Hydrophilic hotmelt adhesive
A hotmelt adhesive comprising a metallocene-catalyzed polyolefin and a hydrophilic melt additive. The adhesive is permanently hydrophilic and can be in particular used to bond components of a disposable hygienic article such as a diaper.
1 . A hydrophilic hotmelt adhesive comprising by weight of the hotmelt adhesive:
from about 30% to about 99% of a metallocene-catalyzed polyolefin, wherein the metallocene-catalyzed polyolefin has a peak molecular weight in the range of from about 10,000 g/mol to about 130,000 g/mol, wherein the peak molecular weight is measured according to the Peak Molecular Weight (Mp) Measurement Method,
from about 0.1% to about 10% of a hydrophilic melt additive, wherein the hydrophilic melt additive comprises a first wetting agent and a second wetting agent, and wherein the second wetting agent comprises a water-soluble, nonionic, nonhydrolyzable polyoxyalkylene-modified organosilicone polymer, and
from about 0% to about 40% of a tackifier.
2 . The hydrophilic hotmelt adhesive according to claim 1 , wherein the metallocene-catalyzed polyolefin is propylene-based.
3 . The hydrophilic hotmelt adhesive according to claim 1 , wherein the hotmelt adhesive has a viscosity at 170° C. in the range of from about 100 mPa·s to about 10,000 mPa·s, as measured by Viscosity Test Method.
4 . The hydrophilic hotmelt adhesive according to claim 1 , wherein the first wetting agent is a water insoluble nonionic alkoxylated alkyl phenol.
5 . The hydrophilic hotmelt adhesive according to claim 1 , wherein the hydrophilic melt additive comprises an ethoxylated alcohol.
6 . The hydrophilic hotmelt adhesive according to claim 5 , wherein the ethoxylated alcohol has the formula:
with x ranging from 2 to 100 and y ranging from 12 to 24.
7 . The hydrophilic hotmelt adhesive according to claim 1 , wherein the hotmelt adhesive exhibits a Fresh Film Contact Angle and an Aged film Contact Angle with distilled water of less than 70 about degrees, as measured by the Contact Angle Method.
8 . The hydrophilic hotmelt adhesive according to claim 1 , wherein the hotmelt adhesive has a storage modulus (G′) higher than about 300,000 Pa at 37° C., wherein the storage modulus is measured with the Oscillatory Rheometry Test Method.
9 . An absorbent article comprising a bond formed by the hydrophilic hotmelt adhesive according to claim 1 , wherein the article comprises a topsheet, an absorbent core, a backsheet, and optionally an acquisition layer, wherein the absorbent core optionally comprises an absorbent material and a core wrap, wherein the bond formed by the hydrophilic hotmelt adhesive is between two layers selected from:
the topsheet and the optional acquisition layer; or
the optional acquisition layer and the absorbent core; or
the topsheet and the absorbent core; or
the core wrap and the absorbent material.
10 . An absorbent article comprising a bond formed by the hydrophilic hotmelt adhesive according to claim 1 , wherein the article comprises an absorbent core, the absorbent core comprising an absorbent material layer sandwiched between the top side and the bottom side of a core wrap, the top side being closer to the topsheet than the bottom side, and wherein the hydrophilic hotmelt adhesive is disposed between the top side and the absorbent material layer, and the hydrophilic hotmelt adhesive at least partially immobilizes the absorbent material within the core wrap.
11 . An absorbent article comprising a bond formed by the hydrophilic hotmelt adhesive according to claim 1 , the article comprising a three-dimensional laminate comprising a first layer and a second layer wherein the first layer is intermittently bonded to the second layer by the hotmelt adhesive so that the first layer comprises a plurality of protrusions not bonded to the second layer, wherein the three-dimensional laminate is a topsheet and the first layer comprises cotton fibers.
12 . An absorbent article comprising a bond formed by the hydrophilic hotmelt adhesive according to claim 1 , wherein the bond is between a first nonwoven and another component of the article, and wherein the first nonwoven is bonded by the hydrophilic hotmelt adhesive to at least one selected from a second nonwoven, cellulose fibers, or superabsorbent particles.
13 . A substrate comprising a coating, wherein the coating is a hotmelt adhesive according to claim 1 .
14 . The hydrophilic hotmelt adhesive according to claim 1 , wherein the metallocene-catalyzed polyolefin has an enthalpy of fusion of from 5 J/g to 45 J/g.
15 . The hydrophilic hotmelt adhesive according to claim 1 , wherein the hydrophilic hotmelt adhesive is substantially free of tackifier.
16 . The hydrophilic hotmelt adhesive according to claim 1 , wherein the metallocene-catalyzed polyolefin has a peak molecular weight in the range of from about 10,000 g/mol to about 70,000 g/mol, wherein the peak molecular weight is measured according to the Peak Molecular Weight (Mp) Measurement Method.
17 . The hydrophilic hotmelt adhesive according to claim 1 , wherein the hydrophilic hotmelt adhesive is permanently hydrophilic.
18 . The hydrophilic hotmelt adhesive according to claim 1 , wherein the hydrophilic hotmelt adhesive comprises a blend of two or more metallocene-catalyzed polyolefins.
19 . An absorbent article comprising a bond formed by a hydrophilic hotmelt adhesive, wherein the article comprises a topsheet, an absorbent core, a backsheet, and optionally an acquisition layer, wherein the absorbent core optionally comprises an absorbent material and a core wrap, wherein the bond formed by the hydrophilic hotmelt adhesive is between two layers selected from:
the topsheet and the optional acquisition layer; or
the optional acquisition layer and the absorbent core; or
the topsheet and the absorbent core; or
the core wrap and the absorbent material;
wherein the hotmelt adhesive comprises, by weight:
from about 30% to about 99% of a metallocene-catalyzed polyolefin, and
from about 0.1% to about 10% of a hydrophilic melt additive, and
from about 0% to about 40% of a tackifier,
wherein the metallocene-catalyzed polyolefin has a peak molecular weight in the range of from about 10,000 g/mol to about 70,000 g/mol, wherein the peak molecular weight is measured according to the Peak Molecular Weight (Mp) Measurement Method, and
wherein the hydrophilic melt additive comprises a first wetting agent and a second wetting agent, and wherein the second wetting agent comprises a water-soluble, nonionic, nonhydrolyzable polyoxyalkylene-modified organosilicone polymer;
and wherein the hotmelt adhesive comprises a plasticizer, wherein the plasticizer comprises up to about 20% of the hotmelt adhesive.