Liquid developer and method of producing liquid developer
A liquid developer containing a liquid carrier and a toner particle that is insoluble in the liquid carrier, wherein a particular substructure is bonded through a covalent bond to a surface of the toner particle, and a method of producing a liquid developer containing a liquid carrier and a toner particle that is insoluble in the liquid carrier, the method comprising a step (I) of covalently bonding, to a surface of the toner particle, a compound having a particular substructure.
1. A liquid developer, comprising:
a liquid carrier; and
a toner particle having a surface comprising a binder resin, the binder resin being a reaction product of (i) a resin having an acid anhydride group and (ii) a compound having a primary amino group and a substructure represented by formula (3)
where R 1 represents an optionally substituted C 6-20 alkylene group or an optionally substituted C 6-20 cycloalkylene group, and p is an integer of at least 1, wherein
the acid anhydride group has been reacted with the primary amino group thereby forming an amide bond binding the resin and the compound to form the binder resin having the substructure, the substructure in the binder resin being covalently bonded to the surface of the toner particle, and
the toner particle is insoluble in the liquid carrier.
2. The liquid developer according to claim 1 , wherein the resin having an acid anhydride group has a weight-average molecular weight of at least 15,000, and
the resin having an acid anhydride group contains no more than 5 mass % of a component having a molecular weight not greater than 1,000.
3. The liquid developer according to claim 1 , wherein the resin having an acid anhydride group has an acid anhydride content of 0.01 to 0.10 mmol/g.
4. The liquid developer according to claim 1 , wherein the substructure represented by formula (3) is represented by formula (4)
5. The liquid developer according to claim 1 , wherein the compound having the primary amino group and substructure represented by formula (3) has an amine value of at least 30 mg KOH/g.