IP Library Granted Patent US 10,115,505
Granted Patent B2
US 10,115,505 · App. 15/440,040 · Granted Oct 30, 2018

Chip resistor

Inventors: Mamoru Murakami (Yokohama, JP); Yusuke Tachibana (Kanagawa, JP)
Assignee: E I DU PONT DE NEMOURS AND COMPANY
H01C17/006H01C1/012H01C1/148H01C17/28
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Quick Facts
Patent No.
US 10,115,505
App. No.
15/440,040
Granted
Oct 30, 2018
Kind
B2
Abstract

The invention relates to a chip resistor. A method of manufacturing a chip resistor comprises the steps of: (a) applying a conductive paste on an insulating substrate, wherein the conductive paste comprises, (i) 40 to 80 weight percent (wt. %) of a conductive powder; (ii) 1 to 14 wt. % of a glass frit, (iii) 0.01 to 3 wt. % of magnesium oxide (MgO), and (iv) 10 to 55 wt. % of an organic vehicle, wherein the wt. % is based on weight of the conductive paste; (b) firing the applied conductive paste to form the front electrodes.

Claims (27)

1. A method of manufacturing a chip resistor comprising the steps of:

(a) applying a conductive paste on an insulating substrate, wherein the conductive paste comprises,

(i) 40 to 80 weight percent (wt. %) of a conductive powder;

(ii) 1 to 14 wt. % of a glass frit,

(iii) 0.01 to 3 wt. % of magnesium oxide (MgO),

(iv) 10 to 55 wt. % of an organic vehicle, and

(v) anorthite (CaAl 2 Si 2 O 8 ),

wherein the wt. % is based on weight of the conductive paste;

(b) firing the applied conductive paste to form the front electrodes.

2. The method of claim 1 , wherein the insulating substrate is a ceramic substrate.

3. The method of claim 1 , wherein particle diameter (D50) of the conductive powder is 0.5 to 12 μm.

4. The method of claim 1 , wherein the conductive powder is selected from the group consisting of aluminum, nickel, copper, silver, gold, molybdenum, magnesium, tungsten, cobalt, zinc, platinum, palladium, an alloy thereof and a mixture thereof.

5. The method of claim 1 , wherein the glass frit is a lead-free glass frit comprising a metal oxide selected from the group consisting of bismuth oxide (Bi 2 O 3 ), boron oxide (B 2 O 3 ), zinc oxide (ZnO), aluminum oxide (Al 2 O 3 ), silicon oxide (SiO 2 ) and a mixture thereof.

6. The method of claim 1 , wherein the MgO is in shape of powder with particle diameter (D50) of 0.1 to 8 μm.

7. The method of claim 1 , wherein the firing temperature in step (b) is 700 to 950° C.

8. The method of claim 1 , wherein the method further comprises steps (c) applying a resistor paste on the insulating substrate to bridge a pair of front electrodes; and (d) firing the applied resistor paste to form a resistor thick film.

9. A conductive paste to form front electrodes of a chip resistor, the conductive paste comprises:

(i) 40 to 80 weight percent (wt. %) of a conductive powder;

(ii) 1 to 14 wt. % of a glass frit,

(iii) 0.01 to 3 wt. % of magnesium oxide (MgO),

(iv) 10 to 55 wt. % of an organic vehicle, and

(v) anorthite (CaAl 2 Si 2 O 8 ),

wherein the wt. % is based on weight of the conductive paste.

10. The conductive paste of claim 9 , wherein particle diameter (D50) of the conductive powder is 0.5 to 12 μm.

11. The conductive paste of claim 9 , wherein the glass frit is a lead-free glass frit comprising a metal oxide selected from the group consisting of bismuth oxide (Bi 2 O 3 ), boron oxide (B 2 O 3 ), zinc oxide (ZnO), aluminum oxide (Al 2 O 3 ), silicon oxide (SiO 2 ) and a mixture thereof.

12. The conductive paste of claim 9 , wherein the MgO is in shape of powder with particle diameter (D50) of 0.1 to 8 μm.

13. A chip resistor comprises an insulating substrate, a pair of front electrodes formed on the insulating substrate, and a resistor thick film formed on the insulating substrate to bridge a pair of front electrodes, wherein the front electrodes comprises a conductive metal, a glass, and magnesium oxide (MgO) and anorthite (CaAl 2 Si 2 O 8 ).

Assignments (4)
CHANGE OF NAME Recorded Mar 20, 2025
From: DU PONT CHINA LIMITED
To: CELANESE MERCURY HOLDINGS INC.
Reel/Frame 070567/0231 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 20, 2022
From: DUPONT ELECTRONICS, INC.
To: DU PONT CHINA LIMITED
Reel/Frame 062201/0889 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 25, 2019
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: DUPONT ELECTRONICS, INC.
Reel/Frame 049583/0269 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 3, 2017
From: MURAKAMI, MAMORU; TACHIBANA, YUSUKE
To: E. I. DU PONT DE NEMOURS AND COMPANY
Reel/Frame 041464/0748 →
Continuity (1)
Related Publication 20180240576A1 · Aug 23, 2018
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