IP Library Granted Patent US 12,445,107
Granted Patent B2
US 12,445,107 · App. 18/449,102 · Granted Oct 14, 2025

Non-lid-bonded MEMS resonator with phosphorus dopant

Inventors: Charles I. Grosjean (Los Gatos, CA); Ginel C. Hill (Sunnyvale, CA); Paul M. Hagelin (Saratoga, CA); Renata Melamud Berger (Palo Alto, CA); Aaron Partridge (Cupertino, CA); Markus Lutz (Mountain View, CA)
Assignee: SiTime Corporation
H03H9/2457B81C1/0069H03H3/0072H03H3/0076H03H9/1057B81C2201/0164B81C2201/0171
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,445,107
App. No.
18/449,102
Granted
Oct 14, 2025
Kind
B2
Abstract

A microelectromechanical system (MEMS) resonator includes a substrate having a substantially planar surface and a resonant member having sidewalls disposed in a nominally perpendicular orientation with respect to the planar surface. Impurity dopant is introduced via the sidewalls of the resonant member such that a non-uniform dopant concentration profile is established along axis extending between the sidewalls parallel to the substrate surface and exhibits a relative minimum concentration in a middle region of the axis.

Claims (40)

1. A semiconductor device comprising:

a substrate;

a layer stack on the substrate, the layer stack including a lid layer, the lid layer having been conformally deposited over one or more underlying layers of the layer stack, the lid layer having at least one vent, the at least one vent being plugged so as to, in combination with the lid layer, hermetically seal a cavity relative to the substrate, the cavity being defined by etch of one or more oxide layers of the layer stack through the at least one vent prior to the at least one vent being plugged; and

a microelectromechanical system (MEMS) device having a body that is free to vibrate or deflect within the cavity during operation of the semiconductor device, the body formed from one or more layers fabricated from the substrate, wherein at least one layer of the one or more layers has a phosphorus dopant concentration greater than or equal to 10 19 /cm 3 ;

wherein the semiconductor device comprises circuitry to (1) receive a signal representing a temperature of operation and a signal representing the resonance frequency, and (2) generate, using the signal representing the temperature of operation and the signal representing the resonance frequency, a timing reference signal, wherein the timing reference signal is to have a reduced proportional variation in frequency relative to a proportional variation in the resonance frequency as a function of change in the temperature of operation of the resonator.

2. The semiconductor device of claim 1 wherein the at least one layer defines a plane, wherein the body has a dimension that is parallel to the plane, and wherein a concentration of the phosphorus dopant within the body is non-uniform along the dimension.

3. The semiconductor device of claim 1 wherein:

the MEMS device comprises a resonator, wherein the body is to vibrate within the cavity at a resonance frequency during operation of the semiconductor device; and

the semiconductor device comprises at least one structure of the semiconductor device to sense the temperature of operation of the resonator.

4. The semiconductor device of claim 3 wherein the at least one structure is also fabricated from the at least one layer, and wherein the body and the at least one structure each feature a layer, of the at least one layer, having a phosphorus dopant concentration greater than or equal to 10 19 /cm 3 .

5. The semiconductor device of claim 4 wherein the resonator is a first MEMS resonator, wherein the at least one structure comprises the first MEMS resonator in combination with a second MEMS resonator, and wherein the first and second MEMS resonators each have a different predominant resonance axis relative to a crystallographic orientation of the at least one layer.

6. The semiconductor device of claim 5 wherein the different predominant resonance axis of the each of the first and second MEMS resonators differ from one another by approximately forty-five degrees.

7. The semiconductor device of claim 5 wherein the second MEMS resonator is to vibrate during operation of the semiconductor device at a resonance frequency which has a substantially-different temperature-dependent variation in resonance frequency relative to a temperature-dependent variation in the resonance frequency of the first MEMS resonator.

8. The semiconductor device of claim 4 wherein the resonator is a first MEMS resonator, wherein the at least one structure comprises the first MEMS resonator in combination with a second MEMS resonator, and wherein the first and second MEMS resonators are characterized as having substantially different maximum phosphorus dopant concentrations.

9. The semiconductor device of claim 3 wherein the at least one structure comprises at least one of a diode, a thermistor and a transistor.

10. The semiconductor device of claim 1 wherein a maximum phosphorus dopant concentration of the at least one layer, within the body, is greater than or equal to 10 21 /cm 3 .

