Light induced electroless plating
View Patent ↗A method and composition for plating metal contacts on photovoltaic solar cells is described. The cell is immersed in an aqueous bath containing platable metal ions and a chemical reducing agent. The cell is then exposed to light, causing the two sides of the cell to become oppositely charged. The metal ions are plated without requiring an external electrical contact, without backside anodic corrosion and without the need for backside sacrificial material.
1. A method of metalizing a photovoltaic solar cell to deposit a layer of metal thereon, said photovoltaic solar cell having a front side and a backside and said front side having a pattern comprising metal thereon, the method comprising the steps of:
a) contacting the photovoltaic solar cell with an electroless plating composition comprising:
i) a source of soluble silver ions; and
ii) a complexing agent for silver ions selected from the group consisting of cyanide, succinimide or substituted succinimide, hydantoin or substituted hydantoin, uracil, thiosulfate, amines and combinations of one or more of the foregoing;
iii) a reducing agent selected from the group consisting of formaldehyde, glucose, dextrose, glyoxal, sugar inverted by nitric acid, hydrazine or hydrazine sulfate, aldonic acids, aldonic lactones, Rochelle's salts, cobalt ions, sulfide salts, sulfite salts, thiosulfate salts, hypophosphite salts, borohydride salts, alkylamine borane, hydrazineborane, cyanoborohydride salts and combinations of one or more of the foregoing; and thereafter
b) illuminating the photovoltaic solar cell with radiant energy from a light source,
wherein the frontside and backside of the solar cell become oppositely charged and metal ions from the electroless plating solution are plated onto the metallic pattern on the frontside of the solar cell, and wherein the solar cell is not electrically connected to an external power source during the plating.
2. The method according to claim 1 , wherein the source of soluble silver ions is selected from the group consisting of silver oxide, silver nitrate, silver methanesulfonate, silver acetate, silver citrate, silver sulfate and combinations of one or more of the foregoing.
3. The method according to claim 2 , wherein the source of soluble silver ions is silver acetate.
4. The method according to claim 2 , wherein the source of soluble silver ions is silver methanesulfonate.
5. The method according to claim 1 , wherein the concentration of the source of soluble silver ions is between about 15 and about 35 grams/liter.
6. The method according to claim 1 , wherein the reducing agent is a Rochelle salt.
7. The method according to claim 1 , wherein the reducing agent is glyoxal or a salt thereof.
8. The method according to claim 1 , wherein the concentration of the reducing agent is between about 15 and about 60 grams/liter.
9. The method according to claim 1 , wherein the complexing agent is hydantoin or substituted hydantoin.
10. The method according to claim 1 , wherein the concentration of the complexing agent is between about 40 and about 80 grams/liter.
11. The method according to claim 1 , wherein the pattern comprising metal on the front side of the solar cell comprises current collection lines and busbars printed thereon.
12. The method according to claim 11 , wherein the pattern comprising metal comprises printed silver paste.
13. The method according to claim 1 , wherein the light source is a selected from the group consisting of quartz halogen lamps, incandescent lamps and mercury lamps.
14. The method according to claim 1 , wherein the step of contacting the photovoltaic cell with the electroless plating composition comprises immersing the photovoltaic cell in the electroless plating composition.