Composite material and quantum dot light emitting diode
A composite material includes a light-emitting quantum dot, and a first ligand and a second ligand bound on a surface of the light-emitting quantum dot. The first ligand includes an oil-soluble organic ligand, and the second ligand including a halogen ligand or a water-soluble ligand.
1 . A composite material comprising:
a light-emitting quantum dot; and
a first ligand and a second ligand bound on a surface of the light-emitting quantum dot, the first ligand including an oil-soluble organic ligand, and the second ligand including a water-soluble ligand,
wherein the water-soluble ligand of the second ligand includes a mercapto acid with a carbon number less than eight; and
the oil-soluble organic ligand includes one or more of a substituted or unsubstituted alkylaminophosphine, a substituted or unsubstituted alkoxyphosphine, and a substituted or unsubstituted silylphosphine.
2 . The composite material of claim 1 , wherein the light-emitting quantum dot includes a II-VI quantum dot, a III-V quantum dot, or a IV-VI quantum dot.
3 . The composite material of claim 1 , wherein the light-emitting quantum dot includes a core-shell quantum dot including a core made of a III-V material or II-VI material and a shell made of a II-VI material.
4 . The composite material of claim 3 , wherein the light-emitting quantum dot includes one or more of CdZnS/ZnS, CdZnSe/ZnSe, CdSeS/CdSeS/CdS, CdSe/CdZnSe/CdZnSe/ZnSe, CdZnSe/CdZnSe/ZnSe, CdS/CdZnS/CdZnS/ZnS, CdSe/ZnS, CdZnSe/ZnS, CdSe/CdS/ZnS, CdSe/ZnSe/ZnS, and CdZnSe/CdZnS/ZnS.
5 . The composite material of claim 1 , wherein a size of the light-emitting quantum dot is 10-20 nm.
6 . The composite material of claim 1 , wherein:
the oil-soluble organic ligand further includes one or more of a secondary or tertiary amine having a side chain with a carbon number of four or more, an organic carboxylic acid with a carbon number of eight or more, an organic phosphoric acid with a carbon number of eight or more, and a primary amine with a carbon number of eight or more and an alkylphosphine having a side chain with a carbon number of four or more.
7 . The composite material of claim 1 , wherein:
the substituted or unsubstituted alkylaminophosphine includes one or more of a tri (dimethylamino) phosphine, a tri (diethylamino) phosphine, a tri (dipropylamino) phosphine, a tri (dibutylamino) phosphine, a tri (dipentylamino) phosphine, a tri (dihexylamino) phosphine, a tri (diheptylamino) phosphine, a tri (dioctylamino) phosphine, and a dibenzyldiethylaminophosphine;
the substituted or unsubstituted alkoxyphosphine includes one or more of a diphenylmethoxyphosphine, a diphenylethoxyphosphine, a diphenylpropoxyphosphine, a diphenylbutoxyphosphine, and a chloro (diisopropylamino) methoxyphosphorus; and/or
the substituted or unsubstituted silylphosphine includes one or more of a tris (trisilyl) phosphine, a tri (triethylsilyl) phosphine, a tri (tripropylsilyl) phosphine, a tri (tributylsilyl) phosphine, a tri (trispentasilyl) phosphine, a tri (trihexylsilyl) phosphine, a tri (triheptylsilyl) phosphine, and a tri (trioctylsilyl) phosphine.
8 . The composite material of claim 1 , wherein the second ligand includes the water-soluble ligand including one or more of a halogen ion ligand, a mercapto alcohol with a carbon number less than eight, and a mercaptoamine with a carbon number less than eight.