Granted Patent B2

US 12,451,511 · App. 18/066,676 · Granted Oct 21, 2025

Inventors: Joerg Schuhmacher (Kornwestheim, DE); Philipp Treis (Bingen am Rhein, DE); Meike Schneider (Taunusstein, DE); Andreas Roters (Mainz, DE); Rolf Samsinger (Rüsselsheim am Main, DE); Sven Schopf (Braunschweig, DE); Arno Kwade (Wendeburg, DE)

Assignee: SCHOTT AG

H01M10/056H01M2300/0065H01M2300/0091

Abstract

Claims (23)

1. A method for producing a conductive composite material for a battery, the method comprising: providing an electrolyte matrix that is ion-conducting and plasticizable, the electrolyte matrix comprising a first ion-conducting substance and a plasticizable base substance or a polyelectrolyte; providing ion-conducting particles; introducing the ion-conducting particles into the electrolyte matrix to produce a mixture consisting of the ion-conducting particles and the electrolyte matrix; homogenizing the mixture with a homogenizing device; and homogenizing the mixture for a length of time of less than 8 hours, wherein the ion-conducting particles and the electrolyte matrix are homogenized so that the ion-conducting particles have a minimum distance of separation of at least 100 nm, and a particle filling of the ion-conducting particles is at least 1% by volume in relation to a total volume of the electrolyte matrix; wherein homogenizing the mixture is selected from the group consisting of: kneading, extruding, and rolling.

2. The method according to claim 1 , further comprising: actively heating or cooling the mixture in the homogenizing device to provide the electrolyte matrix at an at least essentially constant temperature and plasticized state for at least one predeterminable period of time.

3. The method according to claim 1 , further comprising, before or during the introducing: plasticizing the electrolyte matrix and homogenizing the electrolyte matrix by kneading with the homogenizing device.

4. The method according to claim 1 , wherein the homogenizing is carried out for less than 5 hours.

5. The method according to claim 1 , further comprising, prior to the homogenizing:

providing the electrolyte matrix in a particle form; and

dispersive mixing the mixture.

6. The method according to claim 5 , wherein the dispersive mixing is carried out at a lower temperature than the homogenizing.

7. The method according to claim 5 , wherein the dispersive mixing comprises: a first dispersive mixing operation of particles of the plasticizable base substance and the ion-conducting particles to obtain a partial mixture and a second dispersive mixing operation of particles of the at least one ion-conducting substance and the particles of the partial mixture.

8. The method according to claim 1 , wherein the ion-conducting particles are ceramic particles.

9. The method according to claim 8 , wherein the ceramic particles comprise at least one material selected from the group consisting of: P 2 O 5 , TiO 2 , Cr 2 O 3 , Al 2 O 3 , Ga 2 O 3 , Li 2 O, Fe 2 O 3 , GeO 2 , ZrO 2 , Ta 2 O 5 , Nb 2 O 5 , La 2 O 3 , SiO 2 , Gd 2 O 3 , Y 2 O 3 , B 2 O 3 , sulfur, halides, and nitrogen.

10. The method according to claim 8 , wherein the ceramic particles are lithium-based, glass-ceramic particles.

11. The method according to claim 10 , wherein the lithium-based, glass-ceramic particles comprise at least one ion conductor selected from the group consisting of: ion conductors having a garnet structure, ion conductors having a NaSICon structure, ion conductors having a perovskite structure, ion conductors having a spinel structure, ion conductors having a LiSICon structure, and lithium zinc germanate, and wherein the plasticizable base substance comprises polyethylene oxide.

12. The method according to claim 1 , wherein the first ion-conducting substance comprises at least one lithium salt selected from the group consisting of: lithium salts of sulfonyl imides, LiAsF 6 , LiClO 4 , LiSbF 6 , LiPtCl 6 , LiAlCl 4 , LiGaCl 4 , LiSCN, LiAlO 4 , LiCF 3 CF 2 SO 3 , Li(CF 3 )SO 3 (LiTf), LiC(SO 2 CF 3 ) 3 , phosphate-based lithium salts, borate-based lithium salts, and lithium salts of sulfonyl imides.

13. The method according to claim 12 , wherein the lithium salt comprises at least one anion selected from the group consisting of: PF 6 —, BF 4 —, SbF 6 —, AsF 6 —, C 4 F 9 SO 3 —, ClO 4 —, AlO 2 —, AlCl 4 —, (C x F 2x+1 SO 3 )—, where 0<=x<1, and (C x F 2x+1 SO 2 )(C y F 2y+1 SO 2 )N—, where 0<=x<1 and 0<=y<1.

14. The method according to claim 1 , wherein the first ion-conducting substance comprises at least one lithium salt selected from the group consisting of: LiClO 4 , LiBF 4 , lithium bis(oxalate)borate, lithium diflouro(oxalate)borate, LiSO 3 CF 3 , lithium 2-penta-fluoroethoxy-1,1,2,2-tetrafluoroethanesulfonate, LiN(FSO 2 ) 2 , LiN(SO 2 CF 3 ) 2 , lithium perchlorate (LiClO 4 ), lithium tetrafluoroborate (LiBF 4 ), lithium bis(oxalato)borate (LiBOB), lithium diflouro(oxalate)borate (LiDFOB), LiSO 3 CF 3 (LiTf), lithium 2-penta-fluoroethoxy-1,1,2,2-tetrafluoroethanesulfonate (LiSO 3 C 2 F 4 OC 2 F 5 ), lithium bis(fluorosulfonyl)imide (LiN(FSO 2 ) 2 (LIFSI), and lithium bis(trifluoromethane)sulfonimide (LiN(SO 2 CF 3 ) 2 (LiTFSI).

15. The method according to claim 1 , further comprising: drying the ion-conducting particles.

16. The method according to claim 1 , wherein the ion-conducting particles introduced into the electrolyte matrix are provided in a volume percent of between 1% and 30% in the electrolyte matrix.

17. A conductive composite material for a battery, comprising: an electrolyte matrix that is ion-conducting and plasticizable, comprising a plasticizable base substance, an ion-conducting first substance, or a polyelectrolyte; and an ion-conducting second substance in ion-conducting particle form, wherein the ion-conducting particles and the electrolyte matrix are homogenized so that the ion-conducting particles have a minimum distance of separation of at least 100 nm, and a particle filling degree of the ion-conducting particles is at least 1 vol % in relation to a total volume of the electrolyte matrix.

18. The composite material according to claim 17 , wherein the ion-conducting second substance comprises lithium-based glass-ceramic particles.

19. The composite material according to claim 17 , wherein the plasticizable base substance comprises polyethylene oxide.

20. The composite material according to claim 17 , wherein the ion-conducting particles have a volume percent of between 1% and 30% in the electrolyte matrix.

21. A battery, comprising the conductive composite material according to claim 17 .

Assignments (1)

Priority Claims (1)

Continuity (2)

References Cited (22)