Hydrogen isotope concentrating apparatus
To obtain deuterium in a gas state from a mixed gas of hydrogen and deuterium at a low cost. A first electrode 11 is an electrode made of a metal allowing hydrogen (H component and D component) to permeate therethrough (hydrogen permeable metal), and the hydrogen permeable metal is Pd, for example. H ions and D ions having permeated through the first electrode 11 flow to the side of a second electrode 12 in a proton conduction layer 20 . When the first electrode 11 is used as an anode and the second electrode 12 as a cathode, H ions and D ions flow in the proton conduction layer 20 from the left to the right in the drawing. In that case, hydrogen component in an input gas is more likely to flow into an atmosphere on the cathode side than deuterium component, and an H/D composition ratio accordingly becomes higher in a product gas than in the input gas. In an exhaust gas extracted after H and D components in the input gas are thus consumed, D component has been enriched.
1 . A hydrogen isotope concentrating apparatus for outputting an output gas obtained from an input gas in which hydrogen ( 1 H) and a hydrogen isotope, which is an isotope of the hydrogen, are mixed, the output gas having an increased concentration ratio of the hydrogen isotope to the hydrogen than in the input gas,
the hydrogen isotope concentrating apparatus comprising a membrane electrode assembly having:
a proton conduction layer made of a proton conductor to conduct positive ions of hydrogen and having two principal surfaces opposing each other;
a first electrode formed on one of the principal surfaces of the proton conduction layer;
and a second electrode formed on the other one of the principal surfaces of the proton conduction layer,
wherein, in the membrane electrode assembly, a DC voltage is applied between the first electrode and the second electrode, the hydrogen and the hydrogen isotope in the input gas that is in contact with one of the first and second electrodes set to be an anode flow between the first and second electrodes, a product gas is produced at the other one of the first and second electrodes set to be a cathode,
and between the product gas and an exhaust gas corresponding to the input gas after consumption of the hydrogen and the hydrogen isotope for producing the product gas, one having an increased concentration of the hydrogen isotope is extracted as the output gas,
wherein
the first electrode is uniformly made of a film of a hydrogen permeable metal selected from one of palladium (Pd), vanadium (V), tantalum (Ta) and titanium (Ti),
wherein
the second electrode is made of Pt/C catalyst, in which Pt particles are supported on carbon particles.
2 . The hydrogen isotope concentrating apparatus according to claim 1 ,
wherein
the film is an evaporated film of the hydrogen permeable metal.
3 . The hydrogen isotope concentrating apparatus according to claim 1 ,
wherein
a positive potential and a negative potential are applied to the first electrode and the second electrode, respectively, and
the exhaust gas is taken as the output gas.
4 . The hydrogen isotope concentrating apparatus according to claim 1 ,
wherein
a positive potential and a negative potential are applied to the second electrode and the first electrode, respectively, and
the product gas is taken as the output gas.
5 . The hydrogen isotope concentrating apparatus according to claim 1 ,
wherein
the first electrode and the proton conduction layer are in contact with each other across a single atomic layer graphene.
6 . The hydrogen isotope concentrating apparatus according to claim 1 ,
wherein
a plurality of the membrane electrode assemblies are used in a multistage manner from inputting the input gas to outputting the output gas, and
the output gas from the membrane electrode assembly in a preceding stage is used as the input gas to the membrane electrode assembly in a following stage adjacent to the preceding one.
7 . The hydrogen isotope concentrating apparatus according to claim 6 ,
wherein
between the exhaust gas and the product gas of one of the membrane electrode assemblies, one that has not been taken as the output gas is used as the input gas to a membrane electrode assembly in a stage just preceding that of the one of the membrane electrode assemblies.
8 . The hydrogen isotope concentrating apparatus according to claim 6 ,
employing a membrane electrode assembly base material provided with the first electrode, the second electrode and the proton conduction layer,
wherein
the plurality of the membrane electrode assemblies are formed as different regions within a plane in a single body of the membrane electrode assembly base material.
9 . The hydrogen isotope concentrating apparatus according to claim 1 ,
wherein
the hydrogen isotope is deuterium ( 2 H or D) or tritium ( 3 H or T).