IP Library › Granted Patent US 12,448,661
Granted Patent B2
US 12,448,661 · App. 16/213,455 · Granted Oct 21, 2025

Very high-strength, cold-rolled, dual steel sheets

Inventors: Antoine Moulin (Woippy, FR); Veronique Sardoy (Saint Julien Metz, FR); Catherine Vinci (Jury, FR); Gloria Restrepo Gacess (Salon de Provence, FR); Tom Watershoot (Lokeren, BE); Mohamed Goune (Pont a Mousson, FR)
Assignee: ArcelorMittal
C21D9/46B22D7/00B22D11/001C21D1/84C21D6/004C21D6/005C21D6/008C21D8/0205C21D8/021C21D8/0226C21D8/0236C21D8/0263C21D8/0273C21D8/0278C22C38/001C22C38/002C22C38/02C22C38/04C22C38/06C22C38/44C22C38/48C22C38/50C22C38/54C22C38/58C23C2/02C23C2/0224C23C2/024C23C2/06C23C2/28C23C2/29C23C2/36
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,448,661
App. No.
16/213,455
Granted
Oct 21, 2025
Kind
B2
Abstract

The present invention provides a cold-rolled and annealed Dual-Phase steel sheet having a tensile strength from 980 to 1100 MPa. The composition includes the contents being expressed by weight: 0.055%≤C≤0.095%, 2%≤Mn≤2.6%, 0.005%≤Si≤0.35%, S≤0.005%, P≤0.050%, 0.1≤Al≤0.3%, 0.05%≤Mo≤0.25%, 0.2%≤Cr≤0.5%, Cr+2 Mo≤0.6%, Ni≤0.1%, 0.010≤Nb≤0.040%, 0.010≤Ti≤0.050%, 0.0005≤B≤0.0025%, and 0.002%≤N≤0.007%. The remainder of the composition includes iron and inevitable impurities resulting from the smelting. A microstructure of the steel sheet is 40 to 65% ferrite, 35 to 50% martensite and 0 to 10% bainite. A non-recrystallized ferrite fraction is less than or equal to 15%.

Claims (80)

1. A cold-rolled and annealed Dual-Phase steel sheet comprising:

a composition comprising, the contents being expressed by weight:

0.055%≤C≤0.095%;

2%≤Mn≤2.6%;

0.005%≤Si≤0.35%;

S≤0.005%;

P≤0.050%;

0.1≤Al≤0.3%;

0.05%≤Mo≤0.25%;

0.2%≤Cr≤0.5%;

Cr+2Mo≤0.6%;

Ni≤0.1%;

0.010≤Nb≤0.040%;

0.010≤Ti≤0.050%;

0.0005≤B≤0.0025%; and

0.002%≤N≤0.007%;

a remainder of the composition comprising iron and the inevitable impurities resulting from smelting;

a tensile strength between 980 and 1100 MPa; and

a microstructure consisting of 40 to 65% ferrite, 35 to 50% martensite and 0 to 10% bainite, a non-recrystallized ferrite fraction being less than or equal to 15%.

2. The steel sheet as recited in claim 1 , wherein the composition of the steel contains, the content being expressed by weight: 0.12%≤Al≤0.25%.

3. The steel sheet as recited in claim 1 , wherein the composition of the steel contains, the content being expressed by weight: 0.10%≤Si≤0.30%.

4. The steel sheet as recited in claim 1 , wherein the composition of the steel contains, the content being expressed by weight: 0.15%≤Si≤0.28%.

5. The steel sheet as recited in claim 1 , wherein the composition of the steel contains, the content being expressed by weight: P≤0.015%.

6. The steel sheet as recited in claim 1 , wherein a microstructure of the steel sheet includes a surface area fraction of 35 to 50% martensite.

7. The steel sheet as recited in claim 6 , wherein a remainder of the microstructure consists of a surface area fraction of 50 to 65% ferrite.

