Carbon sorbent formulations for carbon dioxide adsorption, and related methods
A carbon sorbent for removing carbon dioxide from a gaseous material includes a surface composition including carbon, nitrogen, and oxygen. The nitrogen atoms at the surface of the carbon sorbent may be present in pyridone, pyrrole, and pyridine. The surface of the carbon sorbent may include lactone groups and pyrone groups. The carbon sorbent may have a bulk density greater than about 0.40 grams per cubic centimeter. The carbon sorbent may be formed using amino acids to provide the nitrogen for the carbon sorbent. In addition, the use of processing aids during the formation of the carbon sorbent facilitates the formation of a denser carbon sorbent. Related methods of forming the carbon sorbent and pellets of the carbon sorbent are also disclosed.
1. A carbon sorbent for removal of carbon dioxide from a gaseous material, the carbon sorbent comprising:
a carbon content of at least about 90.0 atomic percent at a surface of the carbon sorbent and a nitrogen content of at least about 2.0 atomic percent at the surface of the carbon sorbent, the carbon content and the nitrogen content exclusive of hydrogen,
at least 70 atomic percent of the nitrogen at the surface of the carbon sorbent comprising at least one of pyridone or pyrrole, at least some of the nitrogen at the surface of the carbon sorbent comprising pyridine,
greater than about 2.0 atomic percent of carbon atoms at the surface of the carbon sorbent double bonded to an oxygen atom and single bonded to one of another oxygen atom or a nitrogen atom.
2. The carbon sorbent of claim 1 , wherein greater than about 20 atomic percent of the nitrogen at the surface of the carbon sorbent comprises pyridine.
3. The carbon sorbent of claim 1 , wherein the surface of the carbon sorbent comprising at least one of:
an oxygen content at, exclusive of hydrogen, of at least about 4.0 weight percent; or
a carbon content, exclusive of hydrogen, of at least about 92.0 weight percent.
4. The carbon sorbent of claim 1 , wherein less than about 65 atomic percent of carbon atoms at the surface of the carbon sorbent are single bonded to another carbon atom or a hydrogen atom.
5. The carbon sorbent of claim 1 , wherein at least about 10.0 atomic percent of carbon atoms at the surface of the carbon sorbent are conjugated.
6. The carbon sorbent of claim 1 , wherein the carbon sorbent exhibits a carbon dioxide capacity greater than about 10.50 weight percent at about 30° C. and a partial pressure of carbon dioxide of about 760 mmHg.
7. The carbon sorbent of claim 1 , wherein the carbon sorbent exhibits a BET surface area from about 500 m 2 /g to about 700 m 2 /g.
8. The carbon sorbent of claim 1 , wherein the carbon sorbent has a BJH average pore width within a range of from about 3.0 to about 4.0 nm.
9. The carbon sorbent of claim 1 , wherein the carbon sorbent exhibits a selectivity of carbon dioxide to nitrogen greater than about 11.0:1 at about 60° C. and about 760 mmHg total pressure when exposed to a gas including about 15 volume percent carbon dioxide and about 85 volume percent nitrogen.
10. A carbon sorbent for removal of carbon dioxide from a gaseous material, the carbon sorbent comprising:
at least 2.0 atomic percent nitrogen at a surface of the carbon sorbent, a ratio of pyridone and pyrrole to pyridine at the surface greater than about 2.0:1.0;
at least 3.0 atomic percent oxygen at the surface of the carbon sorbent, the atomic percent nitrogen and the atomic percent of oxygen exclusive of hydrogen at the surface of the carbon sorbent; and
greater than about 2.0 atomic percent of carbon atoms of the carbon sorbent at the surface double bonded to an oxygen atom and single bonded to one of another oxygen atom or a nitrogen atom.
11. The carbon sorbent of claim 10 , wherein greater than about 70.0 atomic percent of the nitrogen atoms at the surface are part of a pyridone or pyrrole structure.
12. The carbon sorbent of claim 10 , wherein the surface of the carbon sorbent, exclusive of hydrogen, comprises greater than about 5.0 atomic percent oxygen.
13. The carbon sorbent of claim 10 , wherein the surface of the carbon sorbent comprises carbon atoms single bonded to a nitrogen atom and double bonded to an oxygen atom.
14. The carbon sorbent of claim 10 , wherein:
the carbon sorbent has a BET surface area greater than about 500 m 2 /g to about 700 m 2 /g; and
the surface of the carbon sorbent has a nitrogen content greater than about 2.0 atomic percent and an oxygen content greater than about 3.0 atomic percent.