IP Library Granted Patent US 12,448,664
Granted Patent B2
US 12,448,664 · App. 17/771,908 · Granted Oct 21, 2025

Press hardening method

Inventors: Raisa Grigorieva (Metz, FR); Florin Duminica (Tilff, BE); Brahim Nabi (Leuven, BE); Pascal Drillet (Rozérieulles, FR); Thierry Sturel (Le Ban Saint Martin, FR)
Assignee: ArcelorMittal
C21D9/46B21D22/022B32B15/012B32B15/015C21D1/74C21D7/13C21D8/0205C23C2/26C23C2/261C23C2/28C23C2/29C21D2211/005C21D2211/008C22C18/04C22C21/10
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Quick Facts
Patent No.
US 12,448,664
App. No.
17/771,908
Granted
Oct 21, 2025
Kind
B2
Abstract

A press hardening method including the following steps: A. the provision of a steel sheet for heat treatment being optionally coated with a zinc- or aluminum-based pre-coating, B. the flexible rolling of the steel sheet in the rolling direction so as to obtain a steel sheet having a variable thickness, C. the cutting of the rolled steel sheet to obtain a tailored rolled blank, D. the deposition of a hydrogen barrier pre-coating over a thickness from 10 to 550 nm, E. the heat treatment of the tailored rolled blank to obtain a fully austenitic microstructure in the steel, F. the transfer of the tailored rolled blank into a press tool, G. the hot-forming of the tailored rolled blank to obtain a part having a variable thickness,H. the cooling of the part having a variable thickness obtained at step G).

Claims (27)

1. A press hardening method comprising the following steps:

A. providing a steel sheet for heat treatment, the steel sheet being optionally coated with a zinc-based pre-coating or an aluminum-based pre-coating;

B. flexible rolling the steel sheet in a rolling direction so as to obtain a steel sheet having a variable thickness;

C. cutting the rolled steel sheet to obtain a tailored rolled blank;

D. depositing a hydrogen barrier pre-coating with a thickness from 10 to 550 nm, the hydrogen barrier pre-coating consisting of nickel and chromium;

E. heat treating the tailored rolled blank to obtain a fully austenitic microstructure in the steel sheet;

F. transferring the tailored rolled blank into a press tool;

G. hot-forming the tailored rolled blank to obtain a part having a variable thickness;

H. cooling of the part obtained in step G to obtain a microstructure in steel being (i) martensitic or (martensito-bainitic or (made of at least 75% in terms of volume fraction of equiaxed ferrite, from 5 to 20% in volume of martensite and of bainite in amount less than or equal to 10% in volume.

2. The press hardening method as recited in claim 1 wherein in step A, the aluminum-based pre-coating is present and comprises less than 15% Si and less than 5.0% Fe, optionally 0.1 to 8.0% Mg and optionally 0.1 to 30.0% Zn, a remainder being Al.

3. The press hardening method as recited in claim 1 wherein in step A, the zinc-based pre-coating is present and and comprises less than 6.0% Al and less than 6.0% of Mg, a remainder being Zn.

4. The press hardening method as recited in claim 1 wherein in step B, the flexible rolling is a hot-rolling or a cold-rolling step.

5. The press hardening method as recited in claim 1 wherein in step D, the hydrogen barrier pre-coating consists of nickel and chromium where a weight ratio Ni/Cr is between 1.5 and 9.

6. The press hardening method as recited in claim 1 wherein the hydrogen barrier pre-coating of step D is deposited by physical vapor deposition, by electro-galvanization or by roll-coating.

7. The press hardening method as recited in claim 1 wherein in step E, the heat treating is at an atmosphere that (i) is inert or (ii) has an oxidizing power equal or higher than that of an atmosphere consisting of 1% by volume of oxygen and equal or smaller than that of an atmosphere consisting of 50% by volume of oxygen.

8. The press hardening method as recited in claim 1 wherein in step E, the heat treating is at a temperature between 80° and 970° C.

9. The press hardening method as recited in claim 1 wherein in step E, the heat treating is performed for a dwell time of 1 to 12 minutes.

10. The press hardening method as recited in claim 1 wherein in step G, the hot-forming is performed at a temperature between 60° and 830° C.

11. The press hardening method as recited in claim 1 wherein in step D, the thickness is between 10 and 90 nm.

12. The press hardening method as recited in claim 1 wherein in step D, the thickness is between 150 and 250 nm.

13. The press hardening method as recited in claim 1 wherein in step D, the hydrogen barrier pre-coating consists of 80% nickel and 20% chromium by weight.

14. The press hardening method as recited in claim 1 , wherein, in step D, the hydrogen barrier pre-coating is applied by magnetron sputtering.

15. The press hardening method as recited in claim 1 , wherein the microstructure is mostly martensitic.

16. The press hardening method as recited in claim 1 , wherein in step B, the flexible rolling is at a rolling rate between 1% and 50%.

17. The press hardening method as recited in claim 16 , wherein in step B, the flexible rolling is at a rolling rate of 50%.

18. The press hardening method as recited in claim 7 wherein in step E, the atmosphere has a dew point from −30 to +30° C.

19. The press hardening method as recited in claim 15 , wherein in step B, the flexible rolling is at a rolling rate between 1% and 50%.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 23, 2022
From: GRIGORIEVA, RAISA; DUMINICA, FLORIN; NABI, BRAHIM; DRILLET, PASCAL; STUREL, THIERRY
To: ARCELORMITTAL
Reel/Frame 060868/0230 →
Priority Claims (1)
WO PCT/IB2019/059288 · Oct 30, 2019 · international
Continuity (1)
Related Publication 20220380863A1 · Dec 1, 2022
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