Method for producing acrylic acid
Provided is a method for producing acrylic acid, the method including: preparing a reaction product containing acrylic acid by supplying lactic acid to a reactor and performing a dehydration reaction; supplying a reactor discharge stream containing the reaction product to a cooling tower and condensing the result to transfer a lower discharge stream including a condensate to an acrylic acid purification unit and supplying a non-condensate discharged as an upper discharge stream to a distillation tower; and, in the distillation tower, circulating the lower discharge stream containing acrylic acid to the cooling tower, and removing acetaldehyde from the upper discharge stream.
1 . A method for producing acrylic acid, the method comprising the following steps in sequence:
preparing a reaction product including acrylic acid by supplying lactic acid to a reactor and performing a dehydration reaction;
supplying a reactor discharge stream including the reaction product to a cooling tower that condenses through cooling the reactor discharge stream in a gas phase to yield a condensate and a non-condensate and transferring a lower discharge stream including the condensate to an acrylic acid purification unit, and supplying the non-condensate discharged as an upper discharge stream to a distillation tower; and
in the distillation tower, circulating a distillation tower lower discharge stream including acrylic acid to the cooling tower, and removing acetaldehyde from a distillation tower upper discharge stream,
wherein the cooling tower has an operation pressure of 200 kPa to 1000 kPa, and the distillation tower has an operation pressure of 100 kPa to 900 kPa, and
wherein the operation pressure of the distillation tower is lower than the operation pressure of the cooling tower,
wherein a partial stream of the cooling tower lower discharge stream is refluxed to the cooling tower after passing through a first cooler,
wherein the distillation tower lower discharge stream is heated by going through a reboiler before being circulated to the cooling tower, and then a partial stream is circulated to the cooling tower and the remaining stream is refluxed to the distillation tower, and
the heat source of the reboiler uses the heat removed from the first cooler.
2 . The method of claim 1 , wherein a partial stream of the cooling tower lower discharge stream passing through the first cooler further passes through a second cooler, and refluxed to the cooling tower.
3 . The method of claim 1 , wherein the distillation tower lower discharge stream is, before being circulated to the cooling tower, supplied to the first cooler and heat exchanged with a partial stream of the cooling tower lower discharge stream, and a partial stream of the heat exchanged stream is circulated to the cooling tower and the remaining stream is refluxed to the distillation tower.
4 . The method of claim 1 , wherein the operation pressure of the distillation tower is lower than the operation pressure of the cooling tower by 20 kPa to 900 kPa.
5 . The method of claim 1 , wherein a flow rate of acetaldehyde in the cooling tower lower discharge stream is 3% or less with respect to a flow rate of acetaldehyde in the reactor discharge stream.
6 . The method of claim 1 , wherein a flow rate of acrylic acid in the distillation tower upper discharge stream is 3% or less with respect to a flow rate of acrylic acid in the reactor discharge stream.