11. The semiconductor device of claim 1 wherein the at least one layer is doped using a drive-in doping process, such that the at least one layer exhibits a dopant concentration gradient relative to a boundary of the at least one layer.

12. A method of manufacturing a semiconductor device, the method comprising:

forming a layer stack on a substrate so as to include a lid layer, wherein forming comprises conformally-depositing the lid layer over one or more underlying layers of the layer stack, and wherein forming comprises forming the lid layer so as to have at least one vent;

forming a cavity within the layer stack and a microelectromechanical system (MEMS) device, the MEMS device having a body that is free to vibrate or deflect, within the cavity, during operation of the semiconductor device;

wherein forming the MEMS device comprises doping one or more layers of the layer stack to have a phosphorus dopant concentration greater than or equal to 10 19 /cm 3 , and forming the body to include the phosphorus dopant concentration greater than or equal to 10 19 /cm 3 ;

wherein forming the cavity comprises etching one or more oxide layers of the layer stack through the at least one vent and, subsequently, plugging the at least one vent to hermetically seal the body within the cavity; and

wherein the method further comprises forming the semiconductor device to include circuitry operable to (1) receive a signal representing a temperature of operation and a signal representing the resonance frequency, and (2) generate, using the signal representing the temperature of operation and the signal representing the resonance frequency, a timing reference signal, wherein the timing reference signal is to have a reduced proportional variation in frequency relative to a proportional variation in the resonance frequency as a function of change in the temperature of operation of the resonator.

13. The method of claim 12 wherein the at least one layer defines a plane, wherein the body has a dimension that is parallel to the plane, and wherein doping is performed such that a concentration of the phosphorus dopant is non-uniform within the body along the dimension.

14. The method of claim 12 wherein:

the MEMS device comprises a resonator, wherein the body is to vibrate within the cavity at a resonance frequency during operation of the semiconductor device; and

the method further comprises forming at least one structure of the semiconductor device to sense the temperature of operation of the resonator.

15. The method of claim 14 wherein forming the at least one structure comprises forming the at least one structure to also include a layer of the at least one layer and a phosphorus dopant concentration greater than or equal to 10 19 /cm 3 .

16. The method of claim 15 wherein the resonator is a first MEMS resonator, wherein the at least one structure comprises the first MEMS resonator in combination with a second MEMS resonator, and wherein forming the at least one structure comprises forming the first and second MEMS resonators each to have a different predominant resonance axis relative to a crystallographic orientation of the at least one layer.

17. The method of claim 16 wherein forming the first and second MEMS resonators comprises forming the different predominant resonance axis of the each of the first and second MEMS resonators to differ from one another by approximately forty-five degrees.

18. The method of claim 16 wherein forming the first and second MEMS resonators comprises forming the second MEMS resonator to have a substantially-different temperature-dependent variation in resonance frequency than a temperature-dependent variation in the resonance frequency of the first MEMS resonator.

19. The method of claim 15 wherein the resonator is a first MEMS resonator, wherein the at least one structure comprises the first MEMS resonator in combination with a second MEMS resonator, and wherein forming the first and second MEMS resonators comprises forming the first and second MEMS resonators to have substantially different maximum phosphorus dopant concentrations.

20. The method of claim 12 wherein doping comprises causing the phosphorus dopant concentration of the at least one layer, within the body, to have a maximum phosphorus dopant concentration that is greater than or equal to 10 21 /cm 3 .

21. The method of claim 12 wherein doping comprises conformally depositing, on one or more layers of the layer stack, a substance having phosphorus, and using a temperature-based drive-in doping process to transfer phosphorus from the substance into the at least one layer and, subsequently, removing the substance.

