Micro light-emitting element and image display element
A micro light-emitting element includes: a micro light-emitting diode (LED) element configured to emit excitation light; and a wavelength conversion portion containing a nano particle configured to absorb the excitation light to emit light having a longer wavelength than the excitation light. The wavelength conversion portion has, on at least a light emitting surface of the wavelength conversion portion, a stack of one or more layers including an oxygen absorption film.
1 . A micro light-emitting element comprising:
a micro light-emitting diode (LED) element configured to emit excitation light; and
a wavelength conversion portion containing a nano particle configured to absorb the excitation light to emit light having a wavelength longer than a wavelength of the excitation light,
wherein the wavelength conversion portion has, on at least a light emitting surface of the wavelength conversion portion, a stack of one or more layers comprising an oxygen absorption film that directly contacts the wavelength conversion portion,
the oxygen absorption film comprising an inorganic oxide,
a composition of the inorganic oxide is shifted in an oxygen deficiency direction from a stoichiometric state, and
the oxygen absorption film is in an amorphous state.
2 . The micro light-emitting element according to claim 1 , wherein the inorganic oxide comprises an aluminum-doped zinc oxide (AZO).
3 . The micro light-emitting element according to claim 1 , wherein the stack has a dielectric multi-layer film, and the dielectric multi-layer film comprises a plurality of oxygen absorption films, including the oxygen absorption film.
4 . The micro light-emitting element according to claim 1 , wherein the stack has an aluminum-doped zinc oxide (AZO) film in contact with the wavelength conversion portion and has a dielectric multi-layer film on the AZO film.
5 . The micro light-emitting element according to claim 1 , wherein the stack has a dielectric multi-layer film in contact with the wavelength conversion portion and has an aluminum-doped zinc oxide (AZO) film on the dielectric multi-layer film.
6 . A micro light-emitting element comprising:
a micro light-emitting diode (LED) element configured to emit excitation light; and
a wavelength conversion portion containing a nano particle configured to absorb the excitation light to emit light having a wavelength longer than a wavelength of the excitation light,
wherein the wavelength conversion portion has, on at least a light emitting surface of the wavelength conversion portion, a stack of one or more layers comprising an inorganic oxide thin film that directly contacts the wavelength conversion portion,
the inorganic oxide thin film is configured to increase, over time, conversion efficiency at which the nano particle converts the excitation light into the light having the wavelength longer than the wavelength of the excitation light,
a composition of the inorganic oxide thin film is shifted in an oxygen deficiency direction from a stoichiometric state, and
the inorganic oxide thin film is in an amorphous state.
7 . The micro light-emitting element according to claim 6 , wherein the inorganic oxide thin film continuously covers an entirety of the light emitting surface of the wavelength conversion portion.
8 . The micro light-emitting element according to claim 6 , wherein the inorganic oxide thin film comprises an aluminum-doped zinc oxide (AZO).
9 . The micro light-emitting element according to claim 6 , wherein the stack has a dielectric multi-layer film, and the dielectric multi-layer film comprises a plurality of inorganic oxide thin films, including the inorganic oxide thin film.
10 . The micro light-emitting element according to claim 6 , wherein the stack has an aluminum-doped zinc oxide (AZO) film in a location adjacent to the wavelength conversion portion and has a dielectric multi-layer film on the AZO film.
11 . The micro light-emitting element according to claim 6 , wherein the stack has a dielectric multi-layer film in a location adjacent to the wavelength conversion portion and has an aluminum-doped zinc oxide (AZO) film on the dielectric multi-layer film.
12 . An image display element comprising:
a plurality of micro light-emitting elements disposed in an array; and
a driving circuit substrate comprising a driving circuit configured to supply a current to the plurality of micro light-emitting elements to cause the plurality of micro light-emitting elements to emit light,
wherein each of the plurality of micro light-emitting elements comprises an excitation-light-emitting element configured to emit excitation light, and a wavelength conversion portion configured to absorb the excitation light to emit light having a wavelength longer than a wavelength of the excitation light,
the excitation-light-emitting element and the wavelength conversion portion are stacked in this order on the driving circuit substrate, and each micro light-emitting element emits the light having the wavelength longer than the wavelength of the excitation light in an upward direction that is opposite to where the driving circuit substrate is located,
a partition wall is disposed on a side surface of the wavelength conversion portion,
a first oxygen absorption film is disposed in direct contact with a light emitting surface of the wavelength conversion portion,
a second oxygen absorption film is disposed between the wavelength conversion portion and the excitation-light-emitting element, the second oxygen absorption film being in direct contact with a lower surface of the wavelength conversion portion, and
a third oxygen absorption film is disposed between the wavelength conversion portion and the partition wall, the third oxygen absorption film being in direct contact with the side surface of the wavelength conversion portion.
13 . The image display element according to claim 12 , wherein the first oxygen absorption film continuously covers an entirety of the light emitting surface of the wavelength conversion portion.
14 . The image display element according to claim 12 , wherein the first oxygen absorption film is divided for each of a plurality of wavelength conversion portions, including the wavelength conversion portion.
15 . The image display element according to claim 12 , wherein
the first oxygen absorption film comprises an inorganic oxide, and
a composition of the inorganic oxide is shifted in an oxygen deficiency direction from a stoichiometric state.
16 . The image display element according to claim 12 , wherein the first oxygen absorption film, the second oxygen absorption film, and the third oxygen absorption cover an entire perimeter of the wavelength conversion portion.