Composition for a polishing pad, polishing pad, and process for preparing the same
In the composition according to the embodiment, the content of an unreacted diisocyanate monomer in a urethane-based prepolymer may be controlled to control the physical properties thereof such as gelation time. Thus, since the micropore characteristics, polishing rate, and pad cut rate of a polishing pad obtained by curing the composition according to the embodiment may be controlled, it is possible to efficiently manufacture high-quality semiconductor devices using the polishing pad.
1. A composition, which comprises a urethane-based prepolymer, a curing agent, and a foaming agent, wherein the urethane-based prepolymer comprises a prepolymerization reaction product of at least one diisocyanate monomer and at least one polyol, the at least one diisocyanate monomer comprises at least one aromatic diisocyanate monomer, and the urethane-based prepolymer comprises an unreacted diisocyanate monomer in an amount of 5% by weight to 13% by weight based on the weight of the urethane-based prepolymer.
2. The composition of claim 1 , wherein the urethane-based prepolymer comprises the unreacted diisocyanate monomer in an amount of 9% by weight to 11% by weight based on the weight of the urethane-based prepolymer.
3. The composition of claim 2 , wherein the urethane-based prepolymer comprises an unreacted aromatic diisocyanate monomer in an amount of 2% by weight to 4% by weight based on the weight of the urethane-based prepolymer.
4. The composition of claim 1 , wherein the urethane-based prepolymer comprises an unreacted NCO group in an amount of 5% by weight to 13% by weight and an unreacted aromatic diisocyanate monomer in an amount of 0.1% by weight to 5% by weight, based on the weight of the urethane-based prepolymer.
5. The composition of claim 4 , wherein the urethane-based prepolymer comprises the unreacted NCO group in an amount of 7% by weight to 10% by weight based on the weight of the urethane-based prepolymer.
6. The composition of claim 5 , wherein the urethane-based prepolymer comprises the unreacted aromatic diisocyanate monomer in an amount of 1% by weight to 3% by weight based on the weight of the urethane-based prepolymer.
7. The composition of claim 1 , wherein the urethane-based prepolymer comprises an aromatic diisocyanate monomer in which two NCO groups are reacted in an amount of 10% by weight to 40% by weight based on the total weight of the at least one aromatic diisocyanate monomer.
8. The composition of claim 7 , wherein the urethane-based prepolymer comprises the aromatic diisocyanate monomer in which two NCO groups are reacted in an amount of 15% by weight to 25% by weight based on the total weight of the at least one aromatic diisocyanate monomer.
9. The composition of claim 7 , wherein the urethane-based prepolymer comprises an aromatic diisocyanate monomer in which one NCO group is reacted in an amount of 50% by weight to 80% by weight based on the total weight of the at least one aromatic diisocyanate monomer.
10. The composition of claim 9 , wherein the urethane-based prepolymer comprises the aromatic diisocyanate monomer in which two NCO groups are reacted and the aromatic diisocyanate monomer in which one NCO group is reacted at a weight ratio of 0.2:1 to 0.5:1.
11. The composition of claim 1 , wherein the at least one aromatic diisocyanate monomer comprises toluene 2,4-diisocyanate and toluene 2,6-diisocyanate, and
the urethane-based prepolymer comprises unreacted toluene 2,6-diisocyanate in an amount of 0.1% by weight to 3% by weight based on the weight of the urethane-based prepolymer.
12. The composition of claim 11 , wherein the urethane-based prepolymer comprises toluene 2,4-diisocyanate in which two NCO groups are reacted in an amount of 10% by weight to 30% by weight based on the total weight of the at least one aromatic diisocyanate monomer.
13. The composition of claim 11 , wherein the urethane-based prepolymer comprises toluene 2,4-diisocyanate in which one NCO group is reacted in an amount of 50% by weight to 65% by weight based on the total weight of the at least one aromatic diisocyanate monomer.
14. The composition of claim 11 , wherein the urethane-based prepolymer comprises toluene 2,6-diisocyanate in which one NCO group is reacted in an amount of 10% by weight to 20% by weight based on the total weight of the at least one aromatic diisocyanate monomer.
15. The composition of claim 1 , wherein the at least one diisocyanate monomer comprises at least one aliphatic diisocyanate monomer, and
the urethane-based prepolymer comprises the unreacted aromatic diisocyanate monomer and the unreacted aliphatic diisocyanate monomer at a weight ratio of 0.05:1 to 0.7:1.
16. The composition of claim 1 , which has a gelation time of 80 seconds to 130 seconds and has, upon curing, a tensile strength of 10 N/mm 2 to 23 N/mm 2 , an elongation of 80% to 250%, and a hardness of 40 Shore D to 65 Shore D.
17. A process for preparing a polishing pad, which comprises preparing a first raw material composition comprising a urethane-based prepolymer, a second raw material composition comprising a curing agent, and a third raw material composition comprising a foaming agent;
preparing a raw material mixture by sequentially or simultaneously mixing the first raw material composition with the second raw material composition and the third raw material composition; and
injecting the raw material mixture into a mold and curing it,
wherein the urethane-based prepolymer comprises a prepolymerization reaction product of at least one diisocyanate monomer and at least one polyol, the at least one diisocyanate monomer comprises at least one aromatic diisocyanate monomer, and the urethane-based prepolymer comprises an unreacted diisocyanate monomer in an amount of 5% by weight to 13% by weight based on the weight of the urethane-based prepolymer.
18. A polishing pad, which comprises a polyurethane resin and a plurality of micropores dispersed in the polyurethane resin, wherein the polyurethane resin is derived from a urethane-based prepolymer, the urethane-based prepolymer comprises a prepolymerization reaction product of at least one diisocyanate monomer and at least one polyol, the at least one diisocyanate monomer comprises at least one aromatic diisocyanate monomer, and the urethane-based prepolymer comprises an unreacted diisocyanate monomer in an amount of 5% by weight to 13% by weight based on the weight of the urethane-based prepolymer.
19. The polishing pad of claim 18 , wherein the micropores have an average size of 20 μm to 25 μm, and the polishing pad has a polishing rate of 3,500 Å/50 seconds to 5,000 Å/50 seconds.
20. A process for preparing a semiconductor device, which comprises polishing the surface of a semiconductor substrate using the polishing pad of claim 18 .