IP Library Granted Patent US 12,545,982
Granted Patent B2
US 12,545,982 · App. 16/349,864 · Granted Feb 10, 2026

Hot-rolled and coated steel sheet for hot-stamping, hot-stamped coated steel part and methods for manufacturing the same

Inventors: Thomas Henrion (Valmont, FR); Ronan Jacolot (Landonvillers, FR); Martin Beauvais (Marange Silvange, FR)
Assignee: ArcelorMittal
C22C38/50B21D22/022B32B15/016C21D7/13C21D8/0226C21D8/0278C22C33/04C22C38/001C22C38/002C22C38/02C22C38/04C22C38/06C22C38/44C22C38/48C22C38/54C22C38/58C23C2/02C23C2/0224C23C2/024C23C2/12C23C2/26C23C2/28C23C2/40C23C28/025C21D2211/001C21D2211/005C21D2211/009
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,545,982
App. No.
16/349,864
Granted
Feb 10, 2026
Kind
B2
Abstract

A method for manufacturing a hot-rolled and coated steel sheet having a thickness between 1.8 mm and 5 mm. The method contains the steps of: providing a semi-product having a composition containing: 0.04%≤C≤0.38%, 0.40%≤Mn≤3%, 0.005%≤Si≤0.70%, 0.005%≤Al≤0.1%, 0.001%≤Cr≤2%, 0.001%≤Ni≤2%, 0.001%≤Ti≤0.2%, Nb≤0.1%, B≤0.010%, 0.0005%≤N≤0.010%, 0.0001%≤S≤0.05%, 0.0001%≤P≤0.1%, Mo≤0.65%, W≤0.30%, Ca≤0.006%, hot-rolling with a final rolling temperature FRT, to obtain a hot-rolled steel product having a thickness between 1.8 mm and 5 mm, then cooling down to a coiling temperature T coil satisfying: 450° C.≤T coil ≤T coilmax with T coilmax=650−140×fγ , T coilmax being expressed in degrees Celsius and fγ designating the austenite fraction just before the coiling, and coiling to obtain a hot-rolled steel substrate, pickling and coating the hot-rolled steel substrate with Al or an Al alloy by continuous hot-dipping in a bath, to obtain a hot-rolled and coated steel sheet containing a hot-rolled steel sheet and an Al or an Al alloy coating, having a thickness between 10 and 33 μm, on each side of the hot-rolled steel sheet.

Claims (158)

1 . A hot-rolled and coated steel sheet, comprising:

(i) a hot-rolled steel sheet having a thickness between 1.8 mm and 5 mm, the hot-rolled steel sheet not being cold-rolled, the hot-rolled steel sheet being made of a steel having a composition comprising, by weight percent:

0.04%≤C≤0.38%,

0.40%≤Mn≤3%,

0.005%≤Si≤0.70%,

With Si/Mn≤0.22,

0.005%≤Al≤0.1%,

0.001%≤Cr≤2%,

0.001%≤Ni≤2%,

0.001%≤Ti≤0.2%,

Nb≤0.1%,

B≤0.010%,

0.0005%≤N≤0.010%,

0.0001%≤S≤0.05%,

0.0001%≤P≤0.1%,

Mo≤0.65%,

0.001%≤W≤0.30%,

Ca≤0.006%,

a balance of the composition consisting of iron and unavoidable impurities resulting from smelting,

said hot-rolled steel sheet having a depth of intergranular oxidation of less than 4 μm, said hot-rolled steel sheet having a structure consisting of ferrite and pearlite, and

(ii) an Al or an Al alloy coating, having a thickness between 10 and 33 μm, on each side of the hot-rolled steel sheet.

2 . The hot-rolled and coated steel sheet according to claim 1 , wherein the composition comprises, by weight percent:

0.04%≤C≤0.38%,

0.40%≤Mn≤3%,

0.005%≤Si≤0.70%,

0.005%≤Al≤0.1%,

0.001%≤Cr≤2%,

0.001%≤Ni≤0.1%,

0.001%≤Ti≤0.2%,

Nb≤0.1%,

B≤0.010%,

0.0005%≤N≤0.010%,

0.0001%≤S≤0.05%,

0.0001%≤P≤0.1%,

Mo≤0.65%,

W≤0.30%

Ca≤0.006%,

the balance of the composition consisting of iron and unavoidable impurities resulting from the smelting.

3 . The hot-rolled and coated steel sheet according to claim 2 , wherein the composition comprises, by weight percent:

0.04%≤C≤0.38%,

0.5%≤Mn≤3%,

0.005%≤Si≤0.5%,

0.005%≤Al≤0.1%,

0.001%≤Cr≤1%,

0.001%≤Ni≤0.1%,

0.001%≤Ti≤0.2%,

Nb≤0.1%,

B≤0.010%,

0.0005%≤N≤0.010%,

0.0001%≤S≤0.05%,

0.0001%≤P≤0.1%,

Mo≤0.10%,

Ca≤0.006%,

the balance of the composition consisting of iron and unavoidable impurities resulting from the smelting.

