Converting lignocellulosic feedstock to fuel
A process for converting lignocellulosic biomass to fuel, wherein lignocellulosic feedstock is soaked in a sulfuric acid solution to demineralize the feedstock, the demineralized feedstock is pretreated at a temperature between 150° C. and 230° C. and a pH between 1 and 2.5, at least part of the pretreated material is converted to a fermentation production such as ethanol, and at least a portion of a secondary stream, such as still bottoms from the distillation of ethanol, is converted to biogas by anaerobic digestion. Soaking the lignocellulosic feedstock in sulfuric acid solution reduces the amount of sulfuric acid required for the pretreatment, and thus the amount of sulfate carried downstream to the anaerobic digestion. This increases the biogas yield and/or xylose yield. A recycling process, wherein mineralized soaking liquid produced in the soaking process is fed to cation exchange to remove minerals, reduces excess waste of the sulfuric acid and water usage.
1 . A process for converting lignocellulosic biomass to fuel, said process comprising:
(a) a demineralization, said demineralization comprising subjecting a feedstock to an acid soaking process, said feedstock comprising the lignocellulosic biomass, said acid soaking process comprising one or more acid soak stages, wherein each of the one or more acid soak stages comprises (i) contacting the feedstock with a soaking liquid to produce a soaked feedstock slurry, and (ii) subjecting the soaked feedstock slurry to a solids/liquid separation, wherein the soaking liquid in each of the one or more acid soak stages is an aqueous solution comprising sulfuric acid having a pH between 1 and 5;
(b) a pretreatment, said pretreatment comprising heating a slurry containing sulfuric acid and demineralized feedstock produced from the demineralization, said heating conducted at a temperature between 150° C. and 230° C. and at a pH between 1 and 2.5, said pretreatment producing a pretreated slurry;
(c) a first conversion, said first conversion comprising an enzymatic hydrolysis wherein cellulose in the pretreated slurry is converted to glucose, a fermentation wherein the glucose is converted to a fermentation product, and a fermentation product recovery, wherein the first conversion produces a secondary stream that contains one or more sulfur compounds derived from sulfuric acid used in the demineralization, the sulfuric acid used in pretreatment, or a combination thereof;
(d) a second conversion, said second conversion comprising feeding at least part of the secondary stream to an anaerobic digester and collecting biogas from the anaerobic digester, said biogas used as a fuel within the process, processed to provide a fuel, or a combination thereof, and
(e) a recycling process, said recycling process comprising feeding mineralized soaking liquid produced from step (a) to cation exchange wherein minerals are removed, and feeding clean sulfuric acid solution produced from the cation exchange to at least one acid soak stage in step (a).
2 . The process according to claim 1 , wherein the acid soaking process comprises a multi-stage countercurrent acid soak.
3 . The process according to claim 2 , wherein a pressate recycle fraction in at least one of the stages of the acid soaking process is greater than 10%.
4 . The process according to claim 1 , wherein the feedstock subjected to the acid soaking process has had at least 75% of the potassium originally present removed.
5 . The process according to claim 1 , wherein the conditions for the acid soaking process are selected to remove at least 70% of the calcium originally present in the lignocellulosic biomass.
6 . The process according to claim 1 , wherein the soaking liquid in each of the one or more acid soak stages has a pH between 1.2 and 4 and is at a temperature between 30° C. and 90° C.
7 . The process according to claim 1 , wherein step (i) of each acid soak stage is conducted at a consistency between 2% and 10% for at least 5 minutes.
8 . The process according to claim 1 , wherein step (ii) of each acid soak stage provides solids having a consistency of at least 15%.
9 . The process according to claim 1 , comprising a washing process upstream of the acid soaking process, said washing process comprising one or more washing stages, wherein each of the one or more washing stages comprises
(a) contacting the feedstock with a wash water, and
(b) a solids/liquid separation wherein the feedstock is separated from at least a portion of the wash water,
wherein the conditions for the washing process are selected to remove at least 70% of the potassium originally present in the feedstock.
10 . The process according to claim 1 , wherein the secondary stream comprises at least part of still bottoms from the fermentation product recovery.
11 . The process according to claim 10 , wherein the still bottoms are subjected to a solids/liquid separation that provides solids and liquids, where the secondary stream comprises liquid produced from the solids/liquid separation of the still bottoms.
12 . The process according to claim 1 , wherein the first conversion comprises subjecting the pretreated slurry to a solids/liquid separation, and wherein the secondary stream comprises liquid from the solids/liquid separation of the pretreated slurry.
13 . The process according to claim 1 , wherein the enzymatic hydrolysis in the first conversion is conducted on unwashed demineralized feedstock.
14 . The process according to claim 1 , wherein the fermentation product is ethanol.
15 . The process according to claim 1 , wherein the second conversion comprises producing renewable natural gas from the biogas.
16 . The process according to claim 1 , wherein the amount of sulfuric acid provided in pretreatment is not more than 12 kg H 2 SO 4 /ton of dry lignocellulosic biomass.
17 . The process according to claim 1 , wherein the secondary stream has a sulfate concentration that is not more than 5 g/L.
18 . The process according to claim 1 , wherein the secondary stream has a biologically degraded chemical oxygen demand to sulfate ratio of at least 7 to 1.
19 . A process for converting lignocellulosic biomass to fuel, said process comprising:
subjecting a feedstock comprising lignocellulosic biomass to a washing process to provide a washed feedstock,
subjecting the washed feedstock to an acid soaking process to produce a demineralized feedstock, said acid soaking process comprising a multi-stage countercurrent acid soak, each stage of the multi-stage acid soak comprising (a) contacting the feedstock with an aqueous sulfuric acid solution having a pH not more than 3, and (ii) a solids/liquid separation that provides a pressate and solids, said solids having a consistency of at least 20%, wherein a pressate recycle fraction in at least one stage of the multi-stage countercurrent acid soak is greater than 10% by weight;
pretreating the demineralized feedstock to produce a pretreated slurry comprising cellulose, said pretreating comprising heating a slurry containing sulfuric acid and the demineralized feedstock at a temperature between 150° C. and 230° C. and at a pH between 1 and 2.5;
converting at least part of the pretreated slurry to ethanol, said converting comprising hydrolyzing the cellulose to glucose in an enzymatic hydrolysis, fermenting the glucose to ethanol, and recovering the ethanol in a distillation that produces concentrated ethanol and still bottoms;
feeding a stream comprising at least part of the still bottoms to an anaerobic digestion, said stream comprising sulfate derived from sulfuric acid used in the acid soaking process, sulfate derived from sulfuric acid used in pretreatment, or a combination thereof;
collecting biogas from the anaerobic digester, said collected biogas used as a fuel within the process, processed to provide a transportation fuel, or a combination thereof; and
subjecting mineralized soaking liquid produced from the acid soaking process to cation exchange to remove one or more minerals therefrom and recycling clean sulfuric acid solution produced by cation exchange within the acid soaking process.