Method of forming memory structure
A method of forming a memory structure is provided. The method includes providing a substrate, wherein the substrate has a plurality of isolation structures, and the isolation structures include a plurality of first protrusions protruding above the substrate; replacing the first protrusions with a plurality of second protrusions to define a plurality of predetermined regions of floating gates between the second protrusions. The replacing step includes forming an insulation filling material between the first protrusions and on the substrate, and performing a patterning process to the insulation filling and the first protrusions to form second protrusions to define the predetermined regions of the floating gates, and forming a plurality of floating gates in the predetermined regions of the floating gates.
1 . A method of forming a memory structure, comprising:
providing a substrate with a plurality of isolation structures, wherein the plurality of isolation structures comprise a plurality of first protrusions protruding above the substrate;
replacing the plurality of first protrusions with a plurality of second protrusions to define a plurality of predetermined regions of floating gates between the plurality of second protrusions, comprising:
forming an insulation filling material between the plurality of first protrusions and on the substrate; and
performing a patterning process on the insulation filling material and the plurality of first protrusions to form the plurality of second protrusions to define the plurality of predetermined regions of floating gates, wherein the patterning process comprises forming a patterned mask layer on the insulation filling material, and performing a first etching process on the insulation filling material and/or the plurality of first protrusions with the patterned mask layer; and
forming a plurality of floating gates in the plurality of predetermined regions of floating gates.
2 . The method of forming the memory structure of claim 1 , wherein the plurality of isolation structures have an aspect ratio greater than 1.
3 . The method of forming the memory structure of claim 2 , wherein each of the plurality of isolation structures further comprises a base portion under each of the plurality of first protrusions and located in the substrate.
4 . The method of forming the memory structure of claim 3 , wherein a width of a bottom surface of each of the plurality of second protrusions is smaller than a width of a top surface of the base portion of each of the plurality of isolation structures.
5 . The method of forming the memory structure of claim 3 , wherein a width of a top surface of each of the second protrusions is smaller than a width of a top surface of the base portion of each of the plurality of isolation structures.
6 . The method of forming the memory structure of claim 4 , wherein a width of each pattern of the patterned mask layer is smaller than a width of a top surface of the first protrusion of the isolation structure.
7 . The method of forming the memory structure of claim 1 , wherein the insulation filling material comprises a same material as each of the plurality of first protrusions.
8 . The method of forming the memory structure of claim 1 , wherein each of the plurality of first protrusions include undoped silicon oxide.
9 . The method of forming the memory structure of claim 1 , further comprising:
performing a chemical mechanical polishing (CMP) process on the insulation filling material and/or each of the plurality of first protrusions before the patterning process.
10 . The method of forming the memory structure of claim 1 , wherein the location of each pattern of the patterned mask layer corresponds to a location of one of the plurality of isolation structures, and the insulation filling material remains covering a top surface of the substrate after the first etching process, and wherein the first etching process comprises a dry etching process, a wet etching process, or a combination thereof.
11 . The method of forming the memory structure of claim 10 , wherein the patterning process further comprises:
performing a second etching process on the insulation filling material and/or the first protrusions of the predetermined regions of floating gates to expose the top surface of the substrate to form the second protrusions.
12 . The method of forming the memory structure of claim 11 , wherein the first etching process is a dry etching process, and the second etching process is a wet etching process.
13 . The method of forming the memory structure of claim 12 , wherein the wet etching process uses hydrofluoric acid, hot phosphoric acid, or a combination thereof.
14 . The method of forming the memory structure of claim 1 , wherein the insulation filling material has a trapezoidal structure after the patterning process.
15 . The method of forming the memory structure of claim 1 , further comprising:
after the patterning process, forming a plurality of tunneling dielectric layers over a top surface of the substrate in the plurality of predetermined regions of floating gates.
16 . The method of forming the memory structure of claim 15 , wherein the plurality of floating gates completely cover the tunneling dielectric layers.
17 . The method of forming the memory structure of claim 15 , wherein steps of forming the floating gates comprise:
depositing a floating gate material over the plurality of tunneling dielectric layers in the plurality of predetermined regions of floating gates and over the second protrusions;
performing a planarization process on the floating gate material until top surfaces of the plurality of second protrusions are exposed, leaving remaining floating gate material between the second protrusions as the floating gates.
18 . The method of forming the memory structure of claim 17 , wherein the floating gate material comprises doped polysilicon, undoped polysilicon, or a combination thereof.
19 . The method of forming the memory structure of claim 1 , wherein the floating gates have an inverted trapezoidal shape.
20 . The method of forming the memory structure of claim 1 , wherein a bottom surface width of the plurality of floating gates is greater than a top surface width of the substrate between the plurality of isolation structures.