Method and system for diffusion and implantation in gallium nitride based devices
View Patent ↗A method of forming a doped region in a III-nitride substrate includes providing the III-nitride substrate and forming a masking layer having a predetermined pattern and coupled to a portion of the III-nitride substrate. The III-nitride substrate is characterized by a first conductivity type and the predetermined pattern defines exposed regions of the III-nitride substrate. The method also includes heating the III-nitride substrate to a predetermined temperature and placing a dual-precursor gas adjacent the exposed regions of the III-nitride substrate. The dual-precursor gas includes a nitrogen source and a dopant source. The method further includes maintaining the predetermined temperature for a predetermined time period, forming p-type III-nitride regions adjacent the exposed regions of the III-nitride substrate, and removing the masking layer.
1. A method of forming a doped region in a III-nitride substrate, the method comprising:
providing the III-nitride substrate, wherein the III-nitride substrate is characterized by a first conductivity type;
forming a masking layer having a predetermined pattern and coupled to a portion of the III-nitride substrate, wherein the predetermined pattern defines exposed regions of the III-nitride substrate;
heating the III-nitride substrate to a predetermined temperature;
placing the exposed regions of the III-nitride substrate in a dual-precursor gas comprising both a chemically reactive nitrogen source and a dopant source;
maintaining the predetermined temperature for a predetermined time period;
diffusing the dopant into the exposed regions of the III-nitride substrate and exposing the exposed regions of the III-nitride substrate to the chemically reactive nitrogen source while the exposed regions of the III-nitride substrate are in the dual-precursor gas, wherein the chemically reactive nitrogen source counteracts the effects of nitrogen escaping from the III-nitride substrate while the dopant is diffused into the III-nitride substrate;
forming, using a vapor-phase diffusion process, p-type III-nitride regions in the exposed regions of the III-nitride substrate; and
removing the masking layer.
2. The method of claim 1 wherein the III-nitride substrate comprises an n-type GaN substrate.
3. The method of claim 1 wherein the masking layer comprises a refractory material.
4. The method of claim 1 wherein the predetermined temperature ranges from about 800° C. to about 1800° C.
5. The method of claim 1 wherein the dual-precursor gas includes ammonia and an acceptor species.
6. The method of claim 1 wherein placing the exposed regions of the III-nitride substrate in the dual-precursor gas comprises:
positioning the III-nitride substrate in a chamber; and
flowing the dual-precursor gas including both the nitrogen source and the dopant source through the chamber.
7. The method of claim 6 wherein the chamber comprises an MOCVD chamber.
8. A method of forming a doped region in a III-nitride substrate, the method comprising:
providing the III-nitride substrate, wherein the III-nitride substrate is characterized by a first conductivity type;
forming a masking layer having a predetermined pattern and coupled to a portion of the III-nitride substrate, wherein the predetermined pattern defines predetermined portions of the III-nitride substrate;
placing the III-nitride substrate in a chamber;
forming an environment in the chamber, wherein the environment comprises a dual-precursor gas including both a chemically reactive nitrogen source and a dopant source;
implanting the dopant into the predetermined portions of the III-nitride substrate, wherein the dopant is characterized by a second conductivity type and exposing the III-nitride substrate to the chemically reactive nitrogen source while the III-nitride substrate is in the dual-precursor gas, wherein the chemically reactive nitrogen source counteracts the effects of nitrogen escaping from the III-nitride substrate while the dopant is implanted into the III-nitride substrate;
heating the III-nitride substrate to a predetermined temperature;
maintaining the predetermined temperature for a predetermined time period; and
removing the masking layer.
9. The method of claim 8 wherein the chamber comprises an MOCVD reactor.
10. The method of claim 8 wherein the chamber comprises an annealing furnace.
11. The method of claim 8 wherein the III-nitride substrate comprises an n-type GaN substrate.
12. The method of claim 8 wherein the masking layer comprises a refractory material.
13. The method of claim 8 wherein removing the masking layer is performed prior to placing the III-nitride substrate in the chamber.
14. The method of claim 8 wherein the predetermined temperature ranges from about 800° C. to about 1800° C.
15. The method of claim 8 wherein the dopant comprises an acceptor species.
16. The method of claim 8 further comprising forming a sacrificial layer coupled to the III-nitride substrate prior to implanting the dopant.
17. The method of claim 16 further comprising removing the sacrificial layer is performed after maintaining the predetermined temperature for the predetermined time period.
18. The method of claim 8 wherein implanting a dopant into the predetermined portions of the III-nitride substrate comprises performing an ion implantation process.