8. The steel sheet as recited in claim 6 , wherein a remainder of the microstructure consists of surface area fractions of 1 to 10% bainite and 40 to 64% ferrite.

9. The steel sheet as recited in claim 1 , wherein a remainder of the microstructure consists of martensite and ferrite.

10. The steel sheet as recited in claim 1 , wherein a ratio of yield strength Re to strength Rm is such that: 0.6≤Re/Rm≤0.8.

11. The steel sheet as recited in claim 1 , wherein the steel sheet is continuously galvanized.

12. The steel sheet as recited in claim 1 , further comprising a galvannealed coating.

13. A structural or safety part for a motor vehicle comprising:

the steel sheet as recited in claim 1 .

14. The steel sheet as recited in claim 1 , wherein the composition consists of:

0.055%≤C≤0.095%;

2%≤Mn≤2.6%;

0.005%≤Si≤0.35%;

S≤0.005%;

P≤0.050%;

0.1≤Al≤0.3%;

0.05%≤Mo≤0.25%;

0.2%≤Cr≤0.5%;

Cr+2Mo≤0.6%;

Ni≤0.1%;

0.010≤Nb≤0.040%;

0.010≤Ti≤0.050%;

0.0005≤B≤0.0025%; and

0.002%≤N≤0.007%;

the remainder of the composition consisting of iron and the inevitable impurities resulting from smelting.

15. The steel sheet as recited in claim 1 , wherein the composition consists of:

0.055%≤C≤0.095%;

2%≤Mn≤2.6%;

0.15%≤Si≤0.28%;

S≤0.005%;

P≤0.015%;

0.12≤Al≤0.25%;

0.05%≤Mo≤0.25%;

0.2%≤Cr≤0.5%;

Cr+2Mo≤0.6%;

Ni≤0.1%;

0.010≤Nb≤0.040%;

0.010≤Ti≤0.050%;

0.0005≤B≤0.0025%; and

0.002%≤N≤0.007%;

the remainder of the composition consisting of iron and the inevitable impurities resulting from smelting.

16. The steel sheet as recited in claim 1 , wherein the tensile strength is from 1020 to 1030 MPa and wherein the elongation is from 10 to 14%.

17. The steel sheet as recited in claim 16 , wherein the microstructure includes 42 to 46% martensite.

18. The steel sheet as recited in claim 1 , wherein all of the ferrite in the microstructure is recrystallized ferrite.

19. The steel sheet as recited in claim 1 , wherein the microstructure consists of ferrite, 42 to 46% martensite and up to 8% bainite.

20. The steel sheet as recited in claim 1 , wherein the steel sheet is annealed at a temperature from 780 to 800° C. for 90 to 100 seconds.

21. The steel sheet as recited in claim 1 , wherein the steel sheet is heated at 2° C./s to an annealing temperature from 780 to 800° C. and annealed for 90 to 100 seconds.

22. The steel sheet as recited in claim 1 , wherein the steel sheet is cooled at a rate from 17 to 20° C./s after annealing.

23. The steel sheet as recited in claim 1 , wherein 0.38%≤Cr+2Mo≤0.512%.

24. The steel sheet as recited in claim 1 , wherein 0.27%≤Cr≤0.33%.

25. The steel sheet as recited in claim 24 , wherein 0.055%≤Mo≤0.104%.

26. The steel sheet as recited in claim 25 , wherein 0.062%≤C≤0.076%.

27. The steel sheet as recited in claim 1 , wherein 0.062%≤C≤0.076%.

28. The steel sheet as recited in claim 1 , wherein the martensite comprises islands of average size less than four microns.

29. The steel sheet as recited in claim 28 , wherein at least 50% of the islands have a ratio of their maximum dimension Lmax to their minimum dimension Lmin of less than or equal to 2.

30. The steel sheet as recited in claim 1 , wherein the martensite comprises islands of average size less than two microns, and at least 50% of the islands have a ratio of their maximum dimension Lmax to their minimum dimension Lmin of less than or equal to 2.

