Glass strengthening molten salt and glass strengthening method using the same
Provided is a glass strengthening method including preparing a glass and strengthening the glass by providing the glass with a molten salt, wherein the molten salt has a freezing point of about 220° C. or more and less than 320° C. In addition, the molten salt includes a first salt and a second salt that are different from each other, wherein the first salt is KNO 3 , and the second salt includes at least one ion of Li + , Na + , K + , Cs + , and/or Rb + .
1. A glass strengthening method comprising:
preparing a glass;
heating the glass to a first temperature of about 350° C. to about 400° C.; and
strengthening the glass by providing the glass with a molten salt,
wherein the molten salt has a freezing point equal to or higher than about 220° C. and less than about 320° C., and
wherein the molten salt comprises KNO 3 and NaNO 3 , and a mole fraction of NaNO 3 with respect to KNO 3 and NaNO 3 is more than about 0.05 and about 0.5 or less.
2. The glass strengthening method of claim 1 , wherein the molten salt further comprises, as an additive, at least one of KOH, K 2 CO 3 , K 3 PO 4 , Al 2 (SO 4 ) 3 , Al(NO 3 ) 2 , K 2 SiO 3 , Na 2 SiO 3 , KCl, Ca(NO 3 ), and/or Mg(NO 3 ) 2 .
3. The glass strengthening method of claim 2 , wherein a mole fraction of the additive with respect to the molten salt is 0 to about 0.01.
4. The glass strengthening method of claim 1 , wherein the molten salt further comprises KOH as an additive, and a mole fraction of KOH with respect to KNO 3 , NaNO 3 , and KOH is more than 0 and about 0.001 or less.
5. The glass strengthening method of claim 1 , wherein the molten salt further comprises K 2 CO 3 as an additive, and a mole fraction of K 2 CO 3 with respect to KNO 3 , NaNO 3 , and K 2 CO 3 is more than 0 and about 0.01 or less.
6. The glass strengthening method of claim 1 , wherein the molten salt is heated to the first temperature.
7. The glass strengthening method of claim 1 , further comprising, after removing the glass from the molten salt, performing a post-heat treatment for heating the glass to a second temperature that is different from the first temperature.
8. The glass strengthening method of claim 7 , wherein the second temperature is about 220° C. to about 370° C.
9. The glass strengthening method of claim 1 , wherein the glass has a thickness of about 10 μm to about 50 μm.
10. The glass strengthening method of claim 1 , wherein a compressive stress (CS) of the glass after the strengthening is about 500 MPa to about 2000 MPa.
11. The glass strengthening method of claim 1 , wherein a depth of layer (DOL) of the glass after the strengthening is about 5 μm to about 10 μm.
12. The glass strengthening method of claim 1 , wherein the molten salt further comprises KNO 3 and KCl, and a value of DOL/CS of the glass after the strengthening is about 0.0113 μm/MPa or more.