NO
The nitric oxide (NO) and nitrogen dioxide (NO 2 ) content of lean-burn engine exhaust is beneficially prepared for selective catalytic reduction (SCR) of these oxides to nitrogen by two sidestream additions to the exhaust. An ozone-containing air stream is added to the exhaust to affect oxidation of NO to NO 2 . And a hydrocarbon(s) fuel constituent is added to a second humidified ozone-containing air stream and that mixture subjected to UV radiation. Strongly oxidizing hydroxyl radicals are formed by interaction of ozone, water, and UV radiation for reaction with the hydrocarbon. The resulting partially oxidized hydrocarbons (Pox) are added to the exhaust, providing effective reduction materials for the SCR of NO 2 to nitrogen and water.
1. A method of reducing nitrogen oxides, including NO and NO 2 , in an exhaust stream from a lean-burn combustion source, the method comprising:
adding a quantity of hydrocarbon to a water-containing and ozone-containing stream of air;
exposing the stream of air to ultraviolet radiation of a wavelength selected to induce the formation of hydroxyl radicals in the stream, the hydroxyl radicals reacting with the hydrocarbon to form hydrogen-carbon-oxygen-containing molecules in the air stream; and
adding the air stream to the exhaust wherein the hydrogen-carbon-oxygen-containing molecules are available as reductants for NO 2 .
2. A method of reducing nitrogen oxides as recited in claim 1 in which the lean-bum combustion source is a diesel-fuelled engine and the hydrocarbon is diesel fuel or a hydrocarbon-containing fraction of diesel fuel.
3. A method of reducing nitrogen oxides as recited in claim 1 in which the lean-bum combustion source is a gasoline-fuelled engine and the hydrocarbon is gasoline or a hydrocarbon-containing fraction of gasoline.
4. A method of reducing nitrogen oxides as recited in claim 1 in which the wavelength of the UV radiation is about 254 nanometers.
5. A method of reducing nitrogen oxides, including NO and NO 2 , in an exhaust stream from a lean-bum engine powered automotive vehicle, the method comprising:
adding a stream of ozone-containing air to the exhaust at a first location in the flow path of the exhaust to oxidize at least a portion of the NO content to NO 2 ;
subjecting a mixture of water, ozone, and a hydrocarbon to electromagnetic radiation of ultraviolet wavelength to form hydroxyl radicals, wherein the hydroxyl radicals and ozone react with the hydrocarbon to form hydrogen-carbon-oxygen-containing molecules in the air;
adding the air and hydrogen-carbon-oxygen-containing molecules to the exhaust stream at a second location in the flow path of the exhaust wherein the hydrogen-carbon-oxygen-containing molecules are available as reductants for NO 2 ; and, thereafter
passing the exhaust stream into contact with a catalyst for reduction of NO 2 to nitrogen utilizing the hydrogen-carbon-oxygen-containing molecules.
6. A method of reducing nitrogen oxides as recited in claim 5 in which the lean-burn combustion source is a diesel-fueled engine and the hydrocarbon is diesel fuel or a hydrocarbon-containing fraction of diesel fuel.
7. A method of reducing nitrogen oxides as recited in claim 5 in which the lean-burn combustion source is a gasoline-fueled engine and the hydrocarbon is gasoline or a hydrocarbon-containing fraction of gasoline.
8. A method of reducing nitrogen oxides as recited in claim 5 in which the wavelength of the UV radiation is about 254 nanometers.
9. A method of reducing nitrogen oxides as recited in claim 5 in which second location in the flow path of the exhaust stream is downstream of the first location.
10. A method of reducing nitrogen oxides, including NO and NO 2 , in an exhaust stream from a lean-burn engine powered automotive vehicle, the method comprising:
flowing a stream of moisture-containing ambient air through a flow-through ozone generator on the vehicle to produce a stream of moisture and ozone-containing air exiting the ozone generator;
dividing the exiting stream into a first and second flowing streams;
adding the first stream of ozone-containing air to the exhaust at a first location in the flow path of the exhaust to oxidize at least a portion of the NO content to NO 2 ;
adding hydrocarbon material to the second flowing ozone-containing air stream, the hydrocarbon being vaporizable in the stream;
subjecting the hydrocarbon-containing second stream to electromagnetic radiation of ultraviolet wavelength to form hydroxyl radicals, wherein the hydroxyl radicals and ozone react with the hydrocarbon to form hydrogen-carbon-oxygen-containing molecules in the air;
adding the second stream with its hydrogen-carbon-oxygen-containing molecules to the exhaust stream at a second location in the flow path of the exhaust wherein the hydrogen-carbon-oxygen-containing molecules are available as reductants for NO 2 ; and, thereafter
passing the exhaust stream into contact with a catalyst for reduction of NO 2 to nitrogen utilizing the hydrogen-carbon-oxygen-containing molecules.