Electrolyte and electrode materials for rechargeable lithium batteries
View Patent ↗A composition of matter and method includes Li 1+x+z M(II) 0.5−2x−z M(III) x+y M(IV) 1.5−2y−z M(V) y M(V) z O 4 . M(II) includes any of Mg, Co, Ni, Cu, and Zn. M(III) includes any of Al, Cr, Fe, Ga, and In. M(IV) includes any of Ti, Mn, and Ge. M(V) includes any of Nb, Ta, Sb, and Bi. Additionally, 0≤x≤0.25, 0≤y≤0.75, 0≤z≤0.5, and (x+z)>0.
1. A composition of matter comprising Li 1.25 Cr 0.25 Ti 1.5 O 4 (LCTO) or Li 1.25 Al 0.25 Tl 1.5 O 4 (LATO), and
a second composition of matter a spinel crystal structure electrode material selected from one of LiNi 0.5 Mn 1.5 O 4 (LNMO), LiMn 2 O 4 , or Li 4 Ti 5 O 12 , and further combined with composites of Li 3 BO 3 (LBO),
wherein the spinel crystal structure electrode material comprises a single-phase spinel structure.
2. The composition of matter of claim 1 , wherein the spinel crystal structure electrode material and the second composition of matter comprising composites with Li 3 BO 3 (LBO) are provided as solid-state electrolytes and cathodes.
3. The composition of matter of claim 2 , wherein solid-state electrolytes form an electrochemically-active solid solution with the spinel crystal structure electrode material enabling single-phase fully-solid electrodes and interface free solid cathodes.