenyl, 4,4′,4″-tris(carbazol-9-yl) triphenylamine, N,N′-dimethylquinacridone, or 3-methyltriphenylamine.

11. The organic electroluminescent device according to claim 1 , wherein the luminescent object material is selected from one of 4,4′-bis(9-ethyl-3-carbazole vinyl)-1,1′-biphenyl and/or an amino-substituted distyryl aryl material.

12. The organic electroluminescent device according to claim 1 , wherein a material of the electron blocking layer is selected from 4,4-bis(9-carbazole) biphenyl and/or 9,9′-biphenyl-6-(9-phenyl-9h-carbazol-3-yl)-9h,9′h-3,3′-bicarbazole.

13. The organic electroluminescent device according to claim 1 , wherein in the first sub luminescent layer and the second sub luminescent layer, a mass ratio of the luminescent host material to the luminescent object material is 100:1 to 100:10.

14. The organic electroluminescent device according to claim 1 , wherein the organic electroluminescent layer is a blue luminescent layer.

15. A display panel, comprising: a plurality of pixel units, wherein at least part of the pixel units comprise the organic electroluminescent device according to claim 1 .

16. A display apparatus, comprising: the display panel according to claim 15 .

17. A method for manufacturing an organic electroluminescent device, comprising:

providing a base substrate with an anode;

forming, by adopting a multi-source co-evaporation, a first sub luminescent layer composed of a hole trapping material, a luminescent host material and a luminescent object material on the anode; and forming a second sub luminescent layer composed of the luminescent host material and the luminescent object material on the first sub luminescent layer, wherein the first sub luminescent layer and the second sub luminescent layer constitute an organic electroluminescent layer, and a hole mobility of the hole trapping material is larger than a hole mobility of the luminescent host material; and

forming a cathode on the second sub luminescent layer.

Assignments (1)

Priority Claims (1)

Continuity (1)

References Cited (42)