Composition for electrochemical device functional layer, functional layer for electrochemical device, laminate for electrochemical device, and electrochemical device
A composition for an electrochemical device functional layer contains non-conductive heat-resistant particles and a particulate polymer having a particle diameter distribution value (Dv/Dn) of not less than 1.00 and less than 1.10.
1 . A functional layer for an electrochemical device, comprising: a non-conductive heat-resistant particle layer containing non-conductive heat-resistant particles; and a particulate polymer, wherein
the particulate polymer is dispersed in the non-conductive heat-resistant particle layer,
the particulate polymer has a particle diameter distribution value, expressed by Dv/Dn, of not less than 1.00 and less than 1.10, where Dv is a value for volume-average particle diameter of the particulate polymer and Dn is a value for number-average particle diameter of the particulate polymer, and
a buried fraction of the particulate polymer in the non-conductive heat-resistant particle layer is 30% or less,
wherein the buried fraction is a value that indicates a proportion of the number of particles of the particulate polymer that are buried in the non-conductive heat-resistant particle layer among 100 arbitrarily selected particles of the particulate polymer contained in the functional layer, and a particle of the particulate polymer is determined to be buried when the particle is completely buried in the non-conductive heat-resistant particle layer and does not have a section protruding from a surface of the non-conductive heat-resistant particle layer.
2 . The functional layer for an electrochemical device according to claim 1 , wherein a value obtained by dividing the volume-average particle diameter Dv of the particulate polymer by layer thickness of the non-conductive heat-resistant particle layer is not less than 0.75 and not more than 4.00.
3 . The functional layer for an electrochemical device according to claim 2 , wherein the value obtained by dividing the volume-average particle diameter Dv of the particulate polymer by the layer thickness of the non-conductive heat-resistant particle layer is more than 1.00.
4 . A laminate for an electrochemical device comprising the functional layer for an electrochemical device according to claim 1 stacked on a substrate.
5 . An electrochemical device comprising the functional layer for an electrochemical device according to claim 1 .