IP Library Granted Patent US 7,037,639
Granted Patent B2
US 7,037,639 · App. 10/136,188 · Granted May 2, 2006

Methods of manufacturing a lithography template

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Quick Facts
Patent No.
US 7,037,639
App. No.
10/136,188
Granted
May 2, 2006
Kind
B2
Abstract

A method for forming imprint lithography templates is described herein. The method includes forming a masking layer and a conductive layer on a substrate surface. The use of a conductive layer allows patterning of the masking layer using electron beam pattern generators. The substrate is etched using the patterned masking layer to produce a template.

Claims (60)

1. A method of forming a lithography template, the method comprising:

forming a conductive polysilicon layer upon a substrate, wherein the substrate is composed of a light transmissive material;

forming a masking layer upon the conductive polysilicon layer;

forming a pattern in the masking layer such that a portion of the conductive polysilicon layer is exposed through the masking layer;

etching one or more of the exposed portions of the conductive polysilicon layer such that a portion of the substrate is exposed through the conductive polysilicon layer; and etching one or more of the exposed portions of the substrate.

2. The method of claim 1 , further comprising removing the masking layer and the conductive polysilicon layer, providing the substrate formed from a material selected from a set of materials consisting essentially of glass, quartz glass and fused silica, with said conductive polysilicon layer being n-doped polysilicon.

3. The method of claim 1 wherein the conductive polysilicon layer has a conductivity sufficient to remove a portion of a charge from the substrate during patterning of the masking layer with an electron beam pattern generator.

4. The method of claim 1 , wherein the masking layer is a photoresist material, and wherein forming the pattern in the masking layer comprises:

coating the conductive polysilicon layer with the photoresist material;

exposing one or more portions of the photoresist material to an electron beam with an electron beam pattern generator; and

removing one or more of the exposed portions of the photoresist material.

5. The method of claim 1 , wherein the masking layer is a photoresist material, and wherein forming the pattern in the masking layer comprises:

coating the conductive polysilicon layer with the photoresist material;

exposing one or more portions of the photoresist material to light with a laser pattern generator; and

removing one or more of the exposed portions of the photoresist material.

6. The method of claim 1 wherein the masking layer is a photoresist material, and wherein forming the pattern in the masking layer comprises:

coating the conductive polysilicon layer with the photoresist material;

exposing one or more portions of the photoresist material to an electron beam with an electron beam pattern generator; and

removing one or more of the unexposed portions of the photoresist material.

7. The method of claim 1 wherein the masking layer is a photoresist material, and wherein forming the pattern in the masking layer comprises:

coating the conductive polysilicon layer with the photoresist material;

exposing one or more portions of the photoresist material to light with a laser pattern generator; and

removing one or more of the unexposed portions of the photoresist material.

8. The method of forming alithography template, the method comprising:

providing a substrate, the substrate comprising a base layer, an etch stop layer disposed upon the base layer, and an upper layer disposed above the etch stop layer, wherein the base layer, the etch stop layer, and the upper layer are composed of a light transmissive material;

forming a conductive polysilicon layer upon the upper layer;

forming a masking layer upon the conductive polysilicon layer;

forming a pattern in the masking layer such that a portion of the conductive polysilicon layer is exposed through the masking layer;

etching one or more of the exposed portions of the conductive polysilicon layer such that a portion of the substrate is exposed through the polysilicon layer; and

etching one or more of the exposed portions of the substrate until the etch stop ayer is reached.

9. The method of claim 8 wherein providing said substrate further includes providing the substrate formed from a material selected from a set of materials consisting essentially of glass, quartz glass and fused silica, forming said etch stop layer from indium tin oxide, and forming said upper layer from materials selected from a set consisting essentially of deposited silicon dioxide and grown quartz and said forming said conductive polysilicon layer further including forming said conductive polysilicon layer from n-doped polysilicon.

10. The method of claim 8 wherein the conductive polysilicon layer has a conductivity sufficient to remove a portion of a charge from the substrate during etching of the masking layer with an electron beam pattern generator.

11. The method of claim 8 wherein the masking layer is a photoresist material, and wherein forming the pattern in the masking layer comprises:

coating the conductive polysilicon layer with the photoresist material;

exposing one or more portions of the photoresist material to an electron beam with an electron beam pattern generator; and

removing one or more of the exposed portions of the photoresist material.

12. The method of claim 8 wherein the masking layer is a photoresist material, and wherein forming the pattern in the masking layer comprises:

coating the conductive polysilicon layer with the photoresist material;

exposing one or more portions of the photoresist material to light with a laser pattern generator; and

removing one or more of the exposed portions of the photoresist material.

13. The method of claim 8 wherein the masking layer is a photoresist material, and wherein forming the pattern in the masking layer comprises:

coating the conductive polysilicon layer with the photoresist material;

exposing one or more portions of the photoresist material to an electron beam with an electron beam pattern generator; and

removing one or more of the unexposed portions of the photoresist material.

14. The method of claim 8 wherein the masking layer is a photoresist material, and wherein forming the pattern in the masking layer comprises:

coating the conductive polysilicon layer with the photoresist material;

exposing one or more portions of the photoresist material to light with a laser pattern generator; and

removing one or more of the unexposed portions of the photoresist material.

