Microfabrication method
A microfabrication method is provided with which it is possible to easily form a fine periodic structure on a surface of any substrate. A glass precursor is applied to a substrate, and the glass precursor is irradiated with short-pulse laser light. By the irradiation with short-pulse laser light, the glass precursor is activated to undergo a thermal reaction, and a fine periodic structure can be easily formed on the surface. Furthermore, by oxidizing the substrate on which the fine periodic structure has been formed, the hue of the surface can be improved while maintaining the fine periodic structure.
1. A production method for an antireflection film comprising:
applying a glass precursor onto a substrate;
irradiating a single-beam short pulse laser to the glass precursor, and forming a silica layer having a periodic structure of a size smaller than a wavelength of the single-beam short pulse laser; and
oxidizing the silica layer formed by irradiating the single-beam short pulse laser to the glass precursor, the periodic structure being transparent,
wherein the glass precursor is polysilazane having —(SiH 2 NH)— as a base unit, a pulse duration of the single-beam short pulse laser is between 0.01 picoseconds and 5 picoseconds, and a fluence range of the single-beam short pulse laser is 0.01 J/cm 2 to 1.0 J/cm 2,
wherein the periodic structure has linear or dotted protrusions of a periodic nature with a pitch between 50 nm and 1000 nm and a depth between 10 nm and 1000 nm, and
wherein the applying the glass precursor coats the glass precursor to a thickness of 100 nm to 5 μm.
2. The production method for an antireflection film according to claim 1 , wherein the oxidizing of the silica layer is a heat treatment of the silica layer at a temperature of 300° C. to 550° C. in an oxygen atmosphere.
3. The production method for an antireflection film according to claim 1 , wherein the oxidizing of the silica layer is a heat treatment of the silica layer at a temperature of 400° C. to 550° C. in an oxygen atmosphere.
4. The production method for an antireflection film according to claim 1 , wherein the oxidizing of the silica layer increases a total light transmittance of the silica layer.
5. The production method for an antireflection film according to claim 1 , wherein a fluence range of the single-beam short pulse laser is 0.05 J/cm 2 to 0.5 J/cm 2.
6. The production method for an antireflection film according to claim 1 , wherein the silica layer has a reflectance of 1% or less in a wavelength range of 300 nm to 800 nm.
7. The production method for an antireflection film according to claim 1 , wherein the substrate is a glass.
8. The production method for an antireflection film according to claim 1 , the single-beam short pulse laser has a beam spot of a quadrilateral shape.
9. The production method for an antireflection film according to claim 1 , wherein the silica layer has a contact angle with water of 110 degrees or more and 130 degrees or less.
10. The production method for an antireflection film according to claim 1 , wherein the periodic structure has a pitch width of 350 nm or less.
11. The production method for an antireflection film according to claim 1 , wherein the single-beam short pulse laser has a pulse number of 70 or more.
12. The production method for an antireflection film according to claim 8 , wherein the single-beam short pulse laser has a length in a scanning direction of 30 to 500 μm.