Processes for cofeeding waste plastic and bio feedstocks to a refinery processing unit
A continuous process for transporting one or more waste plastic feedstocks to a refinery processing unit, includes receiving, in a blending unit, one or more waste plastic feedstocks, one or more waste plastic-immiscible bio feedstocks and a recycled inert carrier fluid received from a refinery processing unit, generating, in the blending unit, a homogeneous solution comprising the one or more waste plastic feedstocks, the one or more waste plastic-immiscible bio feedstocks and the recycled inert carrier fluid, and processing the homogeneous solution in the presence of a catalyst under catalytic cracking conditions in the refinery processing unit.
1 . A continuous process, comprising:
receiving, in a blending unit, one or more waste plastic feedstocks, one or more waste plastic-immiscible bio feedstocks, one or more waste plastic-miscible bio feedstocks, and a recycled inert carrier fluid comprising a light cycle oil received from a refinery processing unit, wherein the recycled inert carrier fluid has a conversion rate in the refinery processing unit of less than about 10% using a ZSM-5 catalyst, or a conversion rate in the refinery processing unit of less than about 25% using an ECAT catalyst;
generating, in the blending unit, a homogeneous solution comprising the one or more waste plastic feedstocks, the one or more waste plastic-immiscible bio feedstocks the one or more waste plastic-miscible bio feedstocks, and the recycled inert carrier fluid; and
processing the homogeneous solution in the presence of a catalyst under catalytic cracking conditions in the refinery processing unit, thereby producing a processed homogeneous solution.
2 . The continuous process according to claim 1 , wherein the one or more waste plastic feedstocks comprise one or more polyesters, one or more polyolefins or combinations thereof.
3 . The continuous process according to claim 1 , wherein the one or more waste plastic feedstocks comprise one of a polyethylene waste plastic or a polypropylene waste plastic.
4 . The continuous process according to claim 1 , wherein the one or more waste plastic-immiscible bio feedstocks have an iodine number greater than 95.
5 . The continuous process according to claim 1 , wherein the one or more waste plastic-immiscible bio feedstocks have an iodine number greater than 120.
6 . The continuous process according to claim 1 , wherein the one or more waste plastic feedstocks comprise one of a polyethylene waste plastic or a polypropylene waste plastic and the one or more waste plastic-immiscible bio feedstocks comprise soybean oil.
7 . The continuous process according to claim 1 , wherein the recycled inert carrier fluid is characterized as follows:
having a total paraffin content of less than or equal to about 20 wt. %; and
a total aromatics content of from about 50 wt. % to about 99 wt. %.
8 . The continuous process according to claim 1 , wherein generating the homogeneous solution comprises dissolving the one or more waste plastic feedstocks in the recycled inert carrier fluid.
9 . The continuous process according to claim 1 , wherein the homogeneous solution comprises about 1 to about 20 wt. %, based on a total weight of the homogeneous solution, of the one or more waste plastic feedstocks, about 1 to about 50 wt. %, based on the total weight of the homogeneous solution, of the one or more waste plastic-immiscible bio feedstocks, and about 40 to about 98 wt. %, based on the total weight of the homogeneous solution, of the recycled inert carrier fluid received from a refinery processing unit.
10 . The continuous process according to claim 1 , further comprising:
separating the recycled inert carrier fluid from the processed homogeneous solution;
receiving, in the blending unit, one or more other waste plastic feedstocks, one or more other waste plastic-immiscible bio feedstocks, and the separated recycled inert carrier fluid;
generating, in the blending unit, another homogeneous solution comprising the one or more other waste plastic feedstocks, the one or more other waste plastic-immiscible bio feedstocks and the separated recycled inert carrier fluid; and
processing the other homogeneous solution in the presence of another catalyst under catalytic cracking conditions in the refinery processing unit.
11 . The continuous process according to claim 1 , wherein the one or more waste plastic-miscible bio feedstocks comprise a polyunsaturated triglyceride.
12 . A continuous process, comprising:
adding a recycled inert carrier fluid comprising a light cycle oil received from a refinery processing unit, wherein the recycled inert carrier fluid has a conversion rate in the refinery processing unit of less than about 10% using a ZSM-5 catalyst, or a conversion rate in the refinery processing unit of less than about 25% using an ECAT catalyst, to a non-homogeneous mixture comprising one or more waste plastic feedstocks, one or more waste plastic-immiscible bio feedstocks and one or more waste plastic-miscible bio feedstocks to form a homogeneous solution comprising the one or more waste plastic feedstocks, the one or more waste plastic-immiscible bio feedstocks, the one or more waste plastic-miscible bio feedstocks, and the recycled inert carrier fluid; and
processing the homogeneous solution in the presence of a catalyst under catalytic cracking conditions in the refinery processing unit.
13 . The continuous process according to claim 12 , wherein the one or more waste plastic feedstocks comprise one or more polyesters, one or more polyolefins or combinations thereof, and the one or more waste plastic-immiscible bio feedstocks have an iodine number greater than 95.
14 . The continuous process according to claim 12 , wherein the one or more waste plastic feedstocks comprise one of a polyethylene waste plastic or a polypropylene waste plastic.
15 . The continuous process according to claim 12 , wherein the one or more waste plastic-immiscible bio feedstocks have an iodine number greater than 120.
16 . The continuous process according to claim 12 , wherein the homogeneous solution comprises about 1 to about 20 wt. %, based on a total weight of the homogeneous solution, of the one or more waste plastic feedstocks, about 1 to about 50 wt. %, based on the total weight of the homogeneous solution, of the one or more waste plastic-immiscible bio feedstocks, and about 40 to about 98 wt. %, based on the total weight of the homogeneous solution, of the recycled inert carrier fluid received from a refinery processing unit.
17 . The continuous process according to claim 12 , wherein the one or more waste plastic-miscible bio feedstocks comprise a polyunsaturated triglyceride.
18 . A continuous process, comprising:
processing, in a refinery processing unit, a first homogeneous solution comprising one or more first waste plastic feedstocks, one or more first waste plastic-immiscible bio feedstocks, one or more first waste plastic-miscible bio feedstocks and a recycled inert carrier fluid comprising a light cycle oil received from a refinery processing unit, wherein the recycled inert carrier fluid has a conversion rate in the refinery processing unit of less than about 10% using a ZSM-5 catalyst, or a conversion rate in the refinery processing unit of less than about 25% using an ECAT catalyst, in the presence of a first catalyst under catalytic cracking conditions;
separating the recycled inert carrier fluid from the processed first homogeneous solution;
generating a second homogeneous solution comprising one or more second waste plastic feedstocks, one or more second waste plastic-immiscible bio feedstocks, one or more second waste plastic-miscible bio feedstocks and the separated recycled inert carrier fluid; and
processing the second homogeneous solution in the presence of a second catalyst under catalytic cracking conditions.
19 . The continuous process according to claim 18 , wherein the one or more first waste plastic feedstocks and the one or more second waste plastic feedstocks independently comprise one or more polyesters, one or more polyolefins or combinations thereof, and the one or more first waste plastic-immiscible bio feedstocks and the one or more second waste plastic-immiscible bio feedstocks independently have an iodine number greater than 95.
20 . The continuous process according to claim 18 , wherein the one or more first waste plastic-miscible bio feedstocks in the first homogeneous solution and the one or more second waste plastic-miscible bio feedstocks in the second homogeneous solution each comprises a polyunsaturated triglyceride.