Fixing apparatus and electrophotographic image forming apparatus
A fixing apparatus comprising: a fixing film having an endless shape, a pressurizing member disposed to face the fixing film and configured to form a nip with the fixing film, and a heating member disposed inside of the fixing film, having a facing surface facing an inner circumferential surface of the fixing film, and configured to bias the fixing film against the pressurizing member, and a fluorine grease interposed between the inner circumferential surface and the facing surface, wherein the fixing film has at least a base layer, an elastic layer, and a surface layer in this order, the surface layer comprises a PFA, the surface layer comprises a plurality of spherulites of the PFA, and in an endothermic curve measured with a specific condition by a DSC, using a sample sampled from the surface layer, an endothermic quantity in a temperature rising process is 21 J/g or more.
1 . A fixing apparatus, comprising:
a fixing film having an endless shape, the fixing film comprising a base layer, an elastic layer and a surface layer in this order, the surface layer comprising a plurality of spherulites of tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer (PFA);
a pressurizing member disposed to face the fixing film and configured to form a nip with the fixing film;
a heating member disposed inside of the fixing film, having a facing surface facing an inner circumferential surface of the fixing film, and configured to bias the fixing film against the pressurizing member; and
a fluorine grease interposed between the inner circumferential surface and the facing surface, wherein
in an endothermic curve measured at a ramp rate of 20° C./min by a differential scanning calorimeter (DSC), using a sample sampled from the surface layer as a measurement sample, an endothermic quantity in a first temperature rising process is 21 J/g or more, and
a degree of orientation of molecules of the PFA to a direction orthogonal to a circumferential direction of the surface layer, obtained using a transmission X-ray diffraction method, is 35% or less.
2 . The fixing apparatus according to claim 1 , wherein the endothermic quantity in the first temperature rising process is 21 to 40 J/g.
3 . The fixing apparatus according to claim 1 , wherein the surface layer has a thickness within a range from 10 to 100 μm.
4 . The fixing apparatus according to claim 1 , wherein the fluorine grease comprises a fluororesin particle and a fluorinated oil.
5 . An electrophotographic image forming apparatus comprising a fixing apparatus, the fixing apparatus comprising:
a fixing film having an endless shape, the fixing film comprising a base layer, an elastic layer and a surface layer in this order, the surface layer comprising a plurality of spherulites of tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer (PFA);
a pressurizing member disposed to face the fixing film and configured to form a nip with the fixing film;
a heating member disposed inside of the fixing film, having a facing surface facing an inner circumferential surface of the fixing film, and configured to bias the fixing film against the pressurizing member; and
a fluorine grease interposed between the inner circumferential surface and the facing surface, wherein
in an endothermic curve measured at a ramp rate of 20° C./min by a differential scanning calorimeter (DSC), using a sample sampled from the surface layer as a measurement sample, an endothermic quantity in a first temperature rising process is 21 J/g or more, and
a degree of orientation of molecules of the PFA to a direction orthogonal to a circumferential direction of the surface layer, obtained using a transmission X-ray diffraction method, is 35% or less.