IP Library › Granted Patent US 12,600,888
Granted Patent B2
US 12,600,888 · App. 17/951,798 · Granted Apr 14, 2026

Dual-curable adhesive composition

Inventors: Shingo Tsuno (Kanagawa, JP); Takayuki Kanno (Kanagawa, JP)
Assignee: Henkel AG & Co. KGaA
C09J163/00C08K3/36C08K7/18
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Quick Facts
Patent No.
US 12,600,888
App. No.
17/951,798
Granted
Apr 14, 2026
Kind
B2
Abstract

The object of the present invention is to provide an adhesive composition that has a low toxicity, is curable at a low temperature, and is capable of forming a cured product having high heat resistance. The present invention relates to a dual-curable adhesive composition comprising: (a1) an oxetane compound, (a2) an alicyclic epoxy compound, (a3) an aromatic glycidyl ether-based epoxy compound, (b) a photocationic polymerization initiator, and (c) a thermal cationic polymerization initiator comprising a tetrakis(pentafluorophenyl)borate compound, wherein the amount of the component (a1) is 20 to 95 parts by mass, the amount of the component (a2) is 3 to 55 parts by mass, and the amount of the component (a3) is 3 to 45 parts by mass, each based on 100 parts by mass of the total amount of the components (a1), (a2) and (a3).

Claims (29)

1 . A dual-curable adhesive composition comprising:

(a1) an oxetane compound,

(a2) an alicyclic epoxy compound,

(a3) an aromatic glycidyl ether-based epoxy compound,

(b) a photocationic polymerization initiator, and

(c) a thermal cationic polymerization initiator comprising a tetrakis(pentafluorophenyl) borate compound, wherein

the amount of the component (a1) is 30 to 60 parts by mass,

the amount of the component (a2) is 7 to 45 parts by mass, and

the amount of the component (a3) is 5 to 27 parts by mass,

each based on 100 parts by mass of the total amount of the components (a1), (a2) and (a3).

2 . The dual-curable adhesive composition according to claim 1 , wherein the component (c) is an ammonium salt of tetrakis(pentafluorophenyl) boric acid.

3 . The dual-curable adhesive composition according to claim 1 , further comprising (d) an inorganic filler.

4 . The dual-curable adhesive composition according to claim 1 , which is used for assembling a camera module to bond a lens holder and a base plate on which an image capturing sensor is fixed.

5 . A cured product obtained by curing the dual-curable adhesive composition according to claim 1 .

6 . A camera module comprising the cured product according to claim 5 .

7 . A dual-curable adhesive composition comprising:

(a1) 50 parts by mass of an oxetane compound,

(a2) 25 parts by mass of an alicyclic epoxy compound,

(a3) 25 parts by mass of an aromatic glycidyl ether-based epoxy compound,

each based on 100 parts by mass of the total amount of the components (a1), (a2) and (a3),

(b) a photocationic polymerization initiator,

(c) a thermal cationic polymerization initiator comprising a tetrakis(pentafluorophenyl) borate compound, and

(d) an inorganic filler comprising silica.

8 . The dual curable adhesive composition according to claim 7 , wherein

the amount of the component (b) is 2 parts by mass,

the amount of the component (c) is 1 part by mass, and

the amount of component (d) is 100 parts by mass,

each based on 100 parts by mass of the total amount of the components (a1), (a2) and (a3).

9 . The dual curable adhesive composition according to claim 8 , further comprising (e) 4 parts by mass of a thixo-imparting agent and 1 part by mass of a silane coupling agent, each based on 100 parts by mass of the total amount of the components (a1), (a2) and (a3).

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 17, 2026
From: TSUNO, SHINGO
To: HENKEL JAPAN LTD.
Reel/Frame 074095/0290 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 17, 2026
From: KANNO, TAKAYUKI
To: HENKEL JAPAN LTD.
Reel/Frame 074095/0405 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 17, 2026
From: HENKEL JAPAN LTD.
To: HENKEL AG & CO. KGAA
Reel/Frame 074095/0572 →
Priority Claims (1)
JP 2020-051861 · Mar 23, 2020 · national
Continuity (2)
Continuation PCTJP2021011821 · Mar 22, 2021
Related Publication 20230027326A1 · Jan 26, 2023
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