IP Library Granted Patent US 12,357,547
Granted Patent B2
US 12,357,547 · App. 18/150,292 · Granted Jul 15, 2025

Compositions containing microcapsules

Inventors: Takashi Sasaki (Union Beach, NJ); Johan G.L. Pluyter (Union Beach, NJ)
Assignee: International Flavors & Fragrances Inc.
A61K8/11A61K8/645A61K8/8152A61K8/84A61Q5/02A61Q13/00C11D3/3726C11D3/38C11D3/505C11D17/0039
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,357,547
App. No.
18/150,292
Granted
Jul 15, 2025
Kind
B2
Abstract

A microcapsule composition containing microcapsules coated with a deposition protein, e.g., a protein-silanol copolymer, a protein-silane copolymer, a protein-siloxane copolymer, or a cationically modified protein, is provided as is a method for making the microcapsule composition and using the microcapsule composition in consumer products, in particular rinse-off consumer product.

Claims (19)

1. A microcapsule composition comprising a plurality of microcapsules each containing a polymeric wall and an active material encapsulated within the polymeric wall; the polymeric wall contains a protein or a chitosan; and the polymeric wall is coated with a cross-linked protein-silicon copolymer.

2. The microcapsule composition of claim 1 , wherein the polymeric wall further contains 0.2% to 5%, based on the weight of the microcapsule composition, of an aromatic polyisocyanate having a phenyl, tolyl, xylyl, naphthyl, or diphenyl moiety as the aromatic component.

3. The microcapsule composition of claim 1 , further comprising a hydrocolloid.

4. A consumer product comprising a consumer product base and a microcapsule composition of claim 1 .

5. The consumer product of claim 4 , wherein the consumer product is a fabric conditioner, detergent, fabric spray, personal wash product, home care product, liquid soap, shampoo, rinse-off conditioner, or leave-on conditioner.

6. The microcapsule composition of claim 2 , wherein the aromatic polyisocyanate is a trimethylol propane-adduct of xylylene diisocyanate.

7. The microcapsule composition of claim 1 , wherein the protein-silicon copolymer comprises a protein-siloxane copolymer.

8. The microcapsule composition of claim 1 , wherein the protein-silicon copolymer has a molecular weight in the range of 1000 to 500,000.

9. The microcapsule composition of claim 1 , wherein the protein component of the protein-silicon copolymer comprises between 2% and 25% basic amino acids.

10. The microcapsule composition of claim 1 , wherein the protein component of the protein-silicon copolymer comprises a hydrolyzed protein.

11. The microcapsule composition of claim 1 , wherein the protein component of the protein-silicon copolymer comprises a wheat protein and/or a potato protein.

12. The microcapsule composition of claim 1 , wherein the cross-linked protein-silicon copolymer has siloxane cross-links.

13. A microcapsule composition comprising a plurality of microcapsules each containing a polymeric wall and an active material encapsulated within the polymeric wall; the polymeric wall contains a protein or a chitosan; and the polymeric wall is coated with a protein-acrylate copolymer having a nitrogen-containing acrylic moiety.

14. The microcapsule composition of claim 13 , wherein the nitrogen-containing acrylic moiety comprises a tertiary or quaternary amine group.

15. The microcapsule composition of claim 13 , wherein the protein component of the protein-acrylate copolymer comprises between 2% and 25% basic amino acids.

16. The microcapsule composition of claim 13 , wherein the protein component of the protein-acrylate copolymer comprises a hydrolyzed protein.

17. The microcapsule composition of claim 13 , wherein the protein component of the protein-acrylate copolymer comprises a wheat protein and/or a potato protein.

18. The microcapsule composition of claim 13 further comprising a sulfonated naphthalene-formaldehyde condensate.

19. A consumer product comprising a consumer product base and a microcapsule composition of claim 13 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 6, 2023
From: SASAKI, TAKASHI; PLUYTER, JOHAN G. L.
To: INTERNATIONAL FLAVORS & FRAGRANCES INC.
Reel/Frame 062297/0854 →
Continuity (6)
Continuation 17459348 · Aug 27, 2021
Continuation 16881820 · May 22, 2020
Continuation 15971241 · May 4, 2018
Continuation 15381145 · Dec 16, 2016
Provisional Application 62272743 · Dec 30, 2015
Related Publication 20230172820A1 · Jun 8, 2023
References Cited (39)
US 4946624A · Michael · 1990 [cited by applicant]
US 6045835A · Soper et al. · 2000 [cited by applicant]
US 6979467B1 · Garces Garces et al. · 2005 [cited by applicant]
US 9974720B2 · Sasaki et al. · 2018 [cited by applicant]
US 10188593B2 · Dihora et al. · 2019 [cited by applicant]
US 10695272B2 · Sasaki · 2020 [cited by examiner]
US 11129778B2 · Sasaki · 2021 [cited by examiner]
US 11602494B2 · Sasaki · 2023 [cited by examiner]
US 20060248665A1 · Pluyter et al. · 2006 [cited by applicant]
US 20090176291A1 · Boutique et al. · 2009 [cited by applicant]
US 20140023688A1 · Budijono et al. · 2014 [cited by applicant]
US 20140135253A1 · Bellouard-Drevet · 2014 [cited by examiner]
US 20150164117A1 · Kaplan et al. · 2015 [cited by applicant]
US 20150250689A1 · Dardelle et al. · 2015 [cited by applicant]
US 20160108340A1 · Feng · 2016 [cited by examiner]
US 20160158121A1 · Lei · 2016 [cited by examiner]
US 20180078468A1 · Jerri et al. · 2018 [cited by applicant]
EP 2934464B1 · 2018 [cited by applicant]
GB 2375340 · 2002 [cited by examiner]
WO 2008142637A1 · 2008 [cited by applicant]
WO 2009080401A2 · 2009 [cited by applicant]
WO 2011056904A1 · 2009 [cited by applicant]
WO 2012001604A2 · 2012 [cited by applicant]
WO 2015023961A2 · 2015 [cited by applicant]
WO 2016185171A1 · 2016 [cited by applicant]
WO WO2016193435A1 · 2016 [cited by examiner]
WO 2017102812A1 · 2017 [cited by applicant]
WO 2018002214A1 · 2018 [cited by applicant]
WO 2018019894A1 · 2018 [cited by applicant]
WO 2018019896A1 · 2018 [cited by applicant]
WO 2018077578A1 · 2018 [cited by applicant]
Voluminis Product Information Sheet, Sep. 7, 2010. [cited by applicant]
Office Communication dated Jun. 29, 2017 from U.S. Appl. No. 15/381,145, filed Dec. 16, 2016. [cited by applicant]
Office Communication dated Apr. 26, 2019 from U.S. Appl. No. 15/971,241, filed May 5, 2018. [cited by applicant]
Office Communication dated Oct. 1, 2019 from U.S. Appl. No. 15/971,241, filed May 5, 2018. [cited by applicant]
Office Communication dated Jan. 21, 2021 from U.S. Appl. No. 16/881,820, filed May 22, 2020. [cited by applicant]
Nesterenko et al. (2013) “Vegetable proteins in microencapsulation: A review of recent interventions and their effectiveness,” Industrial Crops and Products 42:469-479. [cited by applicant]
Nesterenko et al. (2014) “Comparative study of encapsulation of vitamins with native and modified soy protein,” Food Hydrocolloids 38:172-179. [cited by applicant]
Office Communication dated Nov. 7, 2022 from U.S. Appl. No. 17/459,348, filed Aug. 27, 2021. [cited by applicant]