Method of dispersing hydrophobic substances in aqueous cleansing system
This disclosure relates to a method for making a dispersion, comprising preparing an aqueous phase comprising water and a surfactant; combining a hydrophobic substance and a plurality of particles comprising cellulose to form a concentrate; and mixing the aqueous phase and concentrate to provide a dispersion. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.
1 . A method for making a dispersion, the method comprising:
(a) preparing an aqueous phase comprising water and a surfactant in an amount of from 30 to 40 wt % based on the total weight of the aqueous phase, wherein the surfactant is a sulfate, sulfonate, isethionate, carboxylate, sarcosinate, amino acid-based surfactant, non-ionic surfactant, soap, sulfoacetate, or a combination thereof;
(b) preparing a hydrophobic phase at ambient temperature, wherein the hydrophobic phase comprises: comprising
(i) a hydrophobic substance in an amount of from 40 to 60 wt % based on the total weight of the hydrophobic phase,
(ii) water in an amount of from 20 to 50 wt % based on the total weight of the hydrophobic phase, and
(iii) a plurality of particles comprising cellulose in an amount of from 20 to 30 wt % based on the total weight of the hydrophobic phase,
wherein the hydrophobic substance comprises an oil, a silicone, a fat, an emollient, a triester of glycerol, or a combination thereof, and
wherein the particles have:
(i) a mean particle size of from about 0.1 to about 100 microns;
(ii) an aspect ratio of from about 1 to about 1.5; and
(iii) a non-spherical shape,
wherein at least a portion of the cellulose is type-II cellulose, thereby providing a concentrate; and
(c)-mixing the aqueous phase and the concentrate at ambient temperature, thereby providing the dispersion.
2 . The method of claim 1 , wherein the particles comprise lignin.
3 . The method of claim 2 , wherein the weight % of lignin in the particles is from about 1 to about 30.
4 . The method of claim 1 , wherein the particles have a crystallinity determined by x-ray diffraction (XRD) of 60% or more.
5 . The method of claim 1 , wherein the particles have a d75 of less than 25microns and/or a d50 of from about 0.5 microns to 20 microns.
6 . The method of claim 1 , wherein the aqueous phase, the concentrate, and the dispersion are substantially free of volatile organic solvent.
7 . The method of claim 1 , wherein the concentrate is not contacted with a surfactant prior to step (c).
8 . The method of claim 1 , wherein the surfactant has a hydrophile-lipophile balance (HLB) number of greater than 10.
9 . The method of claim 1 , wherein the hydrophobic substance is synthetic or derived from a plant or other organic matter.
10 . The method of claim 1 , wherein the hydrophobic substance and the plurality of particles are combined with a preservative during step (b).
11 . The method of claim 1 , wherein the weight % of the hydrophobic substance in the dispersion is at least 10.
12 . The method of claim 1 , wherein the dispersion is a homogeneous dispersion.
13 . The method of claim 1 , wherein the dispersion is a stable emulsion.
14 . A method for making a dispersion, the method comprising:
(a) preparing an aqueous phase comprising water and a surfactant, wherein the surfactant is a sulfate, sulfonate, isethionate, carboxylate, sarcosinate, amino acid-based surfactant, non-ionic surfactant, soap, sulfoacetate, or a combination thereof,
wherein the ratio of the surfactant to the water in the aqueous phase ranges from 0.7 to 1.5;
(b) preparing a hydrophobic phase at ambient temperature, wherein the hydrophobic phase comprises comprising a hydrophobic substance, water, and a plurality of particles comprising lignin and cellulose, at least a portion of which is type-II cellulose, wherein the hydrophobic substance comprises an oil, a silicone, a fat, an emollient, a triester of glycerol, or a combination thereof, and wherein the particles have:
(i) a mean particle size of from about 0.1 to about 100 microns;
(ii) an aspect ratio of from about 1 to about 1.5; and
(iii) a non-spherical shape,
thereby providing a concentrate; and
(d) mixing the aqueous phase and the concentrate at ambient temperature, thereby providing the dispersion,
wherein the weight % of the hydrophobic substance in the concentrate prior to step (c) is from about 40 to about 60;
wherein the ratio of the hydrophobic substance to the plurality of particles in the concentrate prior to step (c) is from about 10:1 to about 2:1 about 6:1;
wherein the ratio of the hydrophobic substance to the water in the concentrate prior to step (c) is from about 1:1 to about 2:1,
wherein the weight % of water in the concentrate prior to step (c) is from about 20 to about 50; and
wherein the weight % of particles in the concentrate prior to step (c) is from about 0.05 to about 30.
15 . A dispersion prepared by the method of claim 1 , the method comprising:
(a) preparing an aqueous phase comprising water and a surfactant in an amount of from 30 to 40 wt % based on the total weight of the aqueous phase, wherein the surfactant is a sulfate, sulfonate, isethionate, carboxylate, sarcosinate, amino acid-based surfactant, non-ionic surfactant, soap, sulfoacetate, or a combination thereof,
(b) preparing a hydrophobic phase at ambient temperature, wherein the hydrophobic phase comprises:
(i) hydrophobic substance in an amount of from 40 to 60 wt % based on the total weight of the hydrophobic phase,
(ii) water in an amount of from 20 to 50 wt % based on the total weight of the hydrophobic phase, and
(iii) a plurality of particles comprising cellulose in an amount of from 20 to 30 wt % based on the total weight of the hydrophobic phase,
wherein the hydrophobic substance comprises an oil, a silicone, a fat, an emollient, a triester of glycerol, or a combination thereof, and
wherein the particles have:
(i) a mean particle size of from about 0.1 to about 100 microns;
(ii) an aspect ratio of from about 1 to about 1.5; and
ii) a non-spherical shape,
wherein at least a portion of the cellulose is type-Il cellulose, thereby providing a concentrate; and
(c) mixing the aqueous phase and the concentrate at ambient temperature, thereby providing the dispersion.
16 . A powder, grain, paste, concentrate, or foam comprising the dispersion of claim 15 .
17 . A cleaning product comprising the dispersion of claim 15 .
18 . A personal or beauty product comprising the dispersion of claim 15 .