Method of manufacturing an all solid state battery
A method of manufacturing an all solid state battery is disclosed. In one embodiment, the method includes forming a negative electrode including a negative active material layer and a negative buffer layer, forming a sulfide-based solid electrolyte layer on a first surface of the negative electrode, forming a positive electrode including a positive active material layer and a positive buffer layer, and bonding the positive electrode to a second surface of the solid electrolyte layer.
1 . A method for manufacturing a solid state battery, the method comprising:
forming a negative electrode including a negative active material layer and a negative buffer layer;
forming a sulfide-based solid electrolyte layer on a first surface of the negative electrode;
forming a positive electrode including a positive active material layer and a positive buffer layer; and
bonding the positive electrode to a second surface of the solid electrolyte layer
wherein forming the negative electrode comprises:
forming surface roughness on a first surface of a negative current collector through a surface treatment,
forming a negative primer layer on the first surface of the negative current collector through wet coating,
forming the negative buffer layer having higher softness than that of the negative primer layer on a first surface of the negative primer layer through wet coating,
forming the negative active material layer having the same ionic conductivity and electronic conductivity as the negative buffer layer on a first surface of the negative buffer layer, and
rolling the negative current collector, the negative primer layer, the negative buffer layer, and the negative active material layer, which are stacked.
2 . The method of claim 1 , wherein the sulfide-based solid electrolyte layer is formed on a first surface of the negative active material layer through wet coating.
3 . The method of claim 1 , wherein the negative primer layer comprises a mixture of a carbon-based conductive material and a first binder.
4 . The method of claim 1 , wherein the negative buffer layer comprises a mixture of a first sulfide-based material, a first conductive material, and a second binder, wherein the negative buffer layer has a different composition than the negative active material layer.
5 . The method of claim 1 , wherein the negative buffer layer has a degree of softness that is higher than that of the negative primer layer.
6 . The method of claim 1 , wherein the negative active material layer comprises a mixture of a second sulfide-based material, a negative electrode active material, a second conductive material, and a third binder, and wherein the negative active material layer is in contact with the solid electrolyte layer.
7 . The method of claim 1 , wherein forming the positive electrode comprises:
forming surface roughness on a first surface of a positive current collector through a surface treatment,
forming a positive primer layer comprising a mixture of a carbon-based material and a first binder on the first surface of the positive current collector through wet coating,
forming the positive buffer layer having higher softness than the positive primer layer on a first surface of the positive primer layer,
forming the positive active material layer having the same ionic conductivity and electronic conductivity as the positive buffer layer on a first surface of the positive buffer layer, and
rolling the positive current collector, the positive primer layer, the positive buffer layer, and the positive active material layer which are stacked.
8 . A method for manufacturing a solid state battery, the method comprising:
forming a negative electrode including a negative active material layer and a negative buffer layer;
forming a sulfide-based solid electrolyte layer on a first surface of the negative electrode;
forming a positive electrode including a positive active material layer and a positive buffer layer; and
bonding the positive electrode to a second surface of the solid electrolyte layer,
wherein forming the positive electrode comprises:
forming surface roughness on a first surface of a positive current collector through a surface treatment,
forming a positive primer layer comprising a mixture of a carbon-based material and a first binder on the first surface of the positive current collector through wet coating,
forming the positive buffer layer having higher softness than the positive primer layer on a first surface of the positive primer layer,
forming the positive active material layer the same ionic conductivity and electronic conductivity as the positive buffer layer on a first surface of the positive buffer layer, and
rolling the positive current collector, the positive primer layer, the positive buffer layer, and the positive active material layer, which are stacked.
9 . The method of claim 8 , wherein the positive buffer layer has a degree of softness that is higher than that of the positive primer layer.
10 . The method of claim 1 , wherein bonding the positive electrode includes:
inverting the positive electrode in a vertical direction and contacting the sulfide-based solid electrolyte layer with the positive active material layer of the positive electrode, and
rolling the negative electrode, the sulfide-based solid electrolyte layer, and the positive electrode.
11 . A method for forming a solid state battery, the method comprising:
forming a negative active material layer on a first surface of a solid electrolyte layer;
forming a negative buffer layer on a first surface of the negative active material layer, the negative buffer layer comprising a mixture of a first sulfide-based material, a first conductive material, and a second binder, wherein the negative buffer layer has a different composition than the negative active material layer;
forming a negative primer layer on a first surface of the negative buffer layer, wherein the negative buffer layer has a degree of softness that is higher than that of the negative primer layer;
forming a negative current collector layer having a second surface disposed on a first surface of the negative primer layer, the second surface of the negative current collector layer having a surface roughness;
forming a positive active material layer on a second surface of the solid electrolyte layer;
forming a positive buffer layer on a second surface of the positive active material layer, the positive buffer layer comprising a mixture of the first sulfide-based material, the first conductive material, and the second binder without an active material, wherein the positive buffer layer has a different composition than the positive active material layer;
forming a positive primer layer on a second surface of the positive buffer layer, wherein the positive buffer layer has a degree of softness that is higher than that of the positive primer layer; and
forming a positive current collector layer having a first surface disposed on a second surface of the positive primer layer, the first surface of the positive current collector layer having a surface roughness.
12 . The method of claim 11 , wherein the negative primer layer comprises a mixture of a carbon-based conductive material and a first binder, and wherein the negative active material layer comprises a mixture of a second sulfide-based material, a negative electrode active material, a second conductive material, and a third binder, wherein the negative active material layer is in contact with the solid electrolyte layer.
13 . The method of claim 12 , wherein the mixture of the carbon-based conductive material and the first binder of the negative primer layer has a ratio of 7:3 to 9.5:0.5.
14 . The method of claim 11 , wherein the mixture of the negative buffer layer comprises the first sulfide-based material in a range of 60 wt % or more and 90 wt % or less, the first conductive material in a range of 9 wt % or more and 30 wt % or less, and the second binder in a range of 1 wt % or more and 10 wt % or less, based on 100 wt % of a total weight.
15 . The method of claim 11 , wherein the negative buffer layer has the same ionic conductivity and electronic conductivity as the negative active material layer.
16 . The method of claim 11 , wherein the positive primer layer comprises a mixture of a carbon-based conductive material and a first binder, and wherein the positive active material layer comprises a mixture of a second sulfide-based material, a positive electrode active material, a second conductive material, and a third binder, wherein the positive active material layer is in contact with the solid electrolyte layer.
17 . The method of claim 16 , wherein the mixture of the carbon-based conductive material and the first binder of the positive primer layer has a ratio of 7:3 to 9.5:0.5.
18 . The method of claim 11 , wherein the mixture of the positive buffer layer comprises the first sulfide-based material in a range of 60 wt % or more and 90 wt % or less, the first conductive material in a range of 9 wt % or more and 30 wt % or less, and the second binder in a range of 1 wt % or more and 10 wt % or less, based on 100 wt % of a total weight.
19 . The method of claim 11 , wherein the positive buffer layer has the same ionic conductivity and electronic conductivity as the positive active material layer.
20 . The method of claim 8 , wherein the positive buffer layer comprises a mixture of a first sulfide-based material, a first conductive material, and a second binder without an active material, wherein the positive buffer layer has a different composition than the positive active material layer.