Manufacturing battery electrodes
Producing an electrode by providing a solvent-free powder that includes an electrode active material and a binder, determining a temperature to be produced at a location of application of a laser beam, selecting a scan frequency at which to control oscillation of the laser beam, producing the electrode by feeding, via a powder feeder, the solvent-free powder onto a current collector and concurrently applying the laser beam to the solvent-free powder to melt the binder of the solvent-free powder at the temperature to produce a coating on the current collector.
1 . A method comprising:
providing a solvent-free powder comprising at least an electrode active material and a binder;
determining a desired temperature to be produced at a location of application of a laser beam;
selecting a scan frequency at which to control oscillation of the laser beam; and
producing an electrode by feeding, via a powder feeder, the solvent-free powder onto a current collector and concurrently applying the laser beam to the solvent-free powder to melt the binder of the solvent-free powder at said desired temperature to produce a coating on the current collector;
wherein the laser beam is operated as a continuous wave emission laser beam; and
wherein the powder feeder applies the solvent-free powder in a direction perpendicular to a profile of the laser beam.
2 . The method of claim 1 , further comprising:
determining a desired thickness of the coating and the desired temperature to be produced at the location of application of the laser beam to melt the binder.
3 . The method of claim 2 , wherein the desired thickness is based on a feed rate of the solvent-free powder and on a coating speed of the solvent-free powder.
4 . The method of claim 2 , wherein the desired temperature is based on a power or power density of the laser beam, a scan width of the laser, the selected scan frequency of the laser, and a coating speed of the solvent-free powder.
5 . The method of claim 1 , wherein the laser beam oscillates at the selected scan frequency to produce a coating width of up 10 mm in one pass of the laser beam, wherein the scan frequency ranges from 10 Hz to 200 Hz.
6 . The method of claim 1 , wherein the coating has a flat or ribbon shaped profile.
7 . The method of claim 1 , wherein one or more other laser beams are disposed adjacent to the laser beam to produce in a given duration a coating width that is wider than another coating width produced by the laser beam during said given duration.
8 . The method of claim 1 , wherein the powder feeder feeds the solvent-free powder in a coaxial powder feeding manner by applying the solvent-free powder coaxially to a profile of the laser beam.
9 . The method of claim 1 , wherein the electrode is a cathode.
10 . The method of claim 1 , wherein the electrode is an anode.
11 . The method of claim 1 , wherein current collector is disposed on a stationary base and the laser beam and powder feeder move in unison at the coating speed relative to a stationary base.
12 . The method of claim 1 , wherein the current collector is disposed on a moving base moving at the coating speed and the laser beam and powder feeder are stationary relative to the moving base.
13 . The method of claim 1 , wherein the electrode is produced in a vacuum-less environment.
14 . The method of claim 1 , wherein the binder is selected from the list consisting of polyvinylidene fluoride (PVDF), Polyacrylic acid (PAA), Polytetrafluoroethylene (PTFE), Polyurethane (PU), and Styrene-butadiene (SBR).
15 . The method of claim 1 , wherein the electrode is a cathode, and the active material comprises Lithium Iron Phosphate (LFP) or Lithium Manganese Oxide (LMO).
16 . The method of claim 1 , wherein the electrode is a cathode and the solvent-free powder further comprises a conductive additive.
17 . The method of claim 1 , wherein the electrode is an anode, and the active material comprises graphite.
18 . The method of claim 1 , wherein the desired temperature is a melting temperature of the binder.
19 . The method of claim 1 , wherein providing the solvent-free powder is responsive to mixing at least the electrode active material and the binder using a mixer.
20 . The method of claim 1 , wherein said feeding is responsive to preheating the current collector and/or solvent-free powder.
21 . The method of claim 1 , further comprising:
measuring a thickness of the coating at a selected surface of the coating; and
responsive to said measured thickness exceeding a defined threshold, automatically controlling one or more parameters of the laser beam and the powder feeder to maintain the desired thickness such that a new measured thickness of a newly created portion of the coating does not exceed the defined threshold.