15. The method of claim 8 wherein the depth of the pattern etched in the substrate is selected for a desired aspect ratio in the template and wherein inspecting the pattern formed on the conductive polysilicon layer comprises exposing the conductive polysilicon layer to an inspection light, wherein a thickness of the conductive polysilicon layer and the wavelength of the inspection light are predetermined to enhance a contrast between the patterned conductive polysilicon layer and the exposed portions of the substrate.

16. The method of claim 8 wherein said conductive polysilicon layer has a thickness that is about ½ of a wavelength of an inspection light.

17. A method of patterning a lithographic template, said method comprising:

forming, on said lithographic template, a layer of conductive polysilicon material that is transparent to visible light;

applying, on said layer of conductive polysilicon material, a masking layer;

creating a pattern in said masking layer to expose a sub-portion of said layer of conductive polysilicon material; and

transferring said pattern into said template.

18. The method as recited in claim 17 wherein said polysilicon material is selected from a set consisting of titanium silicide, tungsten silicide and cobalt silicide.

19. The method as recited in claim 17 wherein forming further includes depositing said layer of conductive polysilicon material employing chemical vapor deposition techniques.

20. The method as recited in claim 17 wherein forming further includes implanting ions into said layer of conductive polysilicon layer.

21. The method as recited in claim 20 wherein said ions are selected from a set of ions consisting of phosphorous, boron and arsenic.

22. The method as recited in claim 20 further includes annealing said layer of conductive polysilicon material.

Assignments (15)
ASSIGNMENT OF SECURITY INTEREST IN PATENTS Recorded Nov 7, 2019
From: JPMORGAN CHASE BANK, N.A.
To: CITIBANK, N.A.
Reel/Frame 050967/0138 →
PATENT SECURITY AGREEMENT Recorded Aug 22, 2019
From: MAGIC LEAP, INC.; MOLECULAR IMPRINTS, INC.; MENTOR ACQUISITION ONE, LLC
To: JP MORGAN CHASE BANK, N.A.
Reel/Frame 050138/0287 →
CONFIRMATORY ASSIGNMENT OF JOINT PATENT OWNERSHIP Recorded Apr 27, 2015
From: CANON NANOTECHNOLOGIES, INC.
To: MOLECULAR IMPRINTS, INC.
Reel/Frame 035507/0559 →
CHANGE OF NAME Recorded Jul 30, 2014
From: MII NEWCO, INC.
To: MOLECULAR IMPRINTS, INC.
Reel/Frame 033449/0684 →
CHANGE OF NAME Recorded Jul 24, 2014
From: MOLECULAR IMPRINTS, INC.
To: CANON NANOTECHNOLOGIES, INC.
Reel/Frame 033400/0184 →
ASSIGNMENT OF JOINT OWNERSHIP Recorded Jul 15, 2014
From: MOLECULAR IMPRINTS, INC.
To: MII NEWCO, INC.
Reel/Frame 033329/0280 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNOR AND ASSIGNEE PREVIOUSLY RECORDED ON REEL 033161 FRAME 0705. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jun 25, 2014
From: CANON INC.
To: MOLECULAR IMPRINTS, INC.
Reel/Frame 033227/0398 →
RELEASE OF SECURITY INTEREST Recorded Jun 13, 2014
From: MOLECULAR IMPRINTS, INC.
To: CANON INC.
Reel/Frame 033161/0705 →
CORRECTIVE ASSIGNMENT TO CORRECT THE NATURE OF CONVEYANCE FROM AN "ASSIGNMENT" TO "SECURITY AGREEMENT" PREVIOUSLY RECORDED ON REEL 026842 FRAME 0929. ASSIGNOR(S) HEREBY CONFIRMS THE THE ORIGINAL DOCUMENT SUBMITTED WAS A "SECURITY AGREEMENT". Recorded Aug 13, 2013
From: MOLECULAR IMPRINTS, INC.
To: CANON INC.
Reel/Frame 031003/0031 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 1, 2011
From: MOLECULAR IMPRINTS, INC.
To: CANON INC.
Reel/Frame 026842/0929 →
RELEASE OF SECURITY INTEREST Recorded Aug 29, 2011
From: VENTURE LENDING & LEASING III, INC.
To: MOLECULAR IMPRINTS, INC.
Reel/Frame 026821/0159 →
RELEASE OF SECURITY INTEREST Recorded Mar 27, 2007
From: VENTURE LENDING & LEASING IV, INC.
To: MOLECULAR IMPRINTS, INC.
Reel/Frame 019072/0882 →
SECURITY INTEREST Recorded Jan 11, 2005
From: MOLECULAR IMPRINTS, INC.
To: VENTURE LENDING & LEASING IV, INC.
Reel/Frame 016133/0369 →
SECURITY INTEREST Recorded Feb 19, 2003
From: MOLECULAR IMPRINTS, INC.
To: VENTURE LENDING & LEASING III, INC.
Reel/Frame 013760/0150 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 16, 2002
From: VOISIN, RONALD D.
To: MOLECULAR IMPRINTS, INC.
Reel/Frame 013399/0864 →