Granted Patent B2

US 12,570,793 · App. 17/984,947 · Granted Mar 10, 2026

Inventors: Tarun Joshi (Salalah, OM); Muteeb Siddiqui (Salalah, OM); Klaus Haarmann (Salalah, OM); Jerry Bradnam (Salalah, OM); Sean Brown (Monclova, OH); Mohammed Razeem (Plano, TX); William J. Barenberg (Plano, TX); Nicholas P. Barakat (Muscat, OM)

Assignee: OCTAL SAOC FZC

C08G63/183C08G63/785C08J3/22C08J11/14C08J11/24C08J11/26C08K3/22C08K3/26C08K3/30C08K3/34C08J2367/02C08K2003/2227C08K2003/265C08K2003/3045

Abstract

Claims (112)

1 . A method for forming additive-containing reclaimed polyester in a continuous process, wherein the method comprises the following steps:

(a) providing a feed of recycled polyester upstream of a de-polymerization reaction vessel and/or a polymerization reaction vessel, wherein the feed of recycled polyester includes polyester particles, off spec polyester flake, off spec polyester resin, or other form of polyester particles, flakes, or resin;

(b) providing a PET depolymerizer upstream of the de-polymerization reaction vessel and/or the polymerization reaction vessel, wherein the PET depolymerizer is one or more selected from the group consisting of water, acidic water, alkaline water, methanol, aqueous methanol, ethylene glycol, and aqueous ethylene glycol; and allowing the PET depolymerizer to intermingle with the feed of recycled polyester, thereby depolymerizing the recycled polyester feed via glycolysis, methanolysis, or hydrolysis to obtain depolymerized polyester monomers;

(c) providing a feed of polyester precursors upstream of the polymerization reaction vessel such that the feed of polyester precursors intermingles with the depolymerized polyester monomers; and removing the PET depolymerizer from the polymerization reaction vessel subsequent to depolymerization of the recycled polyester and prior to polymerization in the continuous process;

(d) polymerizing the depolymerized polyester monomers and the polyester precursors to form reclaimed polyester; and

(e) continuously and directly transferring the reclaimed polyester to a mixing device wherein at least one additive is added to the reclaimed polyester to form additive-containing reclaimed polyester; and

wherein the recycled polyester feed is depolymerized in the de-polymerization reaction vessel, and the recycled polyester feed is depolymerized from the polymerization reaction vessel;

wherein the reclaimed polyester prior to step (e) is characterized as virgin polyester or is indistinguishable from virgin polyester.

2 . The method of claim 1 , wherein the mixing device is a kneader or compounder.

3 . The method of claim 1 , wherein the at least one additive is selected from an organic filler, an inorganic filler, a viscosity enhancer, a liquid additive, and/or a solid masterbatch.

4 . The method of claim 3 , wherein the inorganic filler is selected from the group consisting of calcium carbonate, kaolin (hydrous aluminum silicate), alumina trihydrate, calcium sulfate, and talc.

5 . The method of claim 1 , wherein the at least one additive is a solid masterbatch.

6 . The method of claim 1 , wherein the at least one additive is a liquid additive.

7 . The method of claim 1 , wherein one or more of:

(a) the de-polymerization reaction vessel and/or polymerization reaction vessel receives one or more PET depolymerizers selected from:

(1) water;

(2) methanol;

(3) acid or base; and

(4) ethylene glycol;

(b) one or more of:

(1) the PET depolymerizer is water and the water de-polymerizes the recycled polyester to produce terephthalic acid and ethylene glycol;

(2) the PET depolymerizer is methanol and the methanol de-polymerizes the recycled polyester to produce dimethyl terephthalate and ethylene glycol;

(3) the PET depolymerizer is acid and the acid or base is in aqueous form and de-polymerizes the recycled polyester to produce terephthalic acid and ethylene glycol; or

(4) the PET depolymerizer is ethylene glycol and the ethylene glycol de-polymerizes the recycled polyester to produce bis-hydroxyethyl terephthalate (BHET).

8 . The method of claim 1 , wherein:

the feed of recycled polyester includes PAT; and

the feed of recycled polyester includes PET, in the amount of 0-10%, 0-20%, 0-30%, 0-40%, 0-50%, 0-60%, 0-70%, 0-80%, 0-90%, or 0-100%.

9 . The method of claim 7 , wherein:

the de-polymerization reaction vessel and/or polymerization reaction vessel is any continuous reaction vessel, which may be configured as a mixer capable of mixing liquid polyester in continuous formats, a single screw mixer, double-screw mixer, continuous kneader, reciprocating screw mixer, twin-screw extruder, or continuous plow mixer; and

the de-polymerization reaction vessel and/or polymerization reaction vessel also performs one or more of: degassing, homogenizing, dispersing, or heating.

10 . The method of claim 1 , wherein the method further comprises step (f):

providing the additive-containing reclaimed polyester as output to an output system; and wherein:

the output system provides the additive-containing reclaimed polyester to storage or a polyester product formation system or an analytical system; and

the analytical system includes one or more analytical systems capable of:

determining the intrinsic viscosity of the additive-containing reclaimed polyester;

determining flow rate of the additive-containing reclaimed polyester;

determining melting point of the additive-containing reclaimed polyester;

determining crystallization temperature of the additive-containing reclaimed polyester;

determining a differential scanning calorimetry profile of the additive-containing reclaimed polyester; or

determining heat distortion temperature of the additive-containing reclaimed polyester.

