IP Library Granted Patent US 12,497,552
Granted Patent B2
US 12,497,552 · App. 18/480,888 · Granted Dec 16, 2025

Cement compositions including volcanic ash

Inventors: Noktan Mohammed AlYami (Dammam, SA); Ali Al-Safran (Dhahran, SA); Vikrant Wagle (Dhahran, SA); Abdullah Saleh Hussain Al-Yami (Dhahran, SA); Thomas Heinold (Dhahran, SA); Khawlah Alanqari (Al-Khobar, SA)
Assignee: Saudi Arabian Oil Company
C09K8/467C04B14/045C04B14/104C04B28/04C04B40/0071C04B40/0082E21B33/14C04B2103/0027C04B2103/20C04B2103/46C04B2103/50C04B2201/20C04B2201/52
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Quick Facts
Patent No.
US 12,497,552
App. No.
18/480,888
Granted
Dec 16, 2025
Kind
B2
Abstract

The present disclosure relates to cement compositions including Portland cement and volcanic ash. An exemplary cement composition includes about 10 wt % to about 85 wt % of Portland cement, and about 10% by weight of cement (BWOC) to about 70% BWOC of volcanic ash.

Claims (51)

1 . A cement composition, comprising:

about 10 wt % to about 45 wt % of Portland cement;

about 30% by weight of cement (BWOC) to about 50% BWOC of volcanic ash, wherein the volcanic ash comprises about 75 wt % silicon dioxide (SiO 2 ); and

about 25 wt % to about 80 wt % of water;

wherein a weight ratio of water to a total amount of Portland cement and volcanic ash present in the cement composition is about 0.4:1 to about 2:1; and

the cement composition has no free fluid.

2 . The cement composition of claim 1 , wherein the volcanic ash comprises Saudi Arabian volcanic ash.

3 . The cement composition of claim 1 , wherein the Portland cement comprises an American Petroleum Institute (API) Class G cement.

4 . The cement composition of claim 1 , comprising about 30% BWOC to about 45% BWOC of volcanic ash.

5 . The cement composition of claim 1 , comprising about 40% BWOC of volcanic ash.

6 . The cement composition of claim 1 , comprising

about 15 wt % to about 45 wt % of Portland cement;

and about 30 wt % to about 65 wt % of water.

7 . The cement composition of claim 1 , further comprising an extender.

8 . The cement composition of claim 7 , comprising about 0.1% BWOC to about 20% BWOC of the extender.

9 . The cement composition of claim 1 , further comprising a defoamer.

10 . The cement composition of claim 9 , comprising about 0.01% BWOC to about 2% BWOC of the defoamer.

11 . The cement composition of claim 1 , further comprising a gelling agent.

12 . The cement composition of claim 11 , comprising about 0.1% BWOC to about 5% BWOC of the gelling agent.

13 . The cement composition of claim 1 , further comprising a retarder.

14 . The cement composition of claim 13 , comprising about 0.01% BWOC to about 3% BWOC of the retarder.

15 . The cement composition of claim 1 , having a density of about 80 pcf to about 120 pcf.

16 . The cement composition of claim 1 , having a density of about 80 pcf to about 105 pcf.

17 . The cement composition of claim 1 , having a thickening time of about 3 hours to about 8 hours at about 120° F. and about 2,700 psi.

18 . The cement composition of claim 1 , having a thickening time of about 4 hours to about 7 hours at about 120° F. and about 2,700 psi.

19 . The cement composition of claim 1 , having a compressive strength of about 50 psi to about 1,500 psi after curing for about 1 day at about 150° F.

20 . The cement composition of claim 1 , having a compressive strength of about 100 psi to about 2,000 psi after curing for about 3 days at about 150° F.

21 . A cement composition, comprising:

about 10 wt % to about 45 wt % of Portland cement;

about 30% BWOC to about 50% BWOC of volcanic ash, wherein the volcanic ash comprises about 75 wt % silicon dioxide (SiO 2 );

about 0.01% BWOC to about 2% BWOC of a defoamer;

about 0.1% BWOC to about 5% BWOC of a gelling agent;

about 0.1% BWOC to about 3% BWOC of a retarder; and

about 25 wt % to about 80 wt % of water;

wherein a weight ratio of water to a total amount of Portland cement and volcanic ash present in the cement composition is about 0.4:1 to about 2:1; and

the cement composition has no free fluid.

22 . The cement composition of claim 21 , further comprising about 0.1% BWOC to about 5% BWOC of an extender.

23 . The cement composition of claim 22 , wherein the extender comprises bentonite.

24 . A cement composition, comprising:

about 10 wt % to about 45 wt % of Portland cement;

about 30% BWOC to about 50% BWOC of volcanic ash, wherein the volcanic ash comprises about 75 wt % silicon dioxide (SiO 2 );

about 5% BWOC to about 20% BWOC of an extender;

about 0.01% BWOC to about 2% BWOC of a defoamer;

about 25 wt % to about 80 wt % of water;

wherein a weight ratio of water to a total amount of Portland cement and volcanic ash present in the cement composition is about 0.4:1 to about 2:1; and

the cement composition has no free fluid.

25 . The cement composition of claim 24 , wherein the extender comprises sodium silicate.

26 . A method of cementing a wellbore, comprising

providing the cement composition of claim 1 to the wellbore, and

curing the cement composition.

27 . The method of claim 26 , comprising pumping the cement composition into an annulus between the wellbore and a casing in the wellbore.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 16, 2023
From: ALYAMI, NOKTAN MOHAMMED; AL-SAFRAN, ALI; WAGLE, VIKRANT; AL-YAMI, ABDULLAH SALEH HUSSAIN; HEINOLD, THOMAS; ALANQARI, KHAWLAH
To: SAUDI ARABIAN OIL COMPANY
Reel/Frame 065588/0530 →
Continuity (1)
Related Publication 20250115801A1 · Apr 10, 2025
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