22. A method of manufacturing a semiconductor device, the method comprising:

forming a layer stack on a substrate so as to include a lid layer, wherein forming comprises conformally-depositing the lid layer over one or more underlying layers of the layer stack, and wherein forming comprises forming the lid layer so as to have at least one vent;

forming a cavity within the layer stack and a microelectromechanical system (MEMS) device, the MEMS device having a body that is free to vibrate or deflect, within the cavity, during operation of the semiconductor device;

wherein forming the MEMS device comprises conformally depositing a phosphorus-based substance on at least one layer of the layer stack and using a thermal drive-in process to transfer phosphorus from the substance into the at least one layer of the layer stack, to cause the at least one layer of the layer stack to have a phosphorus dopant concentration greater than or equal to 1019/cm3, and forming the body to include the phosphorus dopant concentration greater than or equal to 1019/cm3;

wherein forming the cavity comprises etching one or more oxide layers of the layer stack through the at least one vent, to thereby free the body to vibrate or deflect within the cavity, and, subsequently, plugging the at least one vent to hermetically seal the body within the cavity; and

wherein the semiconductor device comprises circuitry to (1) receive a signal representing a temperature of operation and a signal representing the resonance frequency, and (2) generate, using the signal representing the temperature of operation and the signal representing the resonance frequency, a timing reference signal, wherein the timing reference signal is to have a reduced proportional variation in frequency relative to a proportional variation in the resonance frequency as a function of change in the temperature of operation of the resonator.

