IP Library › Granted Patent US 12,595,436
Granted Patent B2
US 12,595,436 · App. 17/699,369 · Granted Apr 7, 2026

Chemical product comprising an anionic surfactant, chelant, and enzyme, and process for cleaning nanofiltration and reverse osmosis membranes

Inventor: Joselito Barbosa Maciel (Rio de Janeiro, BR)
Assignee: PETROLEO BRASILEIRO S.A.—PETROBRAS
C11D1/24B01D65/022C11D1/04C11D1/146C11D3/33C11D3/38618C11D3/38627C11D3/38636C11D3/38645B01D61/025B01D61/027B01D2321/162B01D2321/166B01D2321/168C11D2111/20
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Quick Facts
Patent No.
US 12,595,436
App. No.
17/699,369
Granted
Apr 7, 2026
Kind
B2
Abstract

The present invention relates to a chemical product and process for cleaning nanofiltration and reverse osmosis membranes, based on enzymatic action aiming to remove biofouling and inorganic scale quickly. The product mentioned in present invention also proposes elimination of the neutralization step of the chemical product used, given that the enzymatic action allows an adequate pH for disposal to be maintained, which fact increases the speed and efficiency of the process.

Claims (13)

1 . A chemical product for cleaning nanofiltration and reverse osmosis membranes consisting of:

A) from 0.1 to 10% of a surfactant agent selected from the group consisting of dodecylbenzene sodium sulfonate, sodium lauryl sulfate, sodium lauryl ether sulfate, and sodium stearate;

B) a chelating agent selected from the group consisting of ethylenediaminetetraacetic acid (EDTA), sodium or potassium salt thereof, and diethylenetriaminepentaacetic acid (DTPA), or sodium or potassium salt thereof;

C) an enzymatic agent selected from the group consisting of an amylase, a cellulase, a xylanase, a lipase, and a mixture of these enzymes; and

D) a buffering (pH regulating) solution.

2 . The product of claim 1 , wherein the concentration of the chelating agent is between 0.1 and 10%.

3 . The product of claim 1 , wherein the total concentration of the enzymatic agents in said product is between 0.1 and 5%.

4 . The product of claim 1 , wherein the buffering solution (pH-regulating solution) maintains and/or adjusts the pH between 7 and 9.

5 . A process for cleaning nanofiltration and reverse osmosis membranes, wherein the process uses a product as defined in claim 1 .

6 . The process of claim 5 , wherein the process performs cleaning of the membranes through performance of circulation and wetting cycles.

7 . The process of claim 5 , wherein each wetting step lasts between 1 and 4 hours.

8 . The process of claim 6 , wherein at the end of the circulation and wetting cycles, the solution is disposed.

9 . The process of claim 8 , wherein after finalizing the cleaning the process includes rinsing with industrial water directly for disposal.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 19, 2022
From: MACIEL, JOSELITO BARBOSA
To: PETROLEO BRASILEIRO S.A. - PETROBRAS
Reel/Frame 060545/0185 →
Priority Claims (1)
BR 1020210053925 · Mar 22, 2021 · national
Continuity (1)
Related Publication 20220348849A1 · Nov 3, 2022
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