Electrode binder slurry composition for lithium ion electrical storage devices
The present invention provides a slurry composition comprising an electrochemically active material and/or an electrically conductive agent, and a binder comprising a polymer comprising a fluoropolymer dispersed in an organic medium; wherein the organic medium has an evaporation rate less than 10 g/min m 2 , at the dissolution temperature of the fluoropolymer dispersed in the organic medium. The present invention also provides electrodes and electrical storage devices.
1 . A slurry composition comprising:
(a) an electrochemically active material;
(b) a binder comprising a polymer comprising a fluoropolymer dispersed in an organic medium; and
(c) a dispersant comprising an addition polymer comprising a (meth)acrylic polymer comprising constitutional units comprising a residue of methyl methacrylate;
wherein the organic medium has an evaporation rate less than 10 grams per square meter per minute, at a dissolution temperature of the fluoropolymer dispersed in the organic medium.
2 . The slurry composition of claim 1 , wherein the electrochemically active material comprises graphite, silicon compounds, tin, tin compounds, sulfur, sulfur compounds, or a combination thereof.
3 . The slurry composition of claim 1 , wherein the fluoropolymer comprises a (co)polymer comprising a residue of vinylidene fluoride.
4 . The slurry composition of claim 1 , wherein the fluoropolymer comprises a polyvinylidene fluoride polymer.
5 . The slurry composition of claim 1 , wherein the composition further comprises a second dispersant comprising an addition polymer comprising an active hydrogen group.
6 . The slurry composition of claim 1 , wherein the slurry composition further comprises a cross-linker.
7 . The slurry composition of claim 1 , wherein the organic medium has an evaporation rate at 180° C. of greater than 80 grams per square meter per minute.
8 . The slurry composition of claim 1 , wherein the organic medium comprises a primary solvent and a co-solvent.
9 . The slurry composition of claim 8 , wherein the primary solvent comprises butyl pyrrolidone, a trialkylphosphate, 3-methoxy-N,N-dimethylpropanamide, 1,2,3-triacetoxypropane, or combinations thereof, and the co-solvent comprises ethyl acetoacetate, gamma-butyrolactone, propylene glycol methyl ether, dipropylene glycol methyl ether, propylene glycol monopropyl ether, diethylene glycol monobutyl ether, ethylene glycol monohexyl ether, or combinations thereof.
10 . The slurry composition of claim 8 , wherein the primary solvent comprises triethyl phosphate and the co-solvent comprises ethyl acetoacetate.
11 . The slurry composition of claim 1 , further comprising (c) an electrically conductive agent.
12 . The slurry composition of claim 11 , wherein the electrically conductive agent comprises carbon nanotubes.
13 . The slurry composition of claim 11 , wherein the electrochemically active material (a) is present in amounts of 70 to 99 percent by weight; the binder (b) is present in amounts of 0.5 to 20 percent by weight and the electrically conductive agent (c) is present in amounts of 0.5 to 20 percent by weight, based on a total weight of solids in the slurry composition.
14 . The slurry composition of claim 1 , further comprising an adhesion promoter.
15 . The slurry composition of claim 1 , wherein the slurry composition is substantially free of isophorone.
16 . The slurry composition of claim 1 , wherein the slurry composition is substantially free of N-methyl-2-pyrrolidone.
17 . A slurry composition comprising:
(a) a binder comprising a polymer comprising a fluoropolymer dispersed in an organic medium;
(b) an electrically conductive agent; and
(c) a dispersant comprising an addition polymer comprising a (meth)acrylic polymer comprising constitutional units comprising a residue of methyl methacrylate;
wherein the organic medium has an evaporation rate less than 10 grams per square meter per minute, at a dissolution temperature of the fluoropolymer dispersed in the organic medium.
18 . An electrode comprising:
(a) an electrical current collector; and
(b) a film formed on the electrical current collector, wherein the film is deposited from the slurry composition of claim 11 .
19 . The electrode of claim 18 , wherein the electrical current collector is pretreated with a pretreatment composition.
20 . An electrical storage device comprising:
(a) the electrode of claim 18 ;
(b) a counter electrode; and
(c) an electrolyte.
21 . The electrical storage device of claim 20 , wherein the electrical storage device comprises a cell, battery pack, secondary battery, capacitor, supercapacitor, or a combination thereof.
22 . A slurry composition comprising:
(a) an electrochemically active material and/or an electrically conductive material; and
(b) a binder comprising a polymer comprising a fluoropolymer dispersed in an organic medium; and
wherein the organic medium has an evaporation rate less than 10 grams per square meter per minute, at a dissolution temperature of the fluoropolymer dispersed in the organic medium,
wherein the organic medium comprises a primary solvent and a co-solvent, and
wherein the primary solvent comprises butyl pyrrolidone, a trialkylphosphate, 3-methoxy-N,N-dimethylpropanamide, 1,2,3-triacetoxypropane, or combinations thereof, and the co-solvent comprises ethyl acetoacetate, gamma-butyrolactone, propylene glycol methyl ether, dipropylene glycol methyl ether, propylene glycol monopropyl ether, diethylene glycol monobutyl ether, ethylene glycol monohexyl ether, or combinations thereof.
23 . A slurry composition comprising:
(a) an electrochemically active material and/or an electrically conductive material; and
(b) a binder comprising a polymer comprising a fluoropolymer dispersed in an organic medium; and
wherein the organic medium has an evaporation rate less than 10 grams per square meter per minute, at a dissolution temperature of the fluoropolymer dispersed in the organic medium, and wherein the organic medium comprises a primary solvent comprising a trialkylphosphate and a co-solvent comprising ethyl acetoacetate.