Maintaining suitable sealability and hot tack strengths of acrylic- and acetate-based coatings when using base films containing HCR to improve their water-vapor barriers
In one embodiment, the disclosure provides a film, which may be oriented, cast, or blown, that includes a core layer having a first side and a second side, wherein the core layer comprises hydrocarbon resin and polypropylene. Further, the film may include a first tie layer on the first side, wherein the first tie layer consists of polypropylene and about 5% or less of additives with exclusion of hydrocarbon resin (“HCR”), wherein the polypropylene is standard-crystalline polypropylene, high-crystalline polypropylene, or a mixture thereof, but preferably, it is a majority of high-crystalline polypropylene. Further still, the film may include a first skin layer on the first tie layer, and, also a coating on the first skin layer, wherein the coating comprises acrylic or acetate polymers or combinations thereof. The film maintains a minimum seal temperature of 300 g in −1 seal strength as compared to the film without any HCR.
1 . A film comprising:
a core layer having a first side and a second side, wherein the core layer consists essentially of polypropylene and hydrocarbon resin, wherein the hydrocarbon resin is optionally in masterbatch solution;
a first tie layer on the first side, wherein the first tie layer consists of polypropylene and about 5% or less of additives with exclusion of hydrocarbon resin;
a first skin layer on the first tie layer; and
a coating on the first skin layer, wherein the coating comprises acrylic or acetate polymers, wherein minimum seal temperature of 300 g in −1 seal strength of the film is maintained as compared to the film without any hydrocarbon resin.
2 . The film of claim 1 , wherein the film has a water vapor transmission rate of less than about 4 g m −2 d −1 at 100% relative humidity.
3 . The film of claim 1 , wherein the polypropylene in the core comprises high-crystalline polypropylene.
4 . The film of claim 1 , wherein the polypropylene in the core comprises standard-crystalline polypropylene and high-crystalline polypropylene.
5 . The film of claim 1 , further comprising a primer between the first skin layer and the coating.
6 . The film of claim 1 , wherein the first skin layer comprises ethylene-propylene copolymer.
7 . The film of claim 1 , further comprising a second tie layer on the second side of the core layer.
8 . The film of claim 7 , wherein the second tie layer comprises high-crystalline polypropylene.
9 . The film of claim 7 , further comprising a second skin layer on the second tie layer, wherein the second tie layer comprises polypropylene.
10 . The film of claim 9 , further comprising a second primer on the second skin layer, wherein the second primer is identical to or different from the primer.
11 . The film of claim 9 , further comprising a second primer on the second skin layer, wherein the second primer is different from the primer.
12 . The film of claim 10 , further comprising a second coating between the second skin layer and the second primer, wherein the second coating is identical to the coating.
13 . The film of claim 10 , further comprising a second coating between the second skin layer and the second primer, wherein the second coating is different from the coating.
14 . The film of claim 1 , wherein the hydrocarbon resin is in a polypropylene-based masterbatch solution.
15 . The film of claim 1 , wherein the coating comprises wax.
16 . The film of claim 1 , wherein the coating comprises talc.
17 . The film of claim 1 , wherein the film is oriented.
18 . The film of claim 1 , wherein the film is a cast film or a blown film.
19 . The film of claim 1 , wherein the film further comprises adhesive on the second side of the core layer.
20 . The film of claim 19 , wherein the film further comprises a release layer on the adhesive to form a label.