Assignments (2)
SECURITY INTEREST Recorded Jun 30, 2026
From: SITIME CORPORATION
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 075862/0712 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 14, 2023
From: GROSJEAN, CHARLES I.; HILL, GINEL; HAGELIN, PAUL M.; BERGER, RENATA MELAMUD; PARTRIDGE, AARON; LUTZ, MARKUS
To: SITIME CORPORATION
Reel/Frame 064577/0019 →
Continuity (7)
Continuation 16591717 · Oct 3, 2019
Division 15697417 · Sep 6, 2017
Division 14569538 · Dec 12, 2014
Division 13837407 · Mar 15, 2013
Provisional Application 61617230 · Mar 29, 2012
Provisional Application 61617389 · Mar 29, 2012
Related Publication 20240056054A1 · Feb 15, 2024
References Cited (57)
US 6630367B1 · Kubena · 2003 [cited by applicant]
US 6930367B2 · Lutz · 2005 [cited by examiner]
US 7369004B2 · Partridge · 2008 [cited by applicant]
US 7442258B2 · Kim · 2008 [cited by applicant]
US 7446619B2 · Partridge · 2008 [cited by applicant]
US 7639104B1 · Quevy · 2009 [cited by applicant]
US 7868522B2 · Ruby · 2011 [cited by applicant]
US 7944124B1 · Bernstein · 2011 [cited by applicant]
US 8234774B2 · Hagelin · 2012 [cited by applicant]
US 8354332B2 · Ayazi · 2013 [cited by applicant]
US 8546240B2 · Harame · 2013 [cited by applicant]
US 8558643B2 · Prunnila · 2013 [cited by applicant]
US 8916477B2 · Grosjean · 2014 [cited by applicant]
US 9774313B1 · Grosjean · 2017 [cited by examiner]
US 10476477B1 · Grosjean · 2019 [cited by applicant]
US 20050151592A1 · Patridge · 2005 [cited by applicant]
US 20060261915A1 · Lutz · 2006 [cited by applicant]
US 20060276015A1 · Morris · 2006 [cited by applicant]
US 20090153258A1 · Lutz · 2009 [cited by applicant]
US 20090158566A1 · Hagelin · 2009 [cited by applicant]
US 20090224850A1 · Nakamura · 2009 [cited by applicant]
US 20100127596A1 · Ayazi · 2010 [cited by applicant]
US 20100283353A1 · Van Der · 2010 [cited by applicant]
US 20110109194A1 · Hung · 2011 [cited by applicant]
US 20110127625A1 · Van Der · 2011 [cited by applicant]
US 20120013412A1 · Winkler · 2012 [cited by applicant]
US 20120043626A1 · Lin · 2012 [cited by applicant]
US 20120132003A1 · Comi · 2012 [cited by applicant]
US 20120286903A1 · Prunnila · 2012 [cited by applicant]
US 20130285676A1 · Rahafrooz · 2013 [cited by applicant]
US 20140339953A1 · Li · 2014 [cited by applicant]
US 20140339963A1 · Tihola · 2014 [cited by applicant]
US 20150091411A1 · Verhiejden · 2015 [cited by applicant]
US 20200095119A1 · Chang · 2020 [cited by applicant]
WO 2012110708A1 · 2012 [cited by applicant]
Bachelet et al., “Structural-energy calculations based on norm-conserving pseudopotentials and localized Gaussian orbitals”, Physical Review B, vol. 24, No. 8, pp. 4745-4752, Oct. 1981. [cited by applicant]
Bruner et al., “Electronic Effect in the Elastic Constants of Germanium”, Physical Review Letters, vol. 7, No. 2, pp. 55-56, Jul. 1961. [cited by applicant]
Cerdeira et al., “Effect of Carrier Concentration on the Raman Frequencies of Si and Ge”, Physical Review B, vol. 5, No. 4, pp. 1440-1454, Feb. 1972. [cited by applicant]
Csavinszky et al., “Effect of Doping on the Elastic Constants of Silicon”, Physical Review, vol. 132, No. 6, pp. 2434-2440 Dec. 1963. [cited by applicant]
ECN Magazine, “World's First MEMS Real Time Clock,” Nov. 29, 2010, 4 pages. [cited by applicant]
EE Times, “Built-in MEMS resonators beat quartz,” Nov. 30, 2010, 3 pages. [cited by applicant]
Einspruch et al., “Electronic Effect in the Elastic Constant C′ of Silicon”, Applied Physics Letters, vol. 2, No. 1, pp. 1-3, Jan. 1963. [cited by applicant]
Hall, “Electronic Effects in the Elastic Constraints of n-Type Silicon”, Physical Review, vol. 161, No. 3, pp. 756-761, Sep. 1967. [cited by applicant]
Harrison, “Pseudopotential theory of covalent bonding”, Physical Review B, vol. 14, No. 2, pp. 702-711, Jul. 1976. [cited by applicant]
Hopcroft et al., “What is the Young's Modulus of Silicon?”, Journal of Microelectromechanical Systems, vol. 19, No. 2, pp. 229-238, Apr. 2010. [cited by applicant]
Keyes, “Density of States of Degenerate n-Type Silicon from Elastic Constants”, Solid State Communications, vol. 32, No. 2, pp. 179-180; 1979. [cited by applicant]
Keyes, “Elastic Proporties of Diamond-Type Semiconductors”, Journal of Applied Physics, vol. 33, No. 11, pp. 3371-3372, Nov. 1962. [cited by applicant]
Kim, “Electronic effect on the elastic constant of n-type silicon”, J. Appl. Phys., vol. 52, No. 5, pp. 3693-3695, May 1981. [cited by applicant]
McSkimin, “Measurement of Elastic Constants at Low Temperatures by Means of Ultrasonic Waves—Data for Silicon and Germanium Single Crystals, and for Fused Silica”, Journal of Applied Physics, vol. 24, No. 8, pp. 988-997… [cited by applicant]
Pensala et al., “Temperature Compensation of Silicon MEMS Resonators by Heavy Doping”, Ultrasonics Symposium (IUS), 2011 IEEE International, pp. 1952-1955, Oct. 2011. [cited by applicant]
Pourkamali, Siavash; “High Frequency Capacitive Single Crystal Silicon Resonators and Coupled Resonator Systems,” Dissertation at Georgia Institute of Technology; Dec. 2006. [cited by applicant]
Rodriguez et al., “Structural properties of tetrahedrally coordinated crystals from first-principles calculations of pressure and total energies” Physical Review B, vol. 31, No. 8, pp. 5327-5334, Apr. 1985. [cited by applicant]
Samarao, et al., “Temperature Compensation of Silicon Micromechanical Resonators via Degenerate Doping”, IEDM, pp. 789-792, Dec. 2009. [cited by applicant]
Sanchez-Dehesa et al., “Self-consistent calculation of the internal strain parameter of silicon”, Physical Review B, vol. 26, No. 10, pp. 5960-5962, Nov. 1982. [cited by applicant]
Smith et al., “Reevaluation of the derivatives of the half order Fermi integrals”, J. Appl. Phys., vol. 73, No. 11, pp. 7030-7034, Jun. 1993. [cited by applicant]
Van Camp et al. “First Principles Calculation of Ground State and Electronic Properties of C and Si”, Physica Scripta, vol. 35, pp. 706-709; 1987. [cited by applicant]
A.K. Samarao et al., “Passive TCF compensation in high Q silicon micromechanical resonators,” 2010 IEEE 23rd Int'l Conf. on Microelectromechanical Systems (MEMS), 2010, pp. 116-119, doi: 10.1109/MEMSYS 2010.5442553. [cited by applicant]