11 . The method of claim 1 , the method further comprises step (f):

providing the additive-containing reclaimed polyester as output to an output system; and wherein:

the output system provides the additive-containing reclaimed polyester to storage or a polyester product formation system or an analytical system; and

the polyester product formation system is configured to one or more of:

form a product from only the additive-containing reclaimed polyester; or

combine the additive-containing reclaimed polyester with a second feed of polyester (second PAT feed) to produce a product of a polyester alloy.

12 . The method of claim 1 , wherein at least one of:

(a) one or more of:

(1) the feed of recycled polyester is devoid of another polymer; or

(2) the polyester precursors is devoid of another polymer;

(b) one or more of:

(1) the feed of recycled polyester consists essentially of PAT;

(2) the feed of recycled polyester consists of PAT;

(3) the polyester precursors consist essentially of PAT precursors; or

(4) the polyester precursors consist of PAT precursors;

(c) one or more of:

(1) the feed of recycled polyester consists essentially of PET;

(2) the feed of recycled polyester consists of PET;

(3) the polyester precursors consist essentially of PET precursors; or

(4) the polyester precursors consists of PET precursors;

(d) the recycled polyester includes recycled PET flake or off spec PET resin, the recycled PET flake or off spec PET resin includes PET in the amount of 0-10%, 0-20%, 0-30%, 0-40%, 0-50%, 0-60%, 0-70%, 0-80%, 0-90%, or 0-100%;

(e) the feed of recycled polyester includes water at an amount less than 5%, less than 1%, less than 0.1%, at a trace amount of water, or is devoid of water; or

(f) the polymerization reaction vessel receives the polyester precursors from precursor storage, each precursor being stored separately or in any un-reacting combination.

13 . The method of claim 1 , wherein the method comprises

one or more of:

depolymerizing the recycled polyester before mixing with the polyester precursors; and

depolymerizing the recycled polyester during or after mixing with the polyester precursors; and

polymerizing the depolymerized polyester monomers with the polyester precursors to form a reclaimed polyester from polymerizable reagents that polymerize to form PET.

14 . The method of claim 1 , wherein one or more of:

the polymerizing further comprises polymerizing the depolymerized polyester monomers with the polyester precursors to form the reclaimed polyester from polymerizable reagents that polymerize to form PET;

the polyester precursors include first precursors that react with second precursors to form polyester; and

one or more of:

the polyester precursors comprise PET precursors that include: (1) a first PET precursor including a PTA and/or DMT; and (2) a second PET precursor including a MEG and/or DEG;

the polyester precursors include Cyclohexanedimethanol and the product is glycolized polyester;

the polyester precursors include IPA;

the first precursors are provided separately from the second precursors;

the first precursors are mixed with the second precursors under non-polymerizing conditions;

the first precursors are mixed with the second precursors to form a precursor mixture, and the recycled polyester is mixed into the precursor mixture;

the first precursors are mixed with the second precursors to form a precursor mixture, and the recycled polyester and/or depolymerized polyester monomers are mixed into the precursor mixture; and

the first precursors are mixed with the second precursors to form a precursor mixture, and the depolymerized polyester monomers are mixed into the precursor mixture.

15 . The method of claim 1 , wherein:

the polymerizing further comprises polymerizing the depolymerized polyester monomers with the polyester precursors to form a reclaimed polyester from polymerizable reagents that polymerize to form PET;

the polyester precursors include first precursors that react with second precursors to form polyester; and

the method further comprises at least one of:

(1)

mixing the first precursors with the second precursors to form a precursor mixture;

mixing the recycled polyester into the precursor mixture to form a depolymerization mixture; and

performing the depolymerization with the depolymerization mixture;

(2)

mixing the first precursors with the second precursors to form a precursor mixture;

mixing the depolymerized polyester monomers into the precursor mixture to form a polymerization mixture; and

performing the polymerization with the polymerization mixture; and

(3) performing the depolymerization with the recycled polyester before being mixed with the first precursor and second precursor.

16 . The method of claim 1 , wherein one or more of:

(a) the depolymerizing further comprises performing a first depolymerization and a second depolymerization;

the polymerizing further comprises performing a first polymerization and a second polymerization; and

repeating a depolymerization-polymerization cycle for n cycles, wherein n is an integer;

(b) introducing the recycled polyester upstream of the de-polymerization reaction vessel and/or the polymerization reaction vessel;

depolymerizing the recycled polyester in the de-polymerization reaction vessel and/or the polymerization reaction vessel; and

polymerizing the depolymerized polyester monomers with the polyester precursors polymerization reaction vessel;

(c) the polymerizing occurs between about 200° C. and about 330° C.;

(d) the polyester precursors comprise precursors that include: (1) a first precursor including a PTA and/or DMT and/or IPA; and (2) a second PET precursor including a MEG and/or DEG and/or PETG;

(e) the recycled polyester has a weight percentage of between 1 and 50% of total polymerizing composition weight of the reclaimed polyester;

(f) the recycled polyester includes post-industrial flake, cleaned and/or washed post-consumer flake; or

(g) the method further comprises outputting the additive-containing reclaimed polyester as:

a chip stream for forming pellets; or

a polyester sheet.

17 . The method of claim 1 , wherein the method further comprising:

controlling at least one output mass flow by controlling the pressure of the additive-containing reclaimed polyester melt with pressure control loops prior to forming a product, wherein

the controlling is in a die flowing system that includes the use of an outlet pump, the outlet pump directly controlling the flow in the die flowing system.

18 . The method of claim 1 , wherein the PET depolymerizer is one or more selected from the group consisting of water, acidic water, alkaline water, methanol, and ethylene glycol.

19 . The method of claim 1 , wherein the PET depolymerizer is removed by distillation.

Assignments (1)

Continuity (3)

References Cited (113)