IP Library Granted Patent US 9,142,566
Granted Patent B2
US 9,142,566 · App. 14/021,485 · Granted Sep 22, 2015

Method of forming different voltage devices with high-K metal gate

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 9,142,566
App. No.
14/021,485
Granted
Sep 22, 2015
Kind
B2
Abstract

A method and apparatus are described for integrating high voltage (HV) transistor devices and medium voltage or dual gate oxide (DGO) transistor devices with low voltage (LV) core transistor devices on a single substrate, where each high voltage transistor device ( 160 ) includes a metal gate ( 124 ), an upper high-k gate dielectric layer ( 120 ), a middle gate dielectric layer ( 114 ) formed with a relatively lower high-k dual gate oxide layer, and a lower high voltage gate dielectric stack ( 108, 110 ) formed with one or more low-k gate oxide layers ( 22 ), where each DGO transistor device ( 161 ) includes a metal gate ( 124 ), an upper high-k gate dielectric layer ( 120 ), and a middle gate dielectric layer ( 114 ) formed with a relatively lower high-k dual gate oxide layer, and where each core transistor device ( 162 ) includes a metal gate ( 124 ), an upper high-k gate dielectric layer ( 120 ), and a base oxide layer ( 118 ) formed with one or more low-k gate oxide layers.

Claims (24)

1. A semiconductor fabrication process comprising:

providing a wafer comprising a first device area for forming one or more first voltage level transistors, a second device area for forming one or more second voltage level dual gate oxide transistors, and a third device area for forming one or more third voltage level transistors;

forming a high voltage gate dielectric stack on the first and third device areas of the wafer and not on the second device area of the wafer;

forming a dual gate oxide layer over the first, second, and third device areas of the wafer by depositing one or more oxide layers on the high voltage gate dielectric stack and on the exposed second device area of the wafer;

removing the high voltage gate dielectric stack and dual gate oxide layer from the third device area of the wafer while leaving the dual gate oxide layer formed on the first and second device areas;

forming a high-k gate dielectric stack over the first, second, and third device areas of the wafer to cover the dual gate oxide layer formed on the first and second device areas and the third device area of the wafer; and

forming a plurality of patterned high-k metal gate electrodes on the high-k gate dielectric stack in each of the first, second, and third device areas; where the first voltage level is higher than the second voltage level which is higher than the third voltage level.

2. The semiconductor fabrication process of claim 1 , where providing the wafer comprises providing a first semiconductor layer as a semiconductor-on-insulator (SOI) substrate structure or bulk substrate structure comprising one or more shallow trench isolation regions for separating the first, second, and third device areas from one another.

3. The semiconductor fabrication process of claim 1 , where providing the wafer comprises providing a compressive silicon germanium layer formed in the second device area and in a portion of the third device area where PMOS transistors are formed.

4. The semiconductor fabrication process of claim 1 , where forming the high voltage gate dielectric stack comprises:

thermally growing a first oxide layer on the wafer on the first, second, and third device areas;

depositing a second oxide layer on the first oxide layer over the first, second, and third device areas; and

selectively removing the first and second oxide layers from the second device area, thereby exposing the second device area of the wafer.

5. The semiconductor fabrication process of claim 1 , where forming the dual gate oxide layer comprises depositing a high-k dielectric layer comprising a silicate or metal oxy-nitride material.

6. The semiconductor fabrication process of claim 1 , where removing the high voltage gate dielectric stack and dual gate oxide layer from the third device area comprises:

forming a patterned etch mask to cover the high voltage gate dielectric stack and dual gate oxide layer formed over the first device area and to protect the dual gate oxide layer formed over the second device area; and

selectively etching the high voltage gate dielectric stack and dual gate oxide layer formed over the third device area to expose the third device area.

7. The semiconductor fabrication process of claim 1 , where forming the high-k gate dielectric stack comprises:

thermally growing a base oxide layer on the wafer on at least the exposed third device area of the wafer;

depositing a high-k layer of hafnium-based dielectric material to cover the dual gate oxide layer formed over the first and second device areas and to cover the base oxide layer formed over the third device area; and

depositing a metal-based barrier layer on the high-k layer of hafnium-based dielectric material to cover the first, second, and third device areas.

8. The semiconductor fabrication process of claim 1 , where forming the plurality of patterned high-k metal gate electrodes comprises:

depositing a polysilicon layer on the high-k gate dielectric stack in each of the first, second, and third device areas; and

patterning and etching the polysilicon layer and underlying high-k gate dielectric stack to form the plurality of patterned high-k metal gate electrodes.

Assignments (28)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 042985 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051029/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 039361 FRAME 0212. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051029/0387 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051030/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 042762 FRAME 0145. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051145/0184 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050745/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050744/0097 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
Reel/Frame 048734/0001 →
RELEASE OF SECURITY INTEREST Recorded May 29, 2017
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP USA, INC. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 042610/0451 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12681366 PREVIOUSLY RECORDED ON REEL 039361 FRAME 0212. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded May 9, 2017
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 042762/0145 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12681366 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded May 9, 2017
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 042985/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 29, 2017
From: NXP USA, INC.
To: VLSI TECHNOLOGY LLC
Reel/Frame 042374/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 041703/0536 →
MERGER Recorded Jan 3, 2017
From: FREESCALE SEMICONDUCTOR, INC.
To: NXP USA, INC.
Reel/Frame 041144/0363 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE INCORRECT PCT NUMBERS IB2013000664, US2013051970, US201305935 PREVIOUSLY RECORDED AT REEL: 037444 FRAME: 0787. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Oct 17, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 040450/0715 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12092129 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Jul 14, 2016
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039361/0212 →
SUPPLEMENT TO THE SECURITY AGREEMENT Recorded Jun 16, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039138/0001 →
SECURITY AGREEMENT SUPPLEMENT Recorded Mar 7, 2016
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 038017/0058 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 13, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037518/0292 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 5, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037444/0787 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037357/0874 →
SUPPLEMENT TO IP SECURITY AGREEMENT Recorded Nov 13, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 031627/0201 →
SUPPLEMENT TO IP SECURITY AGREEMENT Recorded Nov 13, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 031627/0158 →
SECURITY AGREEMENT Recorded Nov 6, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 031591/0266 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 9, 2013
From: HONG, CHEONG MIN; PERERA, ASANGA H.; KANG, SUNG-TAEG
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 031166/0494 →