Toner and method for producing toner
A toner comprising a toner particle comprising a binder resin, wherein the binder resin comprises a first resin and a second resin, the first resin is a crystalline resin, the second resin is an amorphous resin, in an observation of a cross section of the toner particle with a transmission electron microscope, a matrix-domain structure composed of a matrix comprising the first resin and domains comprising the second resin is present, an area ratio occupied by the matrix in a total area of the matrix and the domains is from 35 area % to 70 area %, a [hydrocarbon group index (Ge)]/[hydrocarbon group index (DIA)] after washing the toner with hexane is 1.10 or more.
1. A toner, comprising:
a toner particle comprising a binder resin;
the binder resin comprising a first resin and a second resin;
the first resin being a crystalline resin;
the second resin being an amorphous resin; and
a matrix-domain structure composed of a matrix comprising the first resin and domains comprising the second resin is present when a cross section of the toner particle is observed with a transmission electron microscope, with an area ratio occupied by the matrix in a total area of the matrix and the domains being 35 to 70 area %, wherein
a ratio [hydrocarbon group index (Ge)]/[hydrocarbon group index (DIA)] after washing the toner with hexane is 1.10 or more,
the hydrocarbon group index (Ge) is a value of A (Ge)/B (Ge) where A (Ge) is a maximum absorption peak intensity in a range of 2800 to 2900 cm −1 corresponding to a stretching vibration of C—H and B (Ge) is a maximum absorption peak intensity in a range of 1500 to 1800 cm −1 corresponding to a stretching vibration of C═O in an FT-IR spectrum obtained by using Ge as an ATR crystal and performing measurements by an ATR method under condition of an infrared light incident angle being 45°, and
the hydrocarbon group index (DIA) is a value of A (DIA)/B (DIA) where A (DIA) is a maximum absorption peak intensity in a range of 2800 to 2900 cm −1 corresponding to the stretching vibration of C—H and B (DIA) is a maximum absorption peak intensity in a range of 1500 to 1800 cm −1 corresponding to the stretching vibration of C═O in an FT-IR spectrum obtained by using diamond as an ATR crystal and performing measurements by the ATR method under condition of the infrared light incident angle being 45°.
2. The toner according to claim 1 , wherein the number average circle-equivalent diameter of the domains is 20 to 500 nm.
3. The toner according to claim 1 , wherein a charge decay rate coefficient of the toner particle measured in an environment of 30° C. and 80% RH is 10 to 70.
4. The toner according to claim 1 , wherein the first resin has a first monomer unit represented by formula (1):
where R Z1 represents a hydrogen atom or a methyl group, and R1 represents an alkyl group having 18 to 36 carbon atoms.
5. The toner according to claim 4 , wherein a content ratio of the first monomer unit in the first resin is 30 to 80.0% by mass.
6. The toner according to claim 1 , wherein the second resin is a polyester resin, a styrene acrylic resin, or a hybrid resin of a polyester resin and a styrene acrylic resin.
7. The toner according to claim 1 , wherein the second resin is a styrene acrylic resin.
8. The toner according to claim 1 , wherein the ratio [hydrocarbon group index (Ge)/hydrocarbon group index (DIA)] is 1.20 to 1.60.
9. A method for producing a toner comprising a toner particle comprising a binder resin, comprising the step of:
surface-treating the toner particle with hot air to obtain a heat-treated toner particle;
the binder resin comprising a first resin and a second resin;
the first resin being a crystalline resin;
the second resin being an amorphous resin; and
a matrix-domain structure composed of a matrix comprising the first resin and domains comprising the second resin is present when a cross section of the toner particle is observed with a transmission electron microscope, with an area ratio occupied by the matrix in a total area of the matrix and the domains being 35 to 70 area %, wherein
a ratio [hydrocarbon group index (Ge)]/[hydrocarbon group index (DIA)] after washing the toner with hexane is 1.10 or more,
the hydrocarbon group index (Ge) is a value of A (Ge)/B (Ge) where A (Ge) is a maximum absorption peak intensity in a range of 2800 to 2900 cm −1 corresponding to a stretching vibration of C—H and B (Ge) is a maximum absorption peak intensity in a range of 1500 to 1800 cm −1 corresponding to a stretching vibration of C═O in an FT-IR spectrum obtained by using Ge as an ATR crystal and performing measurements by an ATR method under condition of an infrared light incident angle being 45°, and
the hydrocarbon group index (DIA) is a value of A (DIA)/B (DIA) where A (DIA) is a maximum absorption peak intensity in a range of 2800 to 2900 cm −1 corresponding to the stretching vibration of C—H and B (DIA) is a maximum absorption peak intensity in a range of 1500 to 1800 cm −1 corresponding to the stretching vibration of C═O in an FT-IR spectrum obtained by using diamond as an ATR crystal and performing measurements by the ATR method under condition of the infrared light incident angle being 45°.