4 . The hot-rolled and coated steel sheet according to claim 1 , wherein the composition comprises, by weight percent: 0.075%≤C≤0.38%.

5 . The hot-rolled and coated steel sheet according to claim 1 , wherein the composition comprises, by weight percent:

0.040%≤C≤0.100%,

0.80%≤Mn≤2.0%,

0.005%≤Si≤0.30%,

0.010%≤Al≤0.070%,

0.001%≤Cr≤0.10%,

0.001%≤Ni≤0.10%,

0.03%≤Ti≤0.08%,

0.015%≤Nb≤0.1%,

0.0005%≤N≤0.009%,

0.0001%≤S≤0.005%,

0.0001%≤P≤0.030%,

Mo≤0.10%,

Ca≤0.006%,

the balance of the composition consisting of iron and unavoidable impurities resulting from the smelting.

6 . The hot-rolled and coated steel sheet according to claim 1 , wherein the composition comprises, by weight percent:

0.062%≤C≤0.095%,

1.4%≤Mn≤1.9%,

0.2%≤Si≤0.5%,

0.020%≤Al≤0.070%,

0.02%≤Cr≤0.1%,

wherein 1.5%≤(C+Mn+Si+Cr)≤2.7%,

3.4×N≤Ti≤8×N,

0.04%≤Nb≤0.06%,

wherein 0.044%≤(Nb+Ti)≤0.09%,

0.0005%≤B≤0.004%,

0.001%≤N≤0.009%,

0.0005%≤S≤0.003%,

0.001%≤P≤0.020%,

and optionally 0.0001%≤Ca≤0.006%,

the balance of the composition consisting of iron and unavoidable impurities resulting from the smelting.

7 . The hot-rolled and coated steel sheet according to claim 1 , wherein the composition comprises, by weight percent:

0.15%≤C≤0.38%,

0.5%≤Mn≤3%,

0.10%≤Si≤0.5%,

0.005%≤Al≤0.1%,

0.01%≤Cr≤1%,

0.001%≤Ti≤0.2%,

0.0005%≤B≤0.010%,

0.0005%≤N≤0.010%,

0.0001%≤S≤0.05%,

0.0001%≤P≤0.1%,

the balance of the composition consisting of iron and unavoidable impurities resulting from the smelting.

8 . The hot-rolled and coated steel sheet according to claim 1 , wherein the hot-rolled and coated steel sheet further comprises, on each side, a Zn coating having a thickness lower than or equal to 1.1 μm.

9 . The hot-rolled and coated steel sheet according to claim 1 , wherein the depth of intergranular oxidation is lower than 3 μm.

10 . The hot-rolled and coated steel sheet according to claim 1 , wherein the depth of intergranular oxidation is 2 μm or less.

11 . The hot-rolled and coated steel sheet according to claim 1 , wherein the hot-rolled steel sheet has no intergranular oxidation.

12 . The hot-rolled and coated steel sheet according to claim 1 , wherein the composition of the steel comprises, by weight percent 0.15%≤C≤0.38%.

13 . The hot-rolled and coated steel sheet according to claim 12 , wherein the composition of the steel comprises, by weight percent 0.40%≤Mn≤1.9%.

14 . The hot-rolled and coated steel sheet according to claim 1 , wherein the composition of the steel comprises, by weight percent 0.40%≤Mn≤1.9%.

15 . The hot-rolled and coated steel sheet according to claim 1 , wherein the composition comprises, by weight percent 0.36%≤Si≤0.70%.

16 . The hot-rolled and coated steel sheet according to claim 1 , wherein the composition of the steel comprises, by weight percent 0.027%≤Cr≤0.354%.

17 . The hot-rolled and coated steel sheet according to claim 1 , wherein a surface percentage of porosities in the coating is lower than or equal to 3%.

18 . The hot-rolled and coated steel sheet according to claim 1 , wherein an intermetallic layer of the coating has a thickness of less than 15 μm.

19 . The hot-rolled and coated steel sheet according to claim 1 , wherein the composition of the steel comprises, by weight percent 0.15%≤Mo≤0.25%.

20 . The hot-rolled and coated steel sheet according to claim 1 , wherein the composition of the steel comprises, by weight percent 0.541%≤Si≤0.70%.

21 . The hot-rolled and coated steel sheet according to claim 1 , wherein the composition of the steel comprises, by weight percent 0.111%≤Cr≤2%.

22 . The hot-rolled and coated steel sheet according to claim 1 , wherein the composition of the steel comprises, by weight percent 0.111%≤Cr≤0.354%.

23 . The hot-rolled and coated steel sheet according to claim 1 , wherein the composition of the steel comprises, by weight percent 0.25%≤Ni≤2%.

24 . The hot-rolled and coated steel sheet according to claim 1 , wherein the composition of the steel comprises, by weight percent Nb≤0.01%.

25 . The hot-rolled and coated steel sheet according to claim 1 , wherein the depth of intergranular oxidation is of 2 μm or more and 4 μm or less.

26 . The hot-rolled and coated steel sheet according to claim 1 , wherein the depth of intergranular oxidation is of 2 μm or more and 3 μm or less.