22 . An apparatus comprising:
a laser system comprising a laser welding head configured to deliver a laser beam, and a laser beam positioning device configured to control the laser beam to oscillate at a selected scan frequency; and
a powder feeder configured to feed a solvent-free powder comprising at least an electrode active material and a binder through a nozzle onto a current collector disposed on a base;
wherein the powder feeder feeds the solvent-free powder on the current collector, concurrently to oscillation of the laser beam such that application of the laser beam to the solvent-free powder at a defined temperature melts the binder of the solvent-free powder to produce a coating on the current collector,
wherein the laser beam is a continuous wave emission laser beam; and
wherein the powder feeder is configured to apply the solvent-free powder in a direction perpendicular to a profile of the laser beam.
23 . The apparatus of claim 22 , wherein the apparatus is configured as an off-axis powder feeding electrode manufacturing system.
24 . The apparatus of claim 23 , wherein the nozzle is a flat nozzle.
25 . The apparatus of claim 22 , wherein the apparatus is configured as a coaxial powder feeding electrode manufacturing system.
26 . The apparatus of claim 22 , wherein the laser welding head is coupled to the powder feeder and moves in unison with the powder feeder.
27 . The apparatus of claim 22 , wherein the current collector is disposed on a moving base that is configured to move relative to the laser beam and powder feeder.
28 . The apparatus of claim 22 , wherein the laser beam has a laser with wavelength of about 1070 nm; and the laser beam is further configured to oscillate at a selected scan width.
29 . The apparatus of claim 22 , wherein the current collector is a cathode current collector.
30 . The apparatus of claim 29 , wherein the solvent-free powder further comprises a conductive additive.
31 . The apparatus of claim 22 , wherein the current collector is an anode current collector.
32 . The apparatus of claim 22 , wherein the apparatus further comprises a housing in which the current collector and base are disposed.
33 . The apparatus of claim 22 , wherein the laser beam positioning device is a galvo mirror.
34 . The apparatus of claim 22 , wherein the laser beam is configured to have a defined scan width and laser power density.
35 . The apparatus of claim 22 , wherein the laser beam is produced using a laser device selected from the list consisting of a fiber laser, a disk laser, a diode laser and a CO 2 laser.
36 . A computer system comprising:
a processor; and
a memory storing instructions that, when executed by the processor, configure the system to:
determine a desired temperature to be produced at a location of application of a laser beam;
control the laser beam to oscillate at a selected scan frequency;
produce an electrode by feeding, via a powder feeder, a solvent-free powder onto a current collector and concurrently applying the laser beam to the solvent-free powder to melt the binder of the solvent-free powder at said desired temperature to produce a coating on the current collector;
wherein the laser beam is operated as a continuous wave emission laser beam; and
wherein the powder feeder is configured to apply the solvent-free powder in a direction perpendicular to a profile of the laser beam.
37 . The computer system of claim 36 , wherein the laser beam is further configured to have a defined scan width and laser power density.
38 . A non-transitory computer-readable storage medium storing instructions that when executed by a computer, cause the computer to:
determine a desired temperature to be produced at a location of application of a laser beam;
control a laser beam to oscillate at a selected scan frequency;
produce an electrode by feeding, via a powder feeder, a solvent-free powder onto a current collector and concurrently applying the laser beam to the solvent-free powder to melt the binder of the solvent-free powder at said desired temperature to produce a coating on the current collector; and
control the powder feeder to apply the solvent-free powder in a direction perpendicular to a profile of the laser beam;
wherein the laser beam is operated as a continuous wave emission laser beam.
39 . The non-transitory computer-readable storage medium of claim 38 , wherein the laser beam is further configured to have a defined scan width and laser power density.
40 . An apparatus comprising:
a laser system comprising a laser welding head configured to deliver a laser beam, a laser beam shaping device configured to produce a line/rectangular beam and a laser beam positioning device configured to move and apply the laser beam; and
a powder feeder configured to feed a solvent-free powder comprising at least an electrode active material and a binder through a nozzle onto a current collector disposed on a base;
wherein the powder feeder feeds the solvent-free powder on the current collector, concurrently to application of the laser beam to the solvent-free powder at a defined temperature such that said application melts the binder of the solvent-free powder to produce a coating on the current collector,
wherein the powder feeder is configured to apply the solvent-free powder in a direction perpendicular to a profile of the laser beam, and
wherein the laser beam is a continuous wave emission laser beam.