IP Library Granted Patent US 10,170,519
Granted Patent B2
US 10,170,519 · App. 15/261,755 · Granted Jan 1, 2019

Magnetoresistive element and memory device

Inventors: Youngmin Eeh (Seongnam-si, KR); Toshihiko Nagase (Seoul, KR); Daisuke Watanabe (Seoul, KR); Koji Ueda (Yokkaichi Mie, JP); Makoto Nagamine (Seoul, KR); Kazuya Sawada (Seoul, KR)
Assignee: TOSHIBA MEMORY CORPORATION
H01L27/228G11C11/161H01L28/00H01L43/02H01L43/10
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Quick Facts
Patent No.
US 10,170,519
App. No.
15/261,755
Granted
Jan 1, 2019
Kind
B2
Abstract

According to one embodiment, a magnetoresistive element includes a first metal layer having a body-centered cubic structure, a second metal layer having a hexagonal close-packed structure on the first metal layer, a metal nitride layer on the second metal layer, a first magnetic layer on the metal nitride layer, an insulating layer on the first magnetic layer, and a second magnetic layer on the insulating layer.

Claims (42)

1. A magnetoresistive element comprising:

a first metal layer having a body-centered cubic structure;

a second metal layer having a hexagonal close-packed structure on the first metal layer;

a metal nitride layer on the second metal layer;

a first magnetic layer on the metal nitride layer;

an insulating layer on the first magnetic layer; and

a second magnetic layer on the insulating layer.

2. The magnetoresistive element of claim 1 , wherein the first metal layer comprises one of Nb, Mo, Ta, Cr and V.

3. The magnetoresistive element of claim 1 , wherein the second metal layer comprises one of Hf, Sc, Y and Zr.

4. The magnetoresistive element of claim 1 , wherein:

the metal nitride layer comprises a nitrogen compound or a mixture of the nitrogen compound and an oxygen compound,

the nitrogen compound comprises magnesium nitride, zirconium nitride, niobium nitride, silicon nitride, aluminum nitride, hafnium nitride, tantalum nitride, tungsten nitride, chromium nitride, molybdenum nitride, titanium nitride, or vanadium nitride, and

the oxygen compound comprises magnesium oxide.

5. The magnetoresistive element of claim 1 , wherein each of the first and second magnetic layers comprises Co and Fe, and the insulating layer comprises magnesium oxide.

6. The magnetoresistive element of claim 3 , wherein:

each of the first and second magnetic layers has a body-centered cubic structure in which a film surface is orientated in a (001)-surface, and

the insulating layer has an NaCl structure in which a film surface is orientated in a (001)-surface.

7. The magnetoresistive element of claim 1 , wherein the first metal layer has a thickness of 0.5 nm or more and 4.5 nm or less.

8. The magnetoresistive element of claim 1 , wherein the second metal layer has a thickness of 2 nm or more and 20 nm or less.

9. The magnetoresistive element of claim 1 , wherein the metal nitride layer has a thickness of 0.4 nm or more and 2 nm or less.

10. The magnetoresistive element of claim 1 , wherein the metal nitride layer has a hexagonal close-packed structure.

11. The magnetoresistive element of claim 1 , wherein the first magnetic layer has variable magnetization direction, and the second magnetic layer has invariable magnetization direction.

12. The magnetoresistive element of claim 11 , further comprising:

a third metal layer on the second magnetic layer; and

a third magnetic layer having invariable magnetization on the third metal layer,

wherein the second and third magnetic layers are SAF-coupled to each other.

13. The magnetoresistive element of claim 1 , further comprising:

a third metal layer under the first metal layer,

wherein the third metal layer has a crystal structure or an amorphous structure.

14. The magnetoresistive element of claim 1 , wherein each of the first and second magnetic layers has an axis of easy magnetization in a direction perpendicular to a film surface.

15. The magnetoresistive element of claim 1 , wherein each of the first and second magnetic layers includes an element selected from a group of Mo, W, Ta, Zr, Hf, Cr and V.

16. A memory device comprising:

a semiconductor substrate;

a select transistor on the semiconductor substrate; and

the magnetoresistive element of claim 1 above the select transistor, the magnetoresistive element being connected to the select transistor.

17. A magnetoresistive element comprising:

a first metal layer comprising one of Nb, Mo, Ta, Cr and V, and having a body-centered cubic structure;

a second metal layer on the first metal layer, the second metal layer comprising one of Hf, Sc, Y and Zr, and having a hexagonal close-packed structure, wherein the second metal layer is in direct contact with the first metal layer;

an aluminum nitride layer on the second metal layer;

a first magnetic layer on the aluminum nitride layer;

an insulating layer on the first magnetic layer; and

a second magnetic layer on the insulating layer.

Assignments (5)
MERGER Recorded Jan 22, 2021
From: TOSHIBA MEMORY CORPORATION
To: K.K. PANGEA
Reel/Frame 055659/0471 →
CHANGE OF NAME AND ADDRESS Recorded Jan 22, 2021
From: TOSHIBA MEMORY CORPORATION
To: KIOXIA CORPORATION
Reel/Frame 055669/0001 →
CHANGE OF NAME AND ADDRESS Recorded Jan 22, 2021
From: K.K. PANGEA
To: TOSHIBA MEMORY CORPORATION
Reel/Frame 055669/0401 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 14, 2017
From: KABUSHIKI KAISHA TOSHIBA
To: TOSHIBA MEMORY CORPORATION
Reel/Frame 043194/0563 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 28, 2017
From: EEH, YOUNGMIN; NAGASE, TOSHIHIKO; WATANABE, DAISUKE; UEDA, KOJI; NAGAMINE, MAKOTO; SAWADA, KAZUYA
To: KABUSHIKI KAISHA TOSHIBA
Reel/Frame 042843/0807 →
Continuity (2)
Provisional Application 62308120 · Mar 14, 2016
Related Publication 20170263676A1 · Sep 14, 2017
Cited By (6)
US 12,284,811 US 12,310,251 US 12,329,038 US 12,356,866 US 12,501,837 US 12,520,499