27 . A hot-rolled and coated steel sheet, comprising:

(i) a hot-rolled steel sheet having a thickness between 1.8 mm and 5 mm, the hot-rolled steel sheet not being cold-rolled, the hot-rolled steel sheet being made of a steel having a composition comprising, by weight percent:

0.15%≤C≤0.38%,

0.40%≤Mn≤3%,

0.005%≤Si≤0.70%,

With Si/Mn≤0.22,

0.005%≤Al≤0.1%,

0.001%≤Cr≤2%,

0.001%≤Ni≤2%,

0.001%≤Ti≤0.2%,

Nb≤0.1%,

B≤0.010%,

0.0005%≤N≤0.010%,

0.0001%≤S≤0.05%,

0.0001%≤P≤0.1%,

Mo≤0.65%,

W≤0.30%,

Ca≤0.006%,

a balance of the composition consisting of iron and unavoidable impurities resulting from smelting,

said hot-rolled steel sheet having a depth of intergranular oxidation of less than 4 μm, said hot-rolled steel sheet having a structure consisting of ferrite and pearlite, and

(ii) an Al or an Al alloy coating, having a thickness between 10 and 33 μm, on each side of the hot-rolled steel sheet.

28 . A hot-rolled and coated steel sheet, comprising:

(i) a hot-rolled steel sheet having a thickness between 1.8 mm and 5 mm, the hot-rolled steel sheet not being cold-rolled, the hot-rolled steel sheet being made of a steel having a composition comprising, by weight percent:

0.04%≤C≤0.38%,

0.40%≤Mn≤3%,

0.005%≤Si≤0.36%,

0.005%≤Al≤0.1%,

0.001%≤Cr≤2%,

0.001%≤Ni≤2%,

0.001%≤Ti≤0.2%,

Nb≤0.1%,

B≤0.010%,

0.0005%≤N≤0.010%,

0.0001%≤S≤0.05%,

0.0001%≤P≤0.1%,

Mo≤0.65%,

0.001%≤W≤0.30%,

Ca≤0.006%,

a balance of the composition consisting of iron and unavoidable impurities resulting from smelting,

said hot-rolled steel sheet having a depth of intergranular oxidation of less than 4 μm, said hot-rolled steel sheet having a structure consisting of ferrite and pearlite, and

(ii) an Al or an Al alloy coating, having a thickness between 10 and 33 μm, on each side of the hot-rolled steel sheet.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 17, 2019
From: HENRION, THOMAS; JACOLOT, RONAN; BEAUVAIS, MARTIN
To: ARCELORMITTAL
Reel/Frame 049206/0224 →
Priority Claims (1)
WO PCT/IB2016/057100 · Nov 24, 2016 · international
Continuity (1)
Related Publication 20200224297A1 · Jul 16, 2020
References Cited (32)
US 8066829B2 · Spehner · 2011 [cited by examiner]
US 20090071575A1 · Sun · 2009 [cited by applicant]
US 20100026048A1 · Vlot · 2010 [cited by applicant]
US 20120085467A1 · Thirion · 2012 [cited by examiner]
US 20140030544A1 · Maki · 2014 [cited by examiner]
US 20140216612A1 · Laurent et al. · 2014 [cited by applicant]
US 20150017471A1 · Shuto et al. · 2015 [cited by applicant]
US 20150122377A1 · Bocharova · 2015 [cited by examiner]
US 20170198374A1 · Allelly et al. · 2017 [cited by applicant]
US 20170253941A1 · Cobo et al. · 2017 [cited by applicant]
US 20170369964A1 · Fujii et al. · 2017 [cited by applicant]
US 20180119240A1 · Tanaka et al. · 2018 [cited by applicant]
EP 2728032A2 · 2014 [cited by applicant]
EP 2995696A1 · 2016 [cited by applicant]
EP 3279353A1 · 2018 [cited by applicant]
JP 2003171752A · 2003 [cited by examiner]
JP 200520477A · 2005 [cited by examiner]
JP 2005205477A · 2005 [cited by applicant]
JP 2010521584A · 2010 [cited by applicant]
JP 2013122076A · 2013 [cited by applicant]
KR 20140098841 · 2014 [cited by applicant]
KR 20160015388 · 2016 [cited by applicant]
WO 2008053273A1 · 2008 [cited by applicant]
WO WO2010085983A1 · 2010 [cited by applicant]
WO 2015181318A1 · 2015 [cited by applicant]
WO 2016016707A1 · 2016 [cited by applicant]
WO WO2016079675A1 · 2016 [cited by applicant]
WO WO2016152870A1 · 2016 [cited by applicant]
WO 2016157896A1 · 2016 [cited by applicant]
Bucher et al. (“Strength and toughness of hot-rolled ferrite-pearlite steels.” Fracture of Metals. Academic Press, 1969. 247-298.) (Year: 1969). [cited by examiner]
The International Search Report issued in connection with International application No. PCT/IB2017/057370 on Mar. 26, 2018. [cited by applicant]
The International Search Report issued in connection with International application No. PCT/IB2016/057100 on Jul. 25, 2017. [cited by applicant]