Granted Patent B2

US 12,734,475 · App. 17/961,002 · Granted Sep 15, 2026

Inventors: Min Ho Maeng (Newark, DE); Sudhir Kulkarni (Wilmington, DE); Shu Fang (Newark, DE)

Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude

B01D53/228B01D53/226B01D2257/504B01D2257/7025B01D2258/05B01D2323/21839

Abstract

Claims (28)

1 . A system for upgrading biogas through a membrane separation process comprising:

an anaerobic digester, operated under an operation pressure higher than atmosphere pressure, configured to generate the biogas from a feedstock containing an organic content;

a first membrane stage, configured to separate the biogas into a first residue stream, enriched in CH 4 , withdrawn from the residue side of the first membrane stage and forwarded to a second membrane stage as a feed gas therein, and a first permeate stream, enriched in CO 2 , withdrawn from the permeate side of the first membrane stage, and vented out;

the second membrane stage, connected to the first membrane stage in series, configured to separate the residue stream from the first membrane into a second residue stream, enriched in CH 4 , withdrawn from the residue side of the second membrane stage and forwarded to a point of use, and a second permeate stream, enriched in CO 2 , withdrawn from the permeate side of the second membrane stage and sent to a compressor; and

a third membrane stage, configured to separate the first permeate stream from the first membrane stage into a third residue stream containing CO 2 and CH 4 , withdrawn from the residue side of the third membrane stage and sent to the compressor, and a third permeate stream, enriched in CO 2 , withdrawn from the permeate side of the third membrane stage, and vented out,

wherein the residue stream from the third membrane stage in combination with the permeate stream from the second membrane stage is compressed and recycled back to the bottom volume of the digestate sludge phase in the anaerobic digester;

wherein the compressor is configured to compress the second permeate stream from the second membrane stage and the third residue stream form the third membrane stage to a pressure greater than the operation pressure.

2 . The system of claim 1 , wherein the operation pressure is higher than 4 bara.

3 . The system of claim 1 , wherein the first membrane stage, second membrane stage and third membrane stage, each contains a plurality of gas separation membranes made of one or more of fluoropolymers, copolymers of polyether-polyamide, polyimides, and polymers of intrinsic morphology (PIMs) having a CO 2 /methane selectivity of at least 10 and a CO 2 permeance of at least 50 GPU.

4 . The system of claim 1 , wherein the first membrane stage, second membrane stage and third membrane stage, each contains a plurality of gas separation membranes, each of the plurality of gas separation membranes is a composite hollow fiber membrane comprising a separation layer disposed on a substrate layer, the separation layer being made of one or more of fluoropolymers, copolymers of polyether-polyamide, polyimides, and polymers of intrinsic morphology (PIMs), the substrate layer being made of one or more of polysulfone, polyvinyledene fluoride, a polyimide, polyether ketone, and polyether ether ketone.

5 . The system of claim 1 , further comprising a recycle gas injector, configured to inject the compressed stream into the digestate sludge phase in the anaerobic digester, wherein a driving force is provided and controlled to achieve a pressure difference between an exterior and interior of the recycle gas injector.

6 . The system of claim 1 , wherein a pressure of the compressed combination stream and a pressure of the compressed second permeate stream are greater than the operation pressure of the anaerobic digester.

7 . The system of claim 1 , wherein a pH adjusting chemical is added to the anaerobic digester, wherein the pH adjusting chemical is a strong base selected from magnesium hydroxide, sodium hydroxide, quicklime, lime, calcium hydroxide or a sodium salt of carbonic acid selected from sodium bicarbonate or sodium carbonate.

8 . The system of claim 1 , wherein pressure differences across the first membrane stage, across the second membrane stage and across the third membrane stage serve as a driving force to separate the biogas, the first residue stream and the first permeate stream, respectively.

9 . The system of claim 1 , wherein the anaerobic digester is a pressurized anaerobic digestion reactor suitable for operation under a pressure greater than atmosphere pressure.

10 . A membrane separation process for upgrading biogas from an anaerobic digester, the process comprising the steps of:

feeding a feedstock having an organic content to the anaerobic digester;

generating the biogas comprising CH 4 and CO 2 from the anaerobic digester under an operation pressure greater than atmosphere pressure;

feeding the biogas to a first membrane stage, wherein the biogas is separated into a first residue stream enriched in CH 4 and a first permeate stream enriched in CO 2 compared to the biogas;

feeding the first residue stream from the first membrane stage to a second membrane stage, wherein the first residue stream is separated into a second residue stream enriched in CH 4 and a second permeate stream enriched in CO 2 compared to the first residue stream;

feeding the first permeate stream to a third membrane stage, wherein the first permeate stream is separated into a third residue stream containing CO 2 and CH 4 and a third permeate gas enriched in CO 2 ;

compressing a combination stream of the third residue stream from the third membrane stage and the second permeate stream from the second membrane stage; and

recycling the compressed combination stream back to the bottom volume of digestate sludge phase in the anaerobic reactor.

11 . The membrane separation process of claim 10 , wherein the operation pressure is greater than 4 bara.

12 . The membrane separation process of claim 10 , wherein the second residue stream from the second membrane stage has a purity greater than 98% CH 4 .

13 . The membrane separation process of claim 10 , wherein a pressure of the compressed combination stream is greater than the operation pressure of the anaerobic digester.

14 . The membrane separation process of claim 10 , further comprising adding a pH adjusting chemical to the feedstock, wherein the pH adjusting chemical is a strong base selected from magnesium hydroxide, sodium hydroxide, quicklime, lime, calcium hydroxide or a sodium salt of carbonic acid selected from sodium bicarbonate or sodium carbonate.

15 . The membrane separation process of claim 10 , wherein pressure differences across the first membrane stage, across the second membrane stage and across the third membrane stage serve as a driving force to separate the biogas, the first residue stream and the first permeate stream.

Continuity (1)

References Cited (77)