31. The steel sheet as recited in claim 1 , wherein the non-recrystallized ferrite fraction is 0%.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 11, 2018
From: MOULIN, ANTOINE; SARDOY, VERONIQUE; VINCI, CATHERINE; GACESS, GLORIA RESTREPO; WATERSHOOT, TOM; GOUNE, MOHAMED
To: ARCELORMITTAL
Reel/Frame 047740/0543 →
Priority Claims (1)
EP 08290474 · May 21, 2008 · regional
Continuity (3)
Division 15097039 · Apr 12, 2016
Continuation 12993498
Related Publication 20190106765A1 · Apr 11, 2019
References Cited (40)
US 5545269A · Koo et al. · 1996 [cited by applicant]
US 5545270A · Koo et al. · 1996 [cited by applicant]
US 7686896B2 · Yoshida et al. · 2010 [cited by applicant]
US 7780799B2 · Goto et al. · 2010 [cited by applicant]
US 7976647B2 · Moulin et al. · 2011 [cited by applicant]
US 20030091857A1 · Pradhan et al. · 2003 [cited by applicant]
US 20030129444A1 · Matsuoka et al. · 2003 [cited by applicant]
US 20030221752A1 · Utsumi · 2003 [cited by examiner]
US 20040033386A1 · Pradhan et al. · 2004 [cited by applicant]
US 20040238082A1 · Hasegawa · 2004 [cited by examiner]
US 20050139293A1 · Nomura et al. · 2005 [cited by applicant]
US 20070029015A1 · Yoshinaga et al. · 2007 [cited by applicant]
US 20070095444A1 · Nonaka et al. · 2007 [cited by applicant]
US 20080099109A1 · Park · 2008 [cited by applicant]
US 20080118390A1 · Kizu et al. · 2008 [cited by applicant]
US 20090025831A1 · Yamamoto et al. · 2009 [cited by applicant]
US 20100132849A1 · Takagi · 2010 [cited by examiner]
US 20100307644A1 · Gil Otin et al. · 2010 [cited by applicant]
US 20110168300A1 · Moulin et al. · 2011 [cited by applicant]
EP 0796928A1 · 1997 [cited by applicant]
EP 1201780A1 · 2002 [cited by applicant]
EP 1548142A1 · 2005 [cited by applicant]
FR 2790009A1 · 2000 [cited by applicant]
JP H11350038A · 1999 [cited by applicant]
JP 2000017385A · 2000 [cited by applicant]
JP 2005220430 · 2005 [cited by examiner]
JP 2005220430A · 2005 [cited by applicant]
JP 3793350B2 · 2006 [cited by applicant]
JP 2006183131A · 2006 [cited by applicant]
JP 2006283128A · 2006 [cited by applicant]
JP 2007070659A · 2007 [cited by applicant]
JP 2007092126A · 2007 [cited by applicant]
RU 2151214C1 · 2000 [cited by applicant]
RU 2152450C1 · 2000 [cited by applicant]
RU 2190685C1 · 2002 [cited by applicant]
RU 2312163C2 · 2007 [cited by applicant]
RU 2321667C2 · 2008 [cited by applicant]
Arnold R. Marder, Effects of Surface Treatments on Materials Performance, Materials Selection and Design, vol. 20, ASM Handbook, Edited By George E. Dieter, ASM International, 1997, p. 470-490, https://doi.org/10.31399/… [cited by examiner]
ASTM international. E415-08 “Standard Test Method for Atomic Emission Vacuum Spectrometric Analysis of Carbon and Low-Alloy Steel.” (Year: 2008). [cited by examiner]
ASTM international. E1019-08 “Standard Test Methods for Determination of Carbon, Sulfur, Nitrogen, and Oxygen in Steel, Iron, Nickel, and Cobalt Alloys by Various Combustion and Fusion Techniques.” (Year: 2008). [cited by examiner]