IP Library Granted Patent US 6,929,762
Granted Patent B2
US 6,929,762 · App. 10/293,223 · Granted Aug 16, 2005

Method of reducing pattern distortions during imprint lithography processes

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Quick Facts
Patent No.
US 6,929,762
App. No.
10/293,223
Filed
Nov 13, 2002
Granted
Aug 16, 2005
Kind
B2
Art Unit
1732
USPC
264/40.1
Abstract

The present invention is directed to a method of reducing distortions in a pattern disposed on a layer of a substrate, defining a recorded pattern, employing a mold having the pattern recorded therein, defining an original pattern. The method includes, defining a region on the layer in which to produce the recorded pattern. Relative extenuative variations between the substrate and the mold are created to ensure that the original pattern defines an area coextensive with the region. Thereafter, the recorded pattern is formed in the region. The relative extenuative variations are created by heating or cooling of the substrate so that the region defines an area that is slightly smaller/larger than the area of the original pattern. Then compression/tensile forces are applied to the mold to provide the recorded pattern with an area coextensive with the area of the region.

Claims (31)

1. A method of reducing distortions in a pattern disposed on a layer of a substrate, defining a recorded pattern, employing a mold having features to form said pattern on said layer, defining an original pattern, said method comprising:

defining a region on said layer in which to produce said recorded pattern;

creating relative extenuative variations between said substrate and said mold by varying a temperature of one of said substrate and said mold so that an area defined by said original pattern differs from said area defined by said region; and

applying mechanical stresses to said mold to varying said area associated with said original pattern to be coextensive with said area defined by said region.

2. The method as recited in claim 1 wherein applying mechanical stress further includes applying compression forces to said mold.

3. The method as recited in claim 1 wherein applying mechanical stresses further includes applying tensile stresses to said mold.

4. The method as recited in claim 1 wherein creating extenuative variations further includes varying said temperature of said substrate to vary said area defined by said region to be less than said area defined by said original pattern.

5. The method as recited in claim 1 wherein creating extenuative variations further includes varying said temperature of said substrate to vary said area defined by said region to be greater than said area defined by said original pattern.

6. The method as recited in claim 1 wherein defining said region further includes defining a plurality of regions on said layer in which to produce said recorded pattern, sequentially placing said original pattern in superimposition with each region associated with a subgroup of said plurality of regions and creating relative extenuative variations between said mold and one of the regions of said subgroup in superimposition therewith by varying said temperature of one of said substrate and said mold so that the area defined by said one of the regions differs from an area defined by said original pattern and applying mechanical stresses further includes applying mechanical stresses to said mold to vary said area defined by said original pattern to be coextensive with said area defined by said one of the regions.

7. The method as recited in claim 1 further including depositing a bead of polymerizable material upon said substrate and spreading said bead over said substrate to define said layer, with forming said recorded pattern further including contacting said layer with said mold to create said recorded pattern in said region and subjecting said layer to conditions to polymerize said layer, wherein creating relative extenuative variations in said substrate and said mold occurs after contacting said layer with said mold.

8. The method as recited in claim 1 further including creating a flowable site on said substrate to define said layer, with forming said recorded pattern further including contacting said if lowable site with said mold to create said recorded pattern in said region and subjecting said layer to conditions to solidify said layer, wherein creating relative extenuative variations in said substrate and said mold occurs after contacting said if lowable region with said mold.

9. The method as recited in claim 1 further including forming a plurality of fiducials in said region and providing said mold with a plurality of alignment marks, wherein creating relative extenuative variations further includes superimposing said mold with said region and sensing differences in alignment between said if iducials and said alignments marks.

10. A method of reducing distortions in a pattern disposed on a layer of a substrate, defining a recorded pattern, employing a mold having features to form said pattern on said layer, defining an original pattern, said method comprising:

defining a plurality of regions on said layer in which to produce said recorded pattern by depositing a plurality of beads of polymerizable material upon said substrate, and spreading said plurality of beads over said substrate to define said layer by repeatably superimposing a mold, having a relief structure, with each of said plurality of regions and contacting said plurality of beads with said mold to create a recess and a protrusion;

forming a plurality of fiducials in each of said plurality of regions and providing said mold with a plurality of alignment marks;

creating relative extenuative variations between said substrate and said mold by varying a temperature of one of said substrate and said mold so that an area defined by said original pattern differs from an area defined by said one of said plurality of regions in superimposition therewith;

applying mechanical stresses to said mold to vary said area defined by said original pattern to be coextensive with said area defined by said one of said plurality of regions; and

sensing differences in alignment between said fiducials and said alignment marks.

11. The method as recited in claim 10 wherein applying mechanical stress further includes applying, to said mold, forces selected from a set of forces consisting essentially of compression forces and tensile forces.

12. The method as recited in claim 11 further including subjecting said layer to conditions to polymerize said polymerizable material.

13. The method as recited in claim 12 wherein creating extenuative variations further includes varying said temperature of said substrate to vary said area defined by said region to be less than said area defined by said original pattern.

14. The method as recited in claim 13 wherein creating extenuative variations further includes varying said temperature of said substrate to vary said area defined by said region to be greater than said area defined by said original pattern.

15. A method of reducing distortions in a pattern disposed on a layer of a substrate, defining a recorded pattern, employing a mold having features to form said pattern on said layer, defining an original pattern, said method comprising:

defining a region on said layer in which to produce said recorded pattern;

creating relative extenuative variations, in first and second transverse directions, between said substrate and said mold by varying a temperature of one of said substrate and said mold so a distance said original pattern extends along said first direction differs from a distance that said region extends along said first direction; and

applying mechanical stress to said mold to vary said distance said original pattern extends along said first direction to be coextensive with said distance said region extends along said first direction.

16. The method as recited in claim 15 wherein creating relative extenuative variations further includes varying said temperature of one of said substrate and said mold so a distance said original pattern extends along said second direction differs from a distance said region extends along said second direction and applying mechanical stress further includes varying said distance said original pattern extends along said second direction to be coextensive with said distance said region extends along said second direction.

17. The method as recited in claim 15 wherein applying mechanical stress further includes applying compression forces to said mold to vary said distance said original pattern extends along said first and second transverse directions.

18. The method as recited in claim 15 wherein applying mechanical stresses further includes applying tensile stresses to said mold to vary said distance said original pattern extends along said first and second transverse directions.

19. The method as recited in claim 15 wherein creating extenuative variations further includes varying said temperature of said substrate to vary said distance along said first direction said region extends to be less than said distance along said first direction said original pattern extends.

20. The method as recited in claim 15 wherein creating extenuative variations further includes varying said temperature of said substrate to vary said distance along said first direction said region extends to be greater than said distance along said first direction said original pattern extends.

Assignments (15)
ASSIGNMENT OF SECURITY INTEREST IN PATENTS Recorded Nov 7, 2019
From: JPMORGAN CHASE BANK, N.A.
To: CITIBANK, N.A.
Reel/Frame 050967/0138 →
PATENT SECURITY AGREEMENT Recorded Aug 22, 2019
From: MAGIC LEAP, INC.; MOLECULAR IMPRINTS, INC.; MENTOR ACQUISITION ONE, LLC
To: JP MORGAN CHASE BANK, N.A.
Reel/Frame 050138/0287 →
CONFIRMATORY ASSIGNMENT OF JOINT PATENT OWNERSHIP Recorded Apr 27, 2015
From: CANON NANOTECHNOLOGIES, INC.
To: MOLECULAR IMPRINTS, INC.
Reel/Frame 035507/0559 →
CHANGE OF NAME Recorded Jul 30, 2014
From: MII NEWCO, INC.
To: MOLECULAR IMPRINTS, INC.
Reel/Frame 033449/0684 →
CHANGE OF NAME Recorded Jul 24, 2014
From: MOLECULAR IMPRINTS, INC.
To: CANON NANOTECHNOLOGIES, INC.
Reel/Frame 033400/0184 →
ASSIGNMENT OF JOINT OWNERSHIP Recorded Jul 15, 2014
From: MOLECULAR IMPRINTS, INC.
To: MII NEWCO, INC.
Reel/Frame 033329/0280 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNOR AND ASSIGNEE PREVIOUSLY RECORDED ON REEL 033161 FRAME 0705. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jun 25, 2014
From: CANON INC.
To: MOLECULAR IMPRINTS, INC.
Reel/Frame 033227/0398 →
RELEASE OF SECURITY INTEREST Recorded Jun 13, 2014
From: MOLECULAR IMPRINTS, INC.
To: CANON INC.
Reel/Frame 033161/0705 →
CORRECTIVE ASSIGNMENT TO CORRECT THE NATURE OF CONVEYANCE FROM AN "ASSIGNMENT" TO "SECURITY AGREEMENT" PREVIOUSLY RECORDED ON REEL 026842 FRAME 0929. ASSIGNOR(S) HEREBY CONFIRMS THE THE ORIGINAL DOCUMENT SUBMITTED WAS A "SECURITY AGREEMENT". Recorded Aug 13, 2013
From: MOLECULAR IMPRINTS, INC.
To: CANON INC.
Reel/Frame 031003/0031 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 1, 2011
From: MOLECULAR IMPRINTS, INC.
To: CANON INC.
Reel/Frame 026842/0929 →
RELEASE OF SECURITY INTEREST Recorded Aug 29, 2011
From: VENTURE LENDING & LEASING III, INC.
To: MOLECULAR IMPRINTS, INC.
Reel/Frame 026821/0159 →
RELEASE OF SECURITY INTEREST Recorded Mar 27, 2007
From: VENTURE LENDING & LEASING IV, INC.
To: MOLECULAR IMPRINTS, INC.
Reel/Frame 019072/0882 →
SECURITY INTEREST Recorded Jan 11, 2005
From: MOLECULAR IMPRINTS, INC.
To: VENTURE LENDING & LEASING IV, INC.
Reel/Frame 016133/0369 →
SECURITY INTEREST Recorded Feb 19, 2003
From: MOLECULAR IMPRINTS, INC.
To: VENTURE LENDING & LEASING III, INC.
Reel/Frame 013760/0150 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 29, 2003
From: RUBIN, DANIEL I.
To: MOLECULAR IMPRINTS, INC.
Reel/Frame 013702/0096 →