Production method for fluoropolymer, surfactant for polymerization, and use of surfactant
A surfactant for polymerization including at least one selected from a surfactant represented by R 1a —CO—R 2a —CO—R 3a —OSO 3 X a and a surfactant represented by R 1b —CO—(CR 2b 2 ) n —(OR 3b ) p —(CR 4b 2 ) q -L-OSO 3 X b , wherein R 1a , R 2a , R 3a , X a , R 1b , R 2b , R 3b , R 4b , L and X b are as defined herein. Also disclosed is a composition containing a fluoropolymer and the at least one surfactant, a composition containing a fluoropolymer and a compound represented by (H—(CF 2 ) 8 —SO 3 ) q M 2 , where M 2 is as defined herein, and a molded article made from the composition containing a fluoropolymer and the compound represented by (H—(CF 2 ) 8 —SO 3 ) q M 2 .
1. A surfactant for polymerization, comprising at least one selected from the group consisting of:
a surfactant (a) represented by the following formula (a):
wherein
R 1a is a linear or branched alkyl group containing one or more carbon atoms or a cyclic alkyl group containing three or more carbon atoms, with a hydrogen atom that binds to a carbon atom therein being optionally replaced by a hydroxy group or a monovalent organic group that contains an ester bond, optionally contains a carbonyl group when containing two or more carbon atoms, and optionally contains a monovalent or divalent heterocycle or optionally forms a ring when containing three or more carbon atoms;
R 2a and R 3a are each individually a single bond or a divalent linking group;
R 1a , R 2a , and R 3a contain six or more carbon atoms in total;
X a is H, a metal atom, NR 4a 4 , imidazolium optionally containing a substituent, pyridinium optionally containing a substituent, or phosphonium optionally containing a substituent, where R 4a s are each H or an organic group and are the same as or different from each other; and
any two of R 1a , R 2a , and R 3a optionally bind to each other to form a ring; and
a surfactant (b) represented by the following formula (b):
wherein
R 1b is a C1-C10 linear alkyl group free from a substituent;
R 2b and R 4b are each individually H or a substituent;
R 3b is a C 1 -C 10 alkylene group optionally containing a substituent;
n is an integer of 1 or greater;
p and q are each individually an integer of 0 or greater;
X b is H, a metal atom, NR 5b 4 , imidazolium optionally containing a substituent, pyridinium optionally containing a substituent, or phosphonium optionally containing a substituent, where R 5b s are each H or an organic group and are the same as or different from each other;
any two of R 1b , R 2b , R 3b , and R 4b optionally bind to each other to form a ring; and
L is a single bond, —CO 2 —B—*, —OCO—B—*, —CONR 6b —B—*, —NR 6b CO—B—*, or —CO— other than the carbonyl groups in —CO 2 —B—, —OCO—B—, —CONR 6b —B—, and —NR 6 CO—B—, where B is a single bond or a C 1 -C 10 alkylene group optionally containing a substituent, R 6b is H or a C 1 -C 4 alkyl group optionally containing a substituent, and * indicates the bond to —OSO 3 X b in the formula.
2. A composition comprising
a fluoropolymer, and
at least one surfactant selected from the group consisting of:
a surfactant (a) represented by the following formula (a):
wherein
R 1a is a linear or branched alkyl group containing one or more carbon atoms or a cyclic alkyl group containing three or more carbon atoms, with a hydrogen atom that binds to a carbon atom therein being optionally replaced by a hydroxy group or a monovalent organic group that contains an ester bond, optionally contains a carbonyl group when containing two or more carbon atoms, and optionally contains a monovalent or divalent heterocycle or optionally forms a ring when containing three or more carbon atoms;
R 2a and R 3a are each individually a single bond or a divalent linking group;
R 1a , R 2a , and R 3a contain six or more carbon atoms in total;
X a is H, a metal atom, NR 4a 4 , imidazolium optionally containing a substituent, pyridinium optionally containing a substituent, or phosphonium optionally containing a substituent, where R 4a s are each H or an organic group and are the same as or different from each other; and
any two of R 1a , R 2a , and R 3a optionally bind to each other to form a ring; and
a surfactant (b) represented by the following formula (b):
wherein
R 1b is a linear or branched alkyl group containing one or more carbon atoms and optionally containing a substituent or a cyclic alkyl group containing three or more carbon atoms and optionally containing a substituent, and optionally contains a monovalent or divalent heterocycle or optionally forms a ring when containing three or more carbon atoms;
R 2b and R 4b are each individually H or a substituent;
R 3b is a C 1 -C 10 alkylene group optionally containing a substituent;
n is an integer of 1 or greater;
p and q are each individually an integer of 0 or greater;
X b is H, a metal atom, NR 5b 4 , imidazolium optionally containing a substituent, pyridinium optionally containing a substituent, or phosphonium optionally containing a substituent, where R 5b s are each H or an organic group and are the same as or different from each other;
any two of R 1b , R 2b , R 3b , and R 4b optionally bind to each other to form a ring; and
L is a single bond, —CO 2 —B—*, —OCO—B—*, —CONR 6b —B—*, —NR 6b CO—B—*, or —CO— other than the carbonyl groups in —CO 2 —B—, —OCO—B—, —CONR 6b —B—, and —NR 6 CO—B—, where B is a single bond or a C 1 -C 10 alkylene group optionally containing a substituent, R 6b is H or a C 1 -C 4 alkyl group optionally containing a substituent, and * indicates the bond to —OSO 3 X b in the formula.
3. A composition comprising:
a fluoropolymer; and
a compound represented by the following formula (3) in an amount of 500 ppb or more relative to the fluoropolymer,
the formula (3) being (H—(CF 2 ) 8 —SO 3 ) q M 2 ,
wherein M 2 is a metal atom, NR 5 4 , imidazolium optionally containing a substituent, pyridinium optionally containing a substituent, or phosphonium optionally containing a substituent; R 5 s are each H or an organic group and are the same as or different from each other; and q is 1 or 2.
4. The composition according to claim 3 ,
wherein the compound represented by the formula (3) is present in an amount of 500 to 20000 ppb relative to the fluoropolymer.
5. The composition according to claim 3 ,
wherein the compound represented by the formula (3) is present in an amount of more than 1000 ppb relative to the fluoropolymer.
6. The composition according to claim 3 ,
wherein the compound represented by the formula (3) is present in an amount of more than 1000 ppb and 20000 ppb or less relative to the fluoropolymer.
7. The composition according to claim 3 , further comprising a compound represented by the following formula (4) in an amount of 500 ppb or more relative to the fluoropolymer,
the formula (4) being (H—(CF 2 ) 7 —COO) p M 1 ,
wherein M 1 is H, a metal atom, NR 5 4 , imidazolium optionally containing a substituent, pyridinium optionally containing a substituent, or phosphonium optionally containing a substituent; R 5 s are each H or an organic group and are the same as or different from each other; and p is 1 or 2.
8. The composition according to claim 3 ,
wherein the composition has a tone L* of 50 or lower after firing and before a fluorine treatment.
9. The composition according to claim 3 ,
wherein the composition exhibits a tone change ΔL* of 70% or higher before and after a fluorination treatment.
10. A molded article comprising the composition according to claim 3 .
11. The molded article according to claim 10 ,
wherein the molded